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Long-Term Thermal Cycling Test and Heat-Charging Kinetics of Fe-Substituted Mn 2 O 3 for Next-Generation Concentrated Solar Power Using Thermochemical Energy Storage at High Temperatures

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  • Nobuyuki Gokon

    (Program of Chemistry & Chemical Engineering, Faculty of Engineering, Niigata University, 8050 Ikarashi 2-Nocho, Niigata 950-2181, Japan
    Graduate School of Science and Technology, Niigata University, 8050 Ikarashi 2-Nocho, Niigata 950-2181, Japan)

  • Kosuke Hayashi

    (Graduate School of Science and Technology, Niigata University, 8050 Ikarashi 2-Nocho, Niigata 950-2181, Japan)

  • Hiroki Sawaguri

    (Graduate School of Science and Technology, Niigata University, 8050 Ikarashi 2-Nocho, Niigata 950-2181, Japan)

  • Fumiya Ohashi

    (Graduate School of Science and Technology, Niigata University, 8050 Ikarashi 2-Nocho, Niigata 950-2181, Japan)

Abstract

We studied the performance in terms of the long-term cyclic thermal storage and heat-charging kinetics of Fe-substituted manganese oxide for use in thermochemical energy storage at temperatures exceeding 550 °C in a next-generation concentrated solar power system in which a gas stream containing oxygen is used for reversible thermochemical processes. The Fe-substituted Mn 2 O 3 was evaluated from the viewpoint of its microstructural characteristics, thermodynamic phase transitions, and long-term cycling stability. A kinetic analysis of the heat-charging mode was performed at different heating rates to formulate the kinetic equation and describe the reaction mechanism by determining the appropriate reaction model. Finally, the kinetics data for the sample obtained after the long-term cycling test were compared and evaluated with those of the as-prepared sample and kinetic literature data tested under different conditions. For the long-term cycled sample, the Avrami–Erofeev reaction model (An) with n = 2 describes the behavior of the first part of the charging mode, whereas the contracting area (R2) reaction model best fits the last half of the charging mode. For the as-prepared sample, except for the early stage of the charging mode (fractional conversion < 0.2), the contracting volume (R3) reaction model fits the charging mode over a fractional conversion range of 0.2–1.0 and the first-order (F1) reaction model fits in the fractional conversion range of 0.4–1.0. The predicted kinetic equations for both the samples were in good agreement with the experimental kinetic data.

Suggested Citation

  • Nobuyuki Gokon & Kosuke Hayashi & Hiroki Sawaguri & Fumiya Ohashi, 2022. "Long-Term Thermal Cycling Test and Heat-Charging Kinetics of Fe-Substituted Mn 2 O 3 for Next-Generation Concentrated Solar Power Using Thermochemical Energy Storage at High Temperatures," Energies, MDPI, vol. 15(13), pages 1-23, June.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:13:p:4812-:d:852989
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    1. Arce, Pablo & Medrano, Marc & Gil, Antoni & Oró, Eduard & Cabeza, Luisa F., 2011. "Overview of thermal energy storage (TES) potential energy savings and climate change mitigation in Spain and Europe," Applied Energy, Elsevier, vol. 88(8), pages 2764-2774, August.
    2. Sánchez Jiménez, Pedro E. & Perejón, Antonio & Benítez Guerrero, Mónica & Valverde, José M. & Ortiz, Carlos & Pérez Maqueda, Luis A., 2019. "High-performance and low-cost macroporous calcium oxide based materials for thermochemical energy storage in concentrated solar power plants," Applied Energy, Elsevier, vol. 235(C), pages 543-552.
    3. Giglio, Andrea & Lanzini, Andrea & Leone, Pierluigi & Rodríguez García, Margarita M. & Zarza Moya, Eduardo, 2017. "Direct steam generation in parabolic-trough collectors: A review about the technology and a thermo-economic analysis of a hybrid system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 453-473.
    4. Galinsky, Nathan & Mishra, Amit & Zhang, Jia & Li, Fanxing, 2015. "Ca1−xAxMnO3 (A=Sr and Ba) perovskite based oxygen carriers for chemical looping with oxygen uncoupling (CLOU)," Applied Energy, Elsevier, vol. 157(C), pages 358-367.
    5. N'Tsoukpoe, K. Edem & Liu, Hui & Le Pierrès, Nolwenn & Luo, Lingai, 2009. "A review on long-term sorption solar energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(9), pages 2385-2396, December.
    6. Chacartegui, R. & Alovisio, A. & Ortiz, C. & Valverde, J.M. & Verda, V. & Becerra, J.A., 2016. "Thermochemical energy storage of concentrated solar power by integration of the calcium looping process and a CO2 power cycle," Applied Energy, Elsevier, vol. 173(C), pages 589-605.
    7. Albrecht, Kevin J. & Jackson, Gregory S. & Braun, Robert J., 2016. "Thermodynamically consistent modeling of redox-stable perovskite oxides for thermochemical energy conversion and storage," Applied Energy, Elsevier, vol. 165(C), pages 285-296.
    8. Larissa Fedunik-Hofman & Alicia Bayon & Scott W. Donne, 2019. "Kinetics of Solid-Gas Reactions and Their Application to Carbonate Looping Systems," Energies, MDPI, vol. 12(15), pages 1-35, August.
    9. Gokon, Nobuyuki & Yawata, Takehiro & Bellan, Selvan & Kodama, Tatsuya & Cho, Hyun-Seok, 2019. "Thermochemical behavior of perovskite oxides based on LaxSr1-x(Mn, Fe, Co)O3-δ and BaySr1-yCoO3-δ redox system for thermochemical energy storage at high temperatures," Energy, Elsevier, vol. 171(C), pages 971-980.
    10. Kearney, D. & Kelly, B. & Herrmann, U. & Cable, R. & Pacheco, J. & Mahoney, R. & Price, H. & Blake, D. & Nava, P. & Potrovitza, N., 2004. "Engineering aspects of a molten salt heat transfer fluid in a trough solar field," Energy, Elsevier, vol. 29(5), pages 861-870.
    11. Gil, Antoni & Medrano, Marc & Martorell, Ingrid & Lázaro, Ana & Dolado, Pablo & Zalba, Belén & Cabeza, Luisa F., 2010. "State of the art on high temperature thermal energy storage for power generation. Part 1--Concepts, materials and modellization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 31-55, January.
    12. Fernández, A.G. & Ushak, S. & Galleguillos, H. & Pérez, F.J., 2014. "Development of new molten salts with LiNO3 and Ca(NO3)2 for energy storage in CSP plants," Applied Energy, Elsevier, vol. 119(C), pages 131-140.
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