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The role of concentration in electrolyte solutions for non-aqueous lithium-based batteries

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  • Guinevere A. Giffin

    (Fraunhofer Institute for Silicate Research
    Julius-Maximilians-University Würzburg)

Abstract

The main components and, most notably, the concentration of the non-aqueous electrolyte solution have not significantly changed since the commercialization of Li-ion batteries in the early 1990s. However, the quest for electrochemical energy storage systems with high-energy content has driven researchers to reconsider the suitability of the “standard” one molar concentration and look toward highly concentrated electrolyte solutions. However, the interplay between the fundamental electrolyte properties and the cell performance is not consistent with what would be expected based only on the electrolyte ionic conductivity. Here, the recent progress and future perspectives on the correlation between the physicochemical properties of non-standard electrolyte solutions and their ability to improve the energy storage performances of lithium-based batteries are discussed.

Suggested Citation

  • Guinevere A. Giffin, 2022. "The role of concentration in electrolyte solutions for non-aqueous lithium-based batteries," Nature Communications, Nature, vol. 13(1), pages 1-6, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32794-z
    DOI: 10.1038/s41467-022-32794-z
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    References listed on IDEAS

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    1. Jing Xie & Yi-Chun Lu, 2020. "A retrospective on lithium-ion batteries," Nature Communications, Nature, vol. 11(1), pages 1-4, December.
    2. Sebastian Pohlmann, 2022. "Metrics and methods for moving from research to innovation in energy storage," Nature Communications, Nature, vol. 13(1), pages 1-5, December.
    3. Jianhui Wang & Yuki Yamada & Keitaro Sodeyama & Ching Hua Chiang & Yoshitaka Tateyama & Atsuo Yamada, 2016. "Superconcentrated electrolytes for a high-voltage lithium-ion battery," Nature Communications, Nature, vol. 7(1), pages 1-9, November.
    4. Liumin Suo & Yong-Sheng Hu & Hong Li & Michel Armand & Liquan Chen, 2013. "A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries," Nature Communications, Nature, vol. 4(1), pages 1-9, June.
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