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Cracks Formation in Lithium-Rich Cathode Materials for Lithium-Ion Batteries during the Electrochemical Process

Author

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  • Tao Cheng

    (Materials Genome Institute, Shanghai University, Shanghai 200444, China
    These authors contributed equally to this work.)

  • Zhongtao Ma

    (Materials Genome Institute, Shanghai University, Shanghai 200444, China
    These authors contributed equally to this work.)

  • Run Gu

    (Materials Genome Institute, Shanghai University, Shanghai 200444, China)

  • Riming Chen

    (Materials Genome Institute, Shanghai University, Shanghai 200444, China)

  • Yingchun Lyu

    (Materials Genome Institute, Shanghai University, Shanghai 200444, China)

  • Anmin Nie

    (Materials Genome Institute, Shanghai University, Shanghai 200444, China
    State Key Lab of Metastable Materials Science & Technology and Key Laboratory for Microstructure Material Physics of Hebei Province, Yanshan University, Qinhuangdao 066004, China)

  • Bingkun Guo

    (Materials Genome Institute, Shanghai University, Shanghai 200444, China)

Abstract

The lithium-rich Li[Li 0.2 Ni 0.13 Mn 0.54 Co 0.13 ]O 2 nanoplates were synthesized using a molten-salt method. The nanoplates showed an initial reversible discharge capacity of 233 mA·h·g −1 , with a fast capacity decay. The morphology and micro-structural change, after different cycles, were studied by a scanning electron microscope (SEM) and transmission electron microscopy (TEM) to understand the mechanism of the capacity decay. Our results showed that the cracks generated from both the particle surface and the inner, and increased with long-term cycling at 0.1 C rate (C = 250 mA·g −1 ), together with the layered to spinel and rock-salt phase transitions. These results show that the cracks and phase transitions could be responsible for the capacity decay. The results will help us to understand capacity decay mechanisms, and to guide our future work to improve the electrochemical performance of lithium-rich cathode materials.

Suggested Citation

  • Tao Cheng & Zhongtao Ma & Run Gu & Riming Chen & Yingchun Lyu & Anmin Nie & Bingkun Guo, 2018. "Cracks Formation in Lithium-Rich Cathode Materials for Lithium-Ion Batteries during the Electrochemical Process," Energies, MDPI, vol. 11(10), pages 1-10, October.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:10:p:2712-:d:174920
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    References listed on IDEAS

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    2. M. Armand & J.-M. Tarascon, 2008. "Building better batteries," Nature, Nature, vol. 451(7179), pages 652-657, February.
    3. Alpesh Khushalchand Shukla & Quentin M. Ramasse & Colin Ophus & Hugues Duncan & Fredrik Hage & Guoying Chen, 2015. "Unravelling structural ambiguities in lithium- and manganese-rich transition metal oxides," Nature Communications, Nature, vol. 6(1), pages 1-9, December.
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    1. Cornelius Satria Yudha & Soraya Ulfa Muzayanha & Hendri Widiyandari & Ferry Iskandar & Wahyudi Sutopo & Agus Purwanto, 2019. "Synthesis of LiNi 0.85 Co 0.14 Al 0.01 O 2 Cathode Material and its Performance in an NCA/Graphite Full-Battery," Energies, MDPI, vol. 12(10), pages 1-14, May.

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