IDEAS home Printed from https://ideas.repec.org/a/gam/jsusta/v10y2018i11p4145-d182035.html
   My bibliography  Save this article

Sustainable Recovery of CO 2 by Using Visible-Light-Responsive Crystal Cuprous Oxide/Reduced Graphene Oxide

Author

Listed:
  • Shou-Heng Liu

    (Department of Environmental Engineering, National Cheng Kung University, Tainan 70101, Taiwan)

  • Jun-Sheng Lu

    (Department of Environmental Engineering, National Cheng Kung University, Tainan 70101, Taiwan)

  • Yi-Chiun Chen

    (Department of Environmental Engineering, National Cheng Kung University, Tainan 70101, Taiwan
    Department of Resources Engineering, National Cheng Kung University, Tainan 701, Taiwan)

Abstract

A simple solution-chemistry method has been investigated to prepare crystal cuprous oxide (Cu 2 O) incorporated with reduced graphene oxide (designated as Cu 2 O-rGO- x , where x represents the contents of rGO = 1%, 5% and 10%) in this work. These Cu 2 O-rGO- x composites combine the prospective advantages of rhombic dodecahedra Cu 2 O together with rGO nanosheets which have been studied as visible-light-sensitive catalysts for the photocatalytic production of methanol from CO 2 . Among the Cu 2 O-rGO- x photocatalysts, the methanol yield photocatalyzed by Cu 2 O-rGO-5% can be observed to be 355.26 μmol g −1 cat, which is ca. 36 times higher than that of pristine Cu 2 O nanocrystal in the 20th hour under visible light irradiation. The improved activity may be attributed to the enhanced absorption ability of visible light, the superior separation of electron–hole pairs, well-dispersed Cu 2 O nanocrystals and the increased photostability of Cu 2 O, which are evidenced by employing UV-vis diffuse reflection spectroscopy, photoluminescence, scanning electron microscopy/transmission electron microscopy and X-ray photoelectron spectroscopy, respectively. This work demonstrates an easy and cost-effective route to prepare non-noble photocatalysts for efficient CO 2 recovery in artificial photosynthesis.

Suggested Citation

  • Shou-Heng Liu & Jun-Sheng Lu & Yi-Chiun Chen, 2018. "Sustainable Recovery of CO 2 by Using Visible-Light-Responsive Crystal Cuprous Oxide/Reduced Graphene Oxide," Sustainability, MDPI, vol. 10(11), pages 1-13, November.
  • Handle: RePEc:gam:jsusta:v:10:y:2018:i:11:p:4145-:d:182035
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2071-1050/10/11/4145/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/2071-1050/10/11/4145/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Heng Rao & Luciana C. Schmidt & Julien Bonin & Marc Robert, 2017. "Visible-light-driven methane formation from CO2 with a molecular iron catalyst," Nature, Nature, vol. 548(7665), pages 74-77, August.
    2. John M. DeCicco, 2018. "Methodological Issues Regarding Biofuels and Carbon Uptake," Sustainability, MDPI, vol. 10(5), pages 1-15, May.
    3. Angelika Więckol-Ryk & Alicja Krzemień & Adam Smoliński & Fernando Sánchez Lasheras, 2018. "Analysis of Biomass Blend Co-Firing for Post Combustion CO 2 Capture," Sustainability, MDPI, vol. 10(4), pages 1-15, March.
    4. Liu, Shou-Heng & Syu, Han-Ren, 2012. "One-step fabrication of N-doped mesoporous TiO2 nanoparticles by self-assembly for photocatalytic water splitting under visible light," Applied Energy, Elsevier, vol. 100(C), pages 148-154.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Duong Duc La & Tuan Anh Nguyen & Thanh Tung Nguyen & Ha Duc Ninh & Hoai Phuong Nguyen Thi & Tham Thi Nguyen & Duy Anh Nguyen & Trung Dung Dang & Eldon R. Rene & Soon Woong Chang & Hien Tran Thi & Dinh, 2019. "Absorption Behavior of Graphene Nanoplates toward Oils and Organic Solvents in Contaminated Water," Sustainability, MDPI, vol. 11(24), pages 1-9, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Shuang Yang & Huiqing Yuan & Kai Guo & Zuting Wei & Mei Ming & Jinzhi Yi & Long Jiang & Zhiji Han, 2024. "Fluorinated chlorin chromophores for red-light-driven CO2 reduction," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Zhengwei Yang & Zhen-Yu Wu & Zhexing Lin & Tianji Liu & Liping Ding & Wenbo Zhai & Zipeng Chen & Yi Jiang & Jinlei Li & Siyun Ren & Zhenhui Lin & Wangxi Liu & Jianyong Feng & Xing Zhang & Wei Li & Yi , 2024. "Optically selective catalyst design with minimized thermal emission for facilitating photothermal catalysis," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    3. Shengyao Wang & Bo Jiang & Joel Henzie & Feiyan Xu & Chengyuan Liu & Xianguang Meng & Sirong Zou & Hui Song & Yang Pan & Hexing Li & Jiaguo Yu & Hao Chen & Jinhua Ye, 2023. "Designing reliable and accurate isotope-tracer experiments for CO2 photoreduction," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    4. Hu, Yulin & Gong, Mengyue & Xing, Xuelian & Wang, Haoyu & Zeng, Yimin & Xu, Chunbao Charles, 2020. "Supercritical water gasification of biomass model compounds: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).
    5. Chih-Chun Kung & Bruce A. McCarl, 2018. "Sustainable Energy Development under Climate Change," Sustainability, MDPI, vol. 10(9), pages 1-4, September.
    6. Chen, Guanyi & Zhao, Liu & Qi, Yun, 2015. "Enhancing the productivity of microalgae cultivated in wastewater toward biofuel production: A critical review," Applied Energy, Elsevier, vol. 137(C), pages 282-291.
    7. Duan, Huiling & Xuan, Yimin, 2014. "Enhanced optical absorption of the plasmonic nanoshell suspension based on the solar photocatalytic hydrogen production system," Applied Energy, Elsevier, vol. 114(C), pages 22-29.
    8. Zhang, Shijie & Tang, Jixia & Chen, Weiyu & Qian, Tu & Li, Xuechen & Feng, Zixuan & He, Jie & Zhang, Rui & Yang, Zhengchun & Li, Huayi & Pan, Peng & Zhang, Kailiang & Zheng, Lingcheng & Feng, Deqiang, 2024. "Advanced flexible photocatalytic fuel cell using TiO2/carbon quantum dots photoanode for green electricity production," Applied Energy, Elsevier, vol. 357(C).
    9. Karol Tucki & Olga Orynycz & Andrzej Wasiak & Antoni Świć & Remigiusz Mruk & Katarzyna Botwińska, 2020. "Estimation of Carbon Dioxide Emissions from a Diesel Engine Powered by Lignocellulose Derived Fuel for Better Management of Fuel Production," Energies, MDPI, vol. 13(3), pages 1-29, January.
    10. Cheng, Ya-Hsin & Nguyen, Van-Huy & Chan, Hsiang-Yu & Wu, Jeffrey C.S. & Wang, Wei-Hon, 2015. "Photo-enhanced hydrogenation of CO2 to mimic photosynthesis by CO co-feed in a novel twin reactor," Applied Energy, Elsevier, vol. 147(C), pages 318-324.
    11. Qinqin Lei & Huiqing Yuan & Jiehao Du & Mei Ming & Shuang Yang & Ya Chen & Jingxiang Lei & Zhiji Han, 2023. "Photocatalytic CO2 reduction with aminoanthraquinone organic dyes," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    12. Yan Shen & Chunjin Ren & Lirong Zheng & Xiaoyong Xu & Ran Long & Wenqing Zhang & Yong Yang & Yongcai Zhang & Yingfang Yao & Haoqiang Chi & Jinlan Wang & Qing Shen & Yujie Xiong & Zhigang Zou & Yong Zh, 2023. "Room-temperature photosynthesis of propane from CO2 with Cu single atoms on vacancy-rich TiO2," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    13. Shuaishuai Wang & Tingrui Li & Chengyihan Gu & Jie Han & Chuan-Gang Zhao & Chengjian Zhu & Hairen Tan & Jin Xie, 2022. "Decarboxylative tandem C-N coupling with nitroarenes via SH2 mechanism," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    14. Xiaodong Li & Li Li & Xingyuan Chu & Xiaohui Liu & Guangbo Chen & Quanquan Guo & Zhen Zhang & Mingchao Wang & Shuming Wang & Alexander Tahn & Yongfu Sun & Xinliang Feng, 2024. "Photothermal CO2 conversion to ethanol through photothermal heterojunction-nanosheet arrays," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    15. Hidalgo, D. & Martín-Marroquín, J.M., 2020. "Power-to-methane, coupling CO2 capture with fuel production: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 132(C).
    16. Delavari, Saeed & Amin, Nor Aishah Saidina, 2016. "Photocatalytic conversion of CO2 and CH4 over immobilized titania nanoparticles coated on mesh: Optimization and kinetic study," Applied Energy, Elsevier, vol. 162(C), pages 1171-1185.
    17. Bonenkamp, T.B. & Middelburg, L.M. & Hosli, M.O. & Wolffenbuttel, R.F., 2020. "From bioethanol containing fuels towards a fuel economy that includes methanol derived from renewable sources and the impact on European Union decision-making on transition pathways," Renewable and Sustainable Energy Reviews, Elsevier, vol. 120(C).
    18. Sanchita Karmakar & Soumitra Barman & Faruk Ahamed Rahimi & Darsi Rambabu & Sukhendu Nath & Tapas Kumar Maji, 2023. "Confining charge-transfer complex in a metal-organic framework for photocatalytic CO2 reduction in water," Nature Communications, Nature, vol. 14(1), pages 1-13, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jsusta:v:10:y:2018:i:11:p:4145-:d:182035. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.