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Lithium lanthanum titanate perovskite as an anode for lithium ion batteries

Author

Listed:
  • Lu Zhang

    (Jilin University)

  • Xiaohua Zhang

    (Northeast Normal University)

  • Guiying Tian

    (Tianjin University of Science & Technology
    Karlsruhe Institute of Technology (KIT))

  • Qinghua Zhang

    (Chinese Academy of Science)

  • Michael Knapp

    (Karlsruhe Institute of Technology (KIT))

  • Helmut Ehrenberg

    (Karlsruhe Institute of Technology (KIT))

  • Gang Chen

    (Jilin University)

  • Zexiang Shen

    (Jilin University
    Nanyang Technological University)

  • Guochun Yang

    (Northeast Normal University)

  • Lin Gu

    (Chinese Academy of Science)

  • Fei Du

    (Jilin University)

Abstract

Conventional lithium-ion batteries embrace graphite anodes which operate at potential as low as metallic lithium, subjected to poor rate capability and safety issues. Among possible alternatives, oxides based on titanium redox couple, such as spinel Li4Ti5O12, have received renewed attention. Here we further expand the horizon to include a perovskite structured titanate La0.5Li0.5TiO3 into this promising family of anode materials. With average potential of around 1.0 V vs. Li+/Li, this anode exhibits high specific capacity of 225 mA h g−1 and sustains 3000 cycles involving a reversible phase transition. Without decrease the particle size from micro to nano scale, its rate performance has exceeded the nanostructured Li4Ti5O12. Further characterizations and calculations reveal that pseudocapacitance dictates the lithium storage process and the favorable ion and electronic transport is responsible for the rate enhancement. Our findings provide fresh impetus to the identification and development of titanium-based anode materials with desired electrochemical properties.

Suggested Citation

  • Lu Zhang & Xiaohua Zhang & Guiying Tian & Qinghua Zhang & Michael Knapp & Helmut Ehrenberg & Gang Chen & Zexiang Shen & Guochun Yang & Lin Gu & Fei Du, 2020. "Lithium lanthanum titanate perovskite as an anode for lithium ion batteries," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-17233-1
    DOI: 10.1038/s41467-020-17233-1
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    References listed on IDEAS

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    1. M. Armand & J.-M. Tarascon, 2008. "Building better batteries," Nature, Nature, vol. 451(7179), pages 652-657, February.
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    1. Sunyoung Lee & Hayoung Park & Jae Young Kim & Jihoon Kim & Min-Ju Choi & Sangwook Han & Sewon Kim & Wonju Kim & Ho Won Jang & Jungwon Park & Kisuk Kang, 2024. "Unveiling crystal orientation-dependent interface property in composite cathodes for solid-state batteries by in situ microscopic probe," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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