IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v277y2023ics0360544223009854.html
   My bibliography  Save this article

Thermodynamic and kinetic affinity of CO2 relative to CH4 and their pressure, temperature and pore structure sensitivity in the competitive adsorption system in shale gas reservoirs

Author

Listed:
  • Xie, Weidong
  • Wang, Hua
  • Vandeginste, Veerle
  • Chen, Si
  • Gan, Huajun
  • Wang, Meng
  • Yu, Zhenghong

Abstract

The adsorption rate, capacity, affinity of CH4 and CO2 in the competitive adsorption system are controlled by their adsorption thermodynamic and kinetic property. In this work, the experimental results of isothermal adsorption and adsorption kinetic experiments at different temperature and pressure are utilized to investigate the thermodynamic and kinetic mechanism of the adsorption difference between CH4 and CO2. Ten thermodynamic models and seven kinetic models are employed to fit the experimental data, and the thermodynamic and kinetic parameters obtained from the fitting process are used to characterize the diffusion ability, adsorption rate, adsorption capacity, adsorption strength, spontaneity of adsorption, difficulty of adsorption, and driver of adsorption in the gas adsorption process. Furthermore, their difference between CH4 and CO2, temperature and pressure sensitivity, and the influence of shale property and pore structure are discussed to clarify the thermodynamic and kinetic mechanism of the higher adsorption affinity of CO2. Results show that (i) the ability of CO2 entering shale pores and contacting adsorption sites is greater than CH4, (ii) the adsorption capacity and adsorption strength of shale to CO2 is higher, (iii) the adsorption of gas is spontaneous and enthalpy-driven, (iv) the selective coefficient of CO2 relative to CH4 decreases with higher experimental pressure and temperature and is caused by the higher pressure and temperature sensitivity of its thermodynamic and kinetic property. Results of this work are of specific reference for research on the adsorption thermodynamic and kinetic behavior of gases and designing schemes of CO2 injection into shale gas reservoirs.

Suggested Citation

  • Xie, Weidong & Wang, Hua & Vandeginste, Veerle & Chen, Si & Gan, Huajun & Wang, Meng & Yu, Zhenghong, 2023. "Thermodynamic and kinetic affinity of CO2 relative to CH4 and their pressure, temperature and pore structure sensitivity in the competitive adsorption system in shale gas reservoirs," Energy, Elsevier, vol. 277(C).
    • Handle: RePEc:eee:energy:v:277:y:2023:i:c:s0360544223009854
    DOI: 10.1016/j.energy.2023.127591
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544223009854
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2023.127591?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Guo, Liheng & Ding, Yudong & Liao, Qiang & Zhu, Xun & Wang, Hong, 2022. "A new heat supply strategy for CO2 capture process based on the heat recovery from turbine exhaust steam in a coal-fired power plant," Energy, Elsevier, vol. 239(PA).
    2. Yuan Chi & Changzhong Zhao & Junchen Lv & Jiafei Zhao & Yi Zhang, 2019. "Thermodynamics and Kinetics of CO 2 /CH 4 Adsorption on Shale from China: Measurements and Modeling," Energies, MDPI, vol. 12(6), pages 1-13, March.
    3. Li, Shuangjun & Deng, Shuai & Zhao, Li & Yuan, Xiangzhou & Yun, Heesun, 2020. "How to express the adsorbed CO2 with the Gibbs’ thermodynamic graphical method: A preliminary study," Energy, Elsevier, vol. 193(C).
    4. Lin, Kui & Zhao, Ya-Pu, 2021. "Entropy and enthalpy changes during adsorption and displacement of shale gas," Energy, Elsevier, vol. 221(C).
    5. Huang, Liang & Ning, Zhengfu & Wang, Qing & Zhang, Wentong & Cheng, Zhilin & Wu, Xiaojun & Qin, Huibo, 2018. "Effect of organic type and moisture on CO2/CH4 competitive adsorption in kerogen with implications for CO2 sequestration and enhanced CH4 recovery," Applied Energy, Elsevier, vol. 210(C), pages 28-43.
    6. Zhang, Chaolin & Wang, Enyuan & Li, Bobo & Kong, Xiangguo & Xu, Jiang & Peng, Shoujian & Chen, Yuexia, 2023. "Laboratory experiments of CO2-enhanced coalbed methane recovery considering CO2 sequestration in a coal seam," Energy, Elsevier, vol. 262(PA).
    7. Qin, Chao & Jiang, Yongdong & Zuo, Shuangying & Chen, Shiwan & Xiao, Siyou & Liu, Zhengjie, 2021. "Investigation of adsorption kinetics of CH4 and CO2 on shale exposure to supercritical CO2," Energy, Elsevier, vol. 236(C).
    8. Xie, Weidong & Wang, Meng & Chen, Si & Vandeginste, Veerle & Yu, Zhenghong & Wang, Hua, 2022. "Effects of gas components, reservoir property and pore structure of shale gas reservoir on the competitive adsorption behavior of CO2 and CH4," Energy, Elsevier, vol. 254(PB).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wu, Jian & Shen, Luming & Huang, Pengyu & Gan, Yixiang, 2023. "Selective adsorption and transport of CO2–CH4 mixture under nano-confinement," Energy, Elsevier, vol. 273(C).
    2. Wu, Jian & Gan, Yixiang & Shi, Zhang & Huang, Pengyu & Shen, Luming, 2023. "Pore-scale lattice Boltzmann simulation of CO2-CH4 displacement in shale matrix," Energy, Elsevier, vol. 278(PB).
    3. Guang, Wenfeng & Zhang, Zhenyu & Zhang, Lei & Ranjith, P.G. & Hao, Shengpeng & Liu, Xiaoqian, 2023. "Confinement effect on transport diffusivity of adsorbed CO2–CH4 mixture in coal nanopores for CO2 sequestration and enhanced CH4 recovery," Energy, Elsevier, vol. 278(PA).
    4. Qin, Chao & Jiang, Yongdong & Zhou, Junping & Zuo, Shuangying & Chen, Shiwan & Liu, Zhengjie & Yin, Hong & Li, Ye, 2022. "Influence of supercritical CO2 exposure on water wettability of shale: Implications for CO2 sequestration and shale gas recovery," Energy, Elsevier, vol. 242(C).
    5. Gao, Zheng & Li, Bobo & Li, Jianhua & Jia, Lidan & Wang, Zhonghui, 2023. "Adsorption characteristics and thermodynamic analysis of shale in northern Guizhou, China: Measurement, modeling and prediction," Energy, Elsevier, vol. 262(PA).
    6. Fu, Shenguang & Wang, Liang & Li, Shuohao & Ni, Sijia & Cheng, Yuanping & Zhang, Xiaolei & Liu, Shimin, 2024. "Re-thinking methane storage mechanism in highly metamorphic coalbed reservoirs — A molecular simulation considering organic components," Energy, Elsevier, vol. 293(C).
    7. Lei Pan & Ling Chen & Peng Cheng & Haifeng Gai, 2022. "Methane Storage Capacity of Permian Shales with Type III Kerogen in the Lower Yangtze Area, Eastern China," Energies, MDPI, vol. 15(5), pages 1-23, March.
    8. Chen, Yang & Wu, Ye & Liu, Xing & Ma, Jiliang & Liu, Daoyin & Chen, Xiaoping & Liu, Dong, 2024. "Energy, exergy and economic (3E) analysis of a novel integration process based on coal-fired power plant with CO2 capture & storage, CO2 refrigeration, and waste heat recovery," Energy, Elsevier, vol. 299(C).
    9. Geng, Jiabo & Zeng, Gaoxiong & Liu, Cunyang & Li, Xiaoshuang & Zhang, Dongming, 2023. "Development and application of triaxial seepage test system for gas-water two-phase in coal rock," Energy, Elsevier, vol. 277(C).
    10. Sun, Fuqiang & Du, Shuheng & Zhao, Ya-Pu, 2022. "Fluctuation of fracturing curves indicates in-situ brittleness and reservoir fracturing characteristics in unconventional energy exploitation," Energy, Elsevier, vol. 252(C).
    11. Qin, Chao & Jiang, Yongdong & Cao, Mengyao & Zhou, Junping & Song, Xiao & Zuo, Shuangying & Chen, Shiwan & Luo, Yahuang & Xiao, Siyou & Yin, Hong & Du, Xidong, 2023. "Experimental study on the methane desorption-diffusion behavior of Longmaxi shale exposure to supercritical CO2," Energy, Elsevier, vol. 262(PA).
    12. Liu, Bo & Mohammadi, Mohammad-Reza & Ma, Zhongliang & Bai, Longhui & Wang, Liu & Xu, Yaohui & Hemmati-Sarapardeh, Abdolhossein & Ostadhassan, Mehdi, 2023. "Pore structure evolution of Qingshankou shale (kerogen type I) during artificial maturation via hydrous and anhydrous pyrolysis: Experimental study and intelligent modeling," Energy, Elsevier, vol. 282(C).
    13. Yang, Xue & Chen, Zeqin & Liu, Xiaoqiang & Xue, Zhiyu & Yue, Fen & Wen, Junjie & Li, Meijun & Xue, Ying, 2022. "Correction of gas adsorption capacity in quartz nanoslit and its application in recovering shale gas resources by CO2 injection: A molecular simulation," Energy, Elsevier, vol. 240(C).
    14. Konstantin Kalmykov & Irina Anikina & Daria Kolbantseva & Milana Trescheva & Dmitriy Treschev & Aleksandr Kalyutik & Alena Aleshina & Iaroslav Vladimirov, 2022. "Use of Heat Pumps in the Hydrogen Production Cycle at Thermal Power Plants," Sustainability, MDPI, vol. 14(13), pages 1-18, June.
    15. Dai, Xuguang & Wei, Chongtao & Wang, Meng & Ma, Ruying & Song, Yu & Zhang, Junjian & Wang, Xiaoqi & Shi, Xuan & Vandeginste, Veerle, 2023. "Interaction mechanism of supercritical CO2 with shales and a new quantitative storage capacity evaluation method," Energy, Elsevier, vol. 264(C).
    16. Wei, Jianguang & Fu, Lanqing & Zhao, Guozhong & Zhao, Xiaoqing & Liu, Xinrong & Wang, Anlun & Wang, Yan & Cao, Sheng & Jin, Yuhan & Yang, Fengrui & Liu, Tianyang & Yang, Ying, 2023. "Nuclear magnetic resonance study on imbibition and stress sensitivity of lamellar shale oil reservoir," Energy, Elsevier, vol. 282(C).
    17. Yijie Xing & Xianming Xiao & Qin Zhou & Wei Liu & Yanming Zhao, 2023. "Influence of Water on the Methane Adsorption Capacity of Organic-Rich Shales and Its Controlling Factors: A Review," Energies, MDPI, vol. 16(8), pages 1-29, April.
    18. Huang, Xianfu & Zhao, Ya-Pu, 2023. "Evolution of pore structure and adsorption-desorption in oil shale formation rocks after compression," Energy, Elsevier, vol. 278(PA).
    19. Liu, Zhengdong & Lin, Xiaosong & Zhu, Wancheng & Hu, Ze & Hao, Congmeng & Su, Weiwei & Bai, Gang, 2023. "Effects of coal permeability rebound and recovery phenomenon on CO2 storage capacity under different coalbed temperature conditions during CO2-ECBM process," Energy, Elsevier, vol. 284(C).
    20. Zhou, Aitao & Li, Jingwen & Gong, Weili & Wang, Kai & Du, Changang, 2023. "Theoretical and numerical study on the contribution of multi-hole arrangement to coalbed methane extraction," Energy, Elsevier, vol. 284(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:277:y:2023:i:c:s0360544223009854. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.