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Promoting superior K-ion storage of Bi2S3 nanorod anode via graphene physicochemical protection and electrolyte stabilization effect

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  • Yuan, Lingling
  • Zhou, Qianwen
  • Li, Ting
  • Wang, Yikun
  • Liu, Zhengqing
  • Chong, Shaokun

Abstract

Potassium-ion batteries (PIBs) have been considered as next generation energy storage device due to abundant and inexpensive resources, and exploring suitable anode materials based on conversion-alloying dual mechanism will promote the fast development of high energy density PIBs. In this work, Bi2S3 nano-rods wrapped by reduced graphene oxide (Bi2S3@rGO) are regarded as anodes for K-ion storage. The physical encapsulation of graphene and chemical bonding of Bi-O can boost the composite to provide outstanding electrochemical kinetics and structure stability. Furthermore, the electrolyte stabilization effect plays an important role in generating a more robust solid electrolyte interface film and maintaining effectiveness of chemical bonding. It is demonstrated by ex situ TEM that Bi2S3 electrode undergoes a dual electrochemical mechanism of conversion-alloying relied on 12 K-ion diffusion per formula unit (Bi2S3 + 6 K ↔ 2Bi + 3K2S, 2Bi + 6 K ↔ 2K3Bi). The above desirable features are integrated into the conductive composite for great cycling stability with high-capacity retention of 148.3 mAh·g−1 after 100 cycles at 50 mA·g−1. This work will guide the way for the construction of dual mechanism anode and the understanding of K-ion storage principle.

Suggested Citation

  • Yuan, Lingling & Zhou, Qianwen & Li, Ting & Wang, Yikun & Liu, Zhengqing & Chong, Shaokun, 2022. "Promoting superior K-ion storage of Bi2S3 nanorod anode via graphene physicochemical protection and electrolyte stabilization effect," Applied Energy, Elsevier, vol. 322(C).
    • Handle: RePEc:eee:appene:v:322:y:2022:i:c:s0306261922007978
    DOI: 10.1016/j.apenergy.2022.119471
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    References listed on IDEAS

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