IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v12y2021i1d10.1038_s41467-021-26739-1.html
   My bibliography  Save this article

Unveiling the key factor for the phase reconstruction and exsolved metallic particle distribution in perovskites

Author

Listed:
  • Hyunmin Kim

    (Ulsan National Institute of Science and Technology (UNIST))

  • Chaesung Lim

    (Pohang University of Science and Technology (POSTECH))

  • Ohhun Kwon

    (University of Pennsylvania)

  • Jinkyung Oh

    (Ulsan National Institute of Science and Technology (UNIST))

  • Matthew T. Curnan

    (Pohang University of Science and Technology (POSTECH))

  • Hu Young Jeong

    (Ulsan National Institute of Science and Technology (UNIST))

  • Sihyuk Choi

    (Kumoh National Institute of Technology)

  • Jeong Woo Han

    (Pohang University of Science and Technology (POSTECH))

  • Guntae Kim

    (Ulsan National Institute of Science and Technology (UNIST))

Abstract

To significantly increase the amount of exsolved particles, the complete phase reconstruction from simple perovskite to Ruddlesden-Popper (R-P) perovskite is greatly desirable. However, a comprehensive understanding of key parameters affecting the phase reconstruction to R-P perovskite is still unexplored. Herein, we propose the Gibbs free energy for oxygen vacancy formation in Pr0.5(Ba/Sr)0.5TO3-δ (T = Mn, Fe, Co, and Ni) as the important factor in determining the type of phase reconstruction. Furthermore, using in-situ temperature & environment-controlled X-ray diffraction measurements, we report the phase diagram and optimum ‘x’ range required for the complete phase reconstruction to R-P perovskite in Pr0.5Ba0.5-xSrxFeO3-δ system. Among the Pr0.5Ba0.5-xSrxFeO3-δ, (Pr0.5Ba0.2Sr0.3)2FeO4+δ – Fe metal demonstrates the smallest size of exsolved Fe metal particles when the phase reconstruction occurs under reducing condition. The exsolved nano-Fe metal particles exhibit high particle density and are well-distributed on the perovskite surface, showing great catalytic activity in fuel cell and syngas production.

Suggested Citation

  • Hyunmin Kim & Chaesung Lim & Ohhun Kwon & Jinkyung Oh & Matthew T. Curnan & Hu Young Jeong & Sihyuk Choi & Jeong Woo Han & Guntae Kim, 2021. "Unveiling the key factor for the phase reconstruction and exsolved metallic particle distribution in perovskites," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-26739-1
    DOI: 10.1038/s41467-021-26739-1
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-021-26739-1
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-021-26739-1?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Sangwook Joo & Ohhun Kwon & Kyeounghak Kim & Seona Kim & Hyunmin Kim & Jeeyoung Shin & Hu Young Jeong & Sivaprakash Sengodan & Jeong Woo Han & Guntae Kim, 2019. "Cation-swapped homogeneous nanoparticles in perovskite oxides for high power density," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    2. Dragos Neagu & Evangelos I. Papaioannou & Wan K. W. Ramli & David N. Miller & Billy J. Murdoch & Hervé Ménard & Ahmed Umar & Anders J. Barlow & Peter J. Cumpson & John T. S. Irvine & Ian S. Metcalfe, 2017. "Demonstration of chemistry at a point through restructuring and catalytic activation at anchored nanoparticles," Nature Communications, Nature, vol. 8(1), pages 1-8, December.
    3. Alexander K. Opitz & Andreas Nenning & Vedran Vonk & Sergey Volkov & Florian Bertram & Harald Summerer & Sabine Schwarz & Andreas Steiger-Thirsfeld & Johannes Bernardi & Andreas Stierle & Jürgen Fleig, 2020. "Understanding electrochemical switchability of perovskite-type exsolution catalysts," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    4. Jae-ha Myung & Dragos Neagu & David N. Miller & John T. S. Irvine, 2016. "Switching on electrocatalytic activity in solid oxide cells," Nature, Nature, vol. 537(7621), pages 528-531, September.
    5. Ohhun Kwon & Sivaprakash Sengodan & Kyeounghak Kim & Gihyeon Kim & Hu Young Jeong & Jeeyoung Shin & Young-Wan Ju & Jeong Woo Han & Guntae Kim, 2017. "Exsolution trends and co-segregation aspects of self-grown catalyst nanoparticles in perovskites," Nature Communications, Nature, vol. 8(1), pages 1-7, December.
    6. No Woo Kwak & Seung Jin Jeong & Han Gil Seo & Siwon Lee & YeonJu Kim & Jun Kyu Kim & Pilgyu Byeon & Sung-Yoon Chung & WooChul Jung, 2018. "In situ synthesis of supported metal nanocatalysts through heterogeneous doping," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    7. Dragos Neagu & Tae-Sik Oh & David N. Miller & Hervé Ménard & Syed M. Bukhari & Stephen R. Gamble & Raymond J. Gorte & John M. Vohs & John T.S. Irvine, 2015. "Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Bo-Wen Zhang & Meng-Nan Zhu & Min-Rui Gao & Xiuan Xi & Nanqi Duan & Zhou Chen & Ren-Fei Feng & Hongbo Zeng & Jing-Li Luo, 2022. "Boosting the stability of perovskites with exsolved nanoparticles by B-site supplement mechanism," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    2. Hyeon Han & Yaolong Xing & Bumsu Park & Dmitry I. Bazhanov & Yeongrok Jin & John T. S. Irvine & Jaekwang Lee & Sang Ho Oh, 2022. "Anti-phase boundary accelerated exsolution of nanoparticles in non-stoichiometric perovskite thin films," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Sanaz Koohfar & Masoud Ghasemi & Tyler Hafen & Georgios Dimitrakopoulos & Dongha Kim & Jenna Pike & Singaravelu Elangovan & Enrique D. Gomez & Bilge Yildiz, 2023. "Improvement of oxygen reduction activity and stability on a perovskite oxide surface by electrochemical potential," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    4. Jo, Seungyeon & Han Kim, Yo & Jeong, Hyeongwon & Park, Chan-ho & Won, Bo-Ram & Jeon, Hyejin & Taek Lee, Kang & Myung, Jae-ha, 2022. "Exsolution of phase-separated nanoparticles via trigger effect toward reversible solid oxide cell," Applied Energy, Elsevier, vol. 323(C).
    5. Wang, Junkai & Yang, Jiaming & Fu, Lei & Zong, Zheng & Zhou, Jun & Wu, Kai, 2022. "In-situ growth of Ru/RuO2 nanoparticles decorated (La0.6Sr1.4)0.95Mn0.9Ru0.1O4 as a potential electrode for symmetrical solid oxide fuel cells," Renewable Energy, Elsevier, vol. 189(C), pages 1419-1427.
    6. Eleonora Calì & Melonie P. Thomas & Rama Vasudevan & Ji Wu & Oriol Gavalda-Diaz & Katharina Marquardt & Eduardo Saiz & Dragos Neagu & Raymond R. Unocic & Stephen C. Parker & Beth S. Guiton & David J. , 2023. "Real-time insight into the multistage mechanism of nanoparticle exsolution from a perovskite host surface," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    7. Min Xu & Yukwon Jeon & Aaron Naden & Heesu Kim & Gwilherm Kerherve & David J. Payne & Yong-gun Shul & John T. S. Irvine, 2024. "Synergistic growth of nickel and platinum nanoparticles via exsolution and surface reaction," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Wang, Junkai & Zhou, Jun & Yang, Jiaming & Zong, Zheng & Fu, Lei & Lian, Zhongjie & Zhang, Xinchang & Wang, Xuan & Chen, Chengxiang & Ma, Wanli & Wu, Kai, 2020. "Nanoscale architecture of (La0.6Sr1.4)0.95Mn0.9B0.1O4 (BCo, Ni, Cu) Ruddlesden–Popper oxides as efficient and durable catalysts for symmetrical solid oxide fuel cells," Renewable Energy, Elsevier, vol. 157(C), pages 840-850.
    9. Georgiadis, Amvrosios G. & Tsiotsias, Anastasios I. & Siakavelas, George I. & Charisiou, Nikolaos D. & Ehrhardt, Benedikt & Wang, Wen & Sebastian, Victor & Hinder, Steven J. & Baker, Mark A. & Mascott, 2024. "An experimental and theoretical approach for the biogas dry reforming reaction using perovskite-derived La0.8X0.2NiO3-δ catalysts (X = Sm, Pr, Ce)," Renewable Energy, Elsevier, vol. 227(C).
    10. Vecino-Mantilla, Sebastian & Zignani, Sabrina C. & Vannier, Rose-Noëlle & Aricò, Antonino S. & Lo Faro, Massimiliano, 2022. "Insights on a Ruddlesden-Popper phase as an active layer for a solid oxide fuel cell fed with dry biogas," Renewable Energy, Elsevier, vol. 192(C), pages 784-792.
    11. Sulata K. Sahu & Dhruba Panthi & Ibrahim Soliman & Hai Feng & Yanhai Du, 2022. "Fabrication and Performance of Micro-Tubular Solid Oxide Cells," Energies, MDPI, vol. 15(10), pages 1-17, May.
    12. Kai Pei & Yucun Zhou & Kang Xu & Hua Zhang & Yong Ding & Bote Zhao & Wei Yuan & Kotaro Sasaki & YongMan Choi & Yu Chen & Meilin Liu, 2022. "Surface restructuring of a perovskite-type air electrode for reversible protonic ceramic electrochemical cells," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    13. Nechache, Aziz & Hody, Stéphane, 2021. "Alternative and innovative solid oxide electrolysis cell materials: A short review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    14. Khan, M.S. & Xu, X. & Knibbe, R. & Zhu, Z., 2021. "Air electrodes and related degradation mechanisms in solid oxide electrolysis and reversible solid oxide cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    15. Kim, J. & Sengodan, S. & Kim, S. & Kwon, O. & Bu, Y. & Kim, G., 2019. "Proton conducting oxides: A review of materials and applications for renewable energy conversion and storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 109(C), pages 606-618.
    16. Yudi Zhang & Kathryn E. Arpino & Qun Yang & Naoki Kikugawa & Dmitry A. Sokolov & Clifford W. Hicks & Jian Liu & Claudia Felser & Guowei Li, 2022. "Observation of a robust and active catalyst for hydrogen evolution under high current densities," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    17. Abdulrasheed, Abdulrahman & Jalil, Aishah Abdul & Gambo, Yahya & Ibrahim, Maryam & Hambali, Hambali Umar & Shahul Hamid, Muhamed Yusuf, 2019. "A review on catalyst development for dry reforming of methane to syngas: Recent advances," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 175-193.
    18. Zhaojian Liang & Jingyi Wang & Keda Ren & Zhenjun Jiao & Meng Ni & Liang An & Yang Wang & Jinbin Yang & Mengying Li, 2024. "Discovering two general characteristic times of transient responses in solid oxide cells," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    19. Wang, Chaoqi & Lü, Zhe & Li, Jingwei & Cao, Zhiqun & Wei, Bo & Li, Huan & Shang, Minghao & Su, Chaoxiang, 2020. "Efficient use of waste carton for power generation, tar and fertilizer through direct carbon solid oxide fuel cell," Renewable Energy, Elsevier, vol. 158(C), pages 410-420.
    20. Jia Zhao & Ricardo Urrego-Ortiz & Nan Liao & Federico Calle-Vallejo & Jingshan Luo, 2024. "Rationally designed Ru catalysts supported on TiN for highly efficient and stable hydrogen evolution in alkaline conditions," Nature Communications, Nature, vol. 15(1), pages 1-14, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-26739-1. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.