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Application of Proton Ionic Liquid in the Process of Obtaining Bioethanol from Hemp Stalks

Author

Listed:
  • Małgorzata Smuga-Kogut

    (Department of Agrobiotechnology, Faculty of Mechanical Engineering, Koszalin University of Technology, Raclawicka 15-17, 75-620 Koszalin, Poland)

  • Bartosz Walendzik

    (Faculty of Civil Engineering, Environmental and Geodetic Sciences, Koszalin University of Technology, Sniadeckich 2, 75-453 Koszalin, Poland)

  • Katarzyna Lewicka-Rataj

    (Water Management Laboratory, Faculty of Civil Engineering, Environmental and Geodetic Studies, Koszalin University of Technology, Sniadeckich 2, 75-453 Koszalin, Poland)

  • Tomasz Kogut

    (Department of Geodesy and Offshore Survey, Maritime University of Szczecin, Waly Chrobrego 1-2, 70-500 Szczecin, Poland)

  • Leszek Bychto

    (Department of Electronics, Faculty of Electronics and Computer Science, Koszalin University of Technology, Sniadeckich 2, 75-453 Koszalin, Poland)

  • Piotr Jachimowicz

    (Department of Environmental Biotechnology, University of Warmia and Mazury in Olsztyn, Słoneczna 45G, 10-709 Olsztyn, Poland)

  • Agnieszka Cydzik-Kwiatkowska

    (Department of Environmental Biotechnology, University of Warmia and Mazury in Olsztyn, Słoneczna 45G, 10-709 Olsztyn, Poland)

Abstract

In this work, hemp ( Cannabis sativa L.) stalks were pretreated with pyrrolidinium acetate [Pyrr][AC] to increase the availability of cellulose for cellulolytic enzymes and thus improve the production of 2G ethanol from reducing sugars. The process was carried out under different temperature and time conditions: The control sample was raw material and deionized water, and the second sample was kept at 21 °C for 24 h. The third sample was kept at 90 °C for 30 min, and the fourth sample was kept at the same temperature for 24 h. For each pretreatment, the extraction of lignin and hemicellulose was determined, as well as the change in biomass composition before and after pretreatment. The stalks of hemp seed contained 41.54% cellulose, 18.08% lignin and 28. 87% hemicellulose. [Pyrr][AC] used to dissolve seed hemp at 90 °C for 24 h was most effective in the extraction of this biopolymer, extracting 3.1% content. After enzymatic hydrolysis, the highest content of reducing sugars was found for samples of hemp stalks that were first pretreated with proton ionic liquid (PIL) and stirred at 90 °C for 24 h. On the other hand, the highest ethanol content (5.6 g/L) after fermentation and yeast viability (56.7%) after 72 h were obtained in samples pretreated at 90 °C and for 24 h.

Suggested Citation

  • Małgorzata Smuga-Kogut & Bartosz Walendzik & Katarzyna Lewicka-Rataj & Tomasz Kogut & Leszek Bychto & Piotr Jachimowicz & Agnieszka Cydzik-Kwiatkowska, 2024. "Application of Proton Ionic Liquid in the Process of Obtaining Bioethanol from Hemp Stalks," Energies, MDPI, vol. 17(4), pages 1-15, February.
  • Handle: RePEc:gam:jeners:v:17:y:2024:i:4:p:972-:d:1341621
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    References listed on IDEAS

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    1. Shafiei, Marzieh & Zilouei, Hamid & Zamani, Akram & Taherzadeh, Mohammad J. & Karimi, Keikhosro, 2013. "Enhancement of ethanol production from spruce wood chips by ionic liquid pretreatment," Applied Energy, Elsevier, vol. 102(C), pages 163-169.
    2. Xu, Feng & Yu, Jianming & Tesso, Tesfaye & Dowell, Floyd & Wang, Donghai, 2013. "Qualitative and quantitative analysis of lignocellulosic biomass using infrared techniques: A mini-review," Applied Energy, Elsevier, vol. 104(C), pages 801-809.
    3. Mussatto, Solange I. & Machado, Ercília M.S. & Carneiro, Lívia M. & Teixeira, José A., 2012. "Sugars metabolism and ethanol production by different yeast strains from coffee industry wastes hydrolysates," Applied Energy, Elsevier, vol. 92(C), pages 763-768.
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