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Enhancement of ethanol production from spruce wood chips by ionic liquid pretreatment

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  • Shafiei, Marzieh
  • Zilouei, Hamid
  • Zamani, Akram
  • Taherzadeh, Mohammad J.
  • Karimi, Keikhosro

Abstract

Pretreatment with three green cellulose solvents, N-methylmorpholine-N-oxide (NMMO), 1-ethyl-3-methylimidazolium acetate ([EMIM][OAc]), and 1-butyl-3-methylimidazolium acetate ([BMIM][OAc]) were used for improvement of ethanol production. Spruce chips and powder were pretreated at 120°C for 1, 3, and 15h. In order to investigate the efficiency of the pretreatments, the pretreated materials were subjected to enzymatic hydrolysis at 45°C for 72h, followed by fermentation with Saccharomyces cerevisiae at 32°C for 24h. The best results were obtained from 15h pretreatment with [EMIM][OAc]. The ethanol yield from the untreated spruce chips and powder were 2.7% and 9.7% of the maximum theoretical yield, respectively, whereas pretreatment of these materials with [EMIM][OAc] improved the ethanol yield to 66.8% and 81.5%, respectively.

Suggested Citation

  • Shafiei, Marzieh & Zilouei, Hamid & Zamani, Akram & Taherzadeh, Mohammad J. & Karimi, Keikhosro, 2013. "Enhancement of ethanol production from spruce wood chips by ionic liquid pretreatment," Applied Energy, Elsevier, vol. 102(C), pages 163-169.
    • Handle: RePEc:eee:appene:v:102:y:2013:i:c:p:163-169
    DOI: 10.1016/j.apenergy.2012.05.060
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    References listed on IDEAS

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    1. Liu, Chun-Zhao & Wang, Feng & Stiles, Amanda R. & Guo, Chen, 2012. "Ionic liquids for biofuel production: Opportunities and challenges," Applied Energy, Elsevier, vol. 92(C), pages 406-414.
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