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Bioinspired design of Na-ion conduction channels in covalent organic frameworks for quasi-solid-state sodium batteries

Author

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  • Yingchun Yan

    (China University of Petroleum)

  • Zheng Liu

    (China University of Petroleum)

  • Ting Wan

    (China University of Petroleum)

  • Weining Li

    (China University of Petroleum)

  • Zhipeng Qiu

    (China University of Petroleum)

  • Chunlei Chi

    (China University of Petroleum)

  • Chao Huangfu

    (China University of Petroleum)

  • Guanwen Wang

    (China University of Petroleum)

  • Bin Qi

    (China University of Petroleum)

  • Youguo Yan

    (China University of Petroleum)

  • Tong Wei

    (China University of Petroleum)

  • Zhuangjun Fan

    (China University of Petroleum)

Abstract

Solid polymer electrolytes are considered among the most promising candidates for developing practical solid-state sodium batteries. However, moderate ionic conductivity and narrow electrochemical windows hinder their further application. Herein, inspired by the Na+/K+ conduction in biological membranes, we report a (–COO–)-modified covalent organic framework (COF) as a Na-ion quasi-solid-state electrolyte with sub-nanometre-sized Na+ transport zones (6.7–11.6 Å) created by adjacent –COO– groups and COF inwalls. The quasi-solid-state electrolyte enables selective Na+ transport along specific areas that are electronegative with sub-nanometre dimensions, resulting in a Na+ conductivity of 1.30×10–4 S cm–1 and oxidative stability of up to 5.32 V (versus Na+/Na) at 25 ± 1 °C. Testing the quasi-solid-state electrolyte in Na||Na3V2(PO4)3 coin cell configuration demonstrates fast reaction dynamics, low polarization voltages, and a stable cycling performance over 1000 cycles at 60 mA g–1 and 25 ± 1 °C with a 0.0048% capacity decay per cycle and a final discharge capacity of 83.5 mAh g−1.

Suggested Citation

  • Yingchun Yan & Zheng Liu & Ting Wan & Weining Li & Zhipeng Qiu & Chunlei Chi & Chao Huangfu & Guanwen Wang & Bin Qi & Youguo Yan & Tong Wei & Zhuangjun Fan, 2023. "Bioinspired design of Na-ion conduction channels in covalent organic frameworks for quasi-solid-state sodium batteries," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38822-w
    DOI: 10.1038/s41467-023-38822-w
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    References listed on IDEAS

    as
    1. Weiwen Xin & Jingru Fu & Yongchao Qian & Lin Fu & Xiang-Yu Kong & Teng Ben & Lei Jiang & Liping Wen, 2022. "Biomimetic KcsA channels with ultra-selective K+ transport for monovalent ion sieving," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Zhi Chang & Huijun Yang & Xingyu Zhu & Ping He & Haoshen Zhou, 2022. "A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    3. Qing Zhao & Xiaotun Liu & Sanjuna Stalin & Kasim Khan & Lynden A. Archer, 2019. "Solid-state polymer electrolytes with in-built fast interfacial transport for secondary lithium batteries," Nature Energy, Nature, vol. 4(5), pages 365-373, May.
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