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Giant intrinsic photovoltaic effect in one-dimensional van der Waals grain boundaries

Author

Listed:
  • Yongheng Zhou

    (Southern University of Science and Technology)

  • Xin Zhou

    (National University of Singapore
    Peking University)

  • Xiang-Long Yu

    (Southern University of Science and Technology
    International Quantum Academy)

  • Zihan Liang

    (Southern University of Science and Technology)

  • Xiaoxu Zhao

    (Peking University)

  • Taihong Wang

    (Southern University of Science and Technology)

  • Jinshui Miao

    (State Key Laboratory of Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences)

  • Xiaolong Chen

    (Southern University of Science and Technology)

Abstract

The photovoltaic effect lies at the heart of eco-friendly energy harvesting. However, the conversion efficiency of traditional photovoltaic effect utilizing the built-in electric effect in p-n junctions is restricted by the Shockley-Queisser limit. Alternatively, intrinsic/bulk photovoltaic effect (IPVE/BPVE), a second-order nonlinear optoelectronic effect arising from the broken inversion symmetry of crystalline structure, can overcome this theoretical limit. Here, we uncover giant and robust IPVE in one-dimensional (1D) van der Waals (vdW) grain boundaries (GBs) in a layered semiconductor, ReS2. The IPVE-induced photocurrent densities in vdW GBs are among the highest reported values compared with all kinds of material platforms. Furthermore, the IPVE-induced photocurrent is gate-tunable with a polarization-independent component along the GBs, which is preferred for energy harvesting. The observed IPVE in vdW GBs demonstrates a promising mechanism for emerging optoelectronics applications.

Suggested Citation

  • Yongheng Zhou & Xin Zhou & Xiang-Long Yu & Zihan Liang & Xiaoxu Zhao & Taihong Wang & Jinshui Miao & Xiaolong Chen, 2024. "Giant intrinsic photovoltaic effect in one-dimensional van der Waals grain boundaries," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-44792-4
    DOI: 10.1038/s41467-024-44792-4
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    as
    1. Yue Li & Jun Fu & Xiaoyu Mao & Chen Chen & Heng Liu & Ming Gong & Hualing Zeng, 2021. "Enhanced bulk photovoltaic effect in two-dimensional ferroelectric CuInP2S6," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    2. Hiroki Matsuo & Yuji Noguchi & Masaru Miyayama, 2017. "Gap-state engineering of visible-light-active ferroelectrics for photovoltaic applications," Nature Communications, Nature, vol. 8(1), pages 1-8, December.
    3. Y. J. Zhang & T. Ideue & M. Onga & F. Qin & R. Suzuki & A. Zak & R. Tenne & J. H. Smet & Y. Iwasa, 2019. "Enhanced intrinsic photovoltaic effect in tungsten disulfide nanotubes," Nature, Nature, vol. 570(7761), pages 349-353, June.
    4. Jingxuan Wei & Ying Li & Lin Wang & Wugang Liao & Bowei Dong & Cheng Xu & Chunxiang Zhu & Kah-Wee Ang & Cheng-Wei Qiu & Chengkuo Lee, 2020. "Zero-bias mid-infrared graphene photodetectors with bulk photoresponse and calibration-free polarization detection," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    5. Zihan Liang & Xin Zhou & Le Zhang & Xiang-Long Yu & Yan Lv & Xuefen Song & Yongheng Zhou & Han Wang & Shuo Wang & Taihong Wang & Perry Ping Shum & Qian He & Yanjun Liu & Chao Zhu & Lin Wang & Xiaolong, 2023. "Strong bulk photovoltaic effect in engineered edge-embedded van der Waals structures," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    6. Qinsheng Wang & Jingchuan Zheng & Yuan He & Jin Cao & Xin Liu & Maoyuan Wang & Junchao Ma & Jiawei Lai & Hong Lu & Shuang Jia & Dayu Yan & Youguo Shi & Junxi Duan & Junfeng Han & Wende Xiao & Jian-Hao, 2019. "Robust edge photocurrent response on layered type II Weyl semimetal WTe2," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
    7. Erfu Liu & Yajun Fu & Yaojia Wang & Yanqing Feng & Huimei Liu & Xiangang Wan & Wei Zhou & Baigeng Wang & Lubin Shao & Ching-Hwa Ho & Ying-Sheng Huang & Zhengyi Cao & Laiguo Wang & Aidong Li & Junwen Z, 2015. "Integrated digital inverters based on two-dimensional anisotropic ReS2 field-effect transistors," Nature Communications, Nature, vol. 6(1), pages 1-7, November.
    8. Yongmin He & Pengyi Tang & Zhili Hu & Qiyuan He & Chao Zhu & Luqing Wang & Qingsheng Zeng & Prafful Golani & Guanhui Gao & Wei Fu & Zhiqi Huang & Caitian Gao & Juan Xia & Xingli Wang & Xuewen Wang & C, 2020. "Engineering grain boundaries at the 2D limit for the hydrogen evolution reaction," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
    9. Ashley M. Cook & Benjamin M. Fregoso & Fernando de Juan & Sinisa Coh & Joel E. Moore, 2017. "Design principles for shift current photovoltaics," Nature Communications, Nature, vol. 8(1), pages 1-9, April.
    10. Jorge Quereda & Talieh S. Ghiasi & Jhih-Shih You & Jeroen Brink & Bart J. Wees & Caspar H. Wal, 2018. "Symmetry regimes for circular photocurrents in monolayer MoSe2," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    11. Junchao Ma & Bin Cheng & Lin Li & Zipu Fan & Haimen Mu & Jiawei Lai & Xiaoming Song & Dehong Yang & Jinluo Cheng & Zhengfei Wang & Changgan Zeng & Dong Sun, 2022. "Unveiling Weyl-related optical responses in semiconducting tellurium by mid-infrared circular photogalvanic effect," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
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    1. Zhouxiaosong Zeng & Zhiqiang Tian & Yufan Wang & Cuihuan Ge & Fabian Strauß & Kai Braun & Patrick Michel & Lanyu Huang & Guixian Liu & Dong Li & Marcus Scheele & Mingxing Chen & Anlian Pan & Xiao Wang, 2024. "Dual polarization-enabled ultrafast bulk photovoltaic response in van der Waals heterostructures," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Shouheng Chen & Zihan Liang & Jinshui Miao & Xiang-Long Yu & Shuo Wang & Yule Zhang & Han Wang & Yun Wang & Chun Cheng & Gen Long & Taihong Wang & Lin Wang & Han Zhang & Xiaolong Chen, 2024. "Infrared optoelectronics in twisted black phosphorus," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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