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Photovoltage memory effect in a portable Faradaic junction solar rechargeable device

Author

Listed:
  • Pin Wang

    (Nanjing University)

  • Mengfan Xue

    (Nanjing University)

  • Dongjian Jiang

    (Nanjing University)

  • Yanliang Yang

    (Nanjing University)

  • Junzhe Zhang

    (Nanjing University)

  • Hongzheng Dong

    (Nanjing University)

  • Gengzhi Sun

    (Nanjing Tech University)

  • Yingfang Yao

    (Nanjing University)

  • Wenjun Luo

    (Nanjing University)

  • Zhigang Zou

    (Nanjing University
    Nanjing University)

Abstract

Two-electrode solar rechargeable device is one of the promising technologies to address the problem of solar energy storage in large scale. However, the mechanism of dark output voltage remains unclear and the low volumetric energy density also limits its practical applications. Herein, we report that a Si/CoOx/KBi(aq)/MnOx Faradaic junction device exhibits a photovoltage memory effect, that is, the dark output voltage can precisely record the value of the photovoltage in the device. To investigate the mechanism of the effect, we develop an open circuit potential method to real-time monitor the photo charge and dark discharge processes in the Faradaic junction device. This effect leads to minimized interface energy loss in the Faradaic junction device, which achieves much higher performances than the devices without the effect. Moreover, we realize a portable device with a record value of the dark volumetric energy density (∼1.89 mJ cm−3) among all reported two-electrode solar rechargeable devices. These results offer guidance to improve the performance of a solar rechargeable device and design other photoelectric devices for new applications.

Suggested Citation

  • Pin Wang & Mengfan Xue & Dongjian Jiang & Yanliang Yang & Junzhe Zhang & Hongzheng Dong & Gengzhi Sun & Yingfang Yao & Wenjun Luo & Zhigang Zou, 2022. "Photovoltage memory effect in a portable Faradaic junction solar rechargeable device," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-30346-z
    DOI: 10.1038/s41467-022-30346-z
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    References listed on IDEAS

    as
    1. Mingzhi Chen & Hongzheng Dong & Mengfan Xue & Chunsheng Yang & Pin Wang & Yanliang Yang & Heng Zhu & Congping Wu & Yingfang Yao & Wenjun Luo & Zhigang Zou, 2021. "Faradaic junction and isoenergetic charge transfer mechanism on semiconductor/semiconductor interfaces," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    2. Y. J. Zhang & T. Ideue & M. Onga & F. Qin & R. Suzuki & A. Zak & R. Tenne & J. H. Smet & Y. Iwasa, 2019. "Enhanced intrinsic photovoltaic effect in tungsten disulfide nanotubes," Nature, Nature, vol. 570(7761), pages 349-353, June.
    3. Quinn Burlingame & Xiaheng Huang & Xiao Liu & Changyeong Jeong & Caleb Coburn & Stephen R. Forrest, 2019. "Intrinsically stable organic solar cells under high-intensity illumination," Nature, Nature, vol. 573(7774), pages 394-397, September.
    4. Jiantie Xu & Yonghua Chen & Liming Dai, 2015. "Efficiently photo-charging lithium-ion battery by perovskite solar cell," Nature Communications, Nature, vol. 6(1), pages 1-7, November.
    5. J. Tyler Mefford & Andrew R. Akbashev & Minkyung Kang & Cameron L. Bentley & William E. Gent & Haitao D. Deng & Daan Hein Alsem & Young-Sang Yu & Norman J. Salmon & David A. Shapiro & Patrick R. Unwin, 2021. "Correlative operando microscopy of oxygen evolution electrocatalysts," Nature, Nature, vol. 593(7857), pages 67-73, May.
    6. Andrea Paolella & Cyril Faure & Giovanni Bertoni & Sergio Marras & Abdelbast Guerfi & Ali Darwiche & Pierre Hovington & Basile Commarieu & Zhuoran Wang & Mirko Prato & Massimo Colombo & Simone Monaco , 2017. "Light-assisted delithiation of lithium iron phosphate nanocrystals towards photo-rechargeable lithium ion batteries," Nature Communications, Nature, vol. 8(1), pages 1-10, April.
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    Cited by:

    1. Hongzheng Dong & Xiangyu Pan & Yuancai Gong & Mengfan Xue & Pin Wang & SocMan Ho-Kimura & Yingfang Yao & Hao Xin & Wenjun Luo & Zhigang Zou, 2023. "Potential window alignment regulating ion transfer in faradaic junctions for efficient photoelectrocatalysis," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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