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Influence of phosphorus based additives on nitrogen and sulfur pollutants emissions during densified biochar combustion

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  • Wang, Qian
  • Cao, Qiankun
  • Wang, Rui
  • Wang, Peifu
  • Zhao, Yanhua
  • Li, Shijie
  • Han, Feifei

Abstract

Biomass is a carbon neutral fuel and can effectively replace fossil fuels. However, its large scale application is limited by disadvantages such as low calorific value, low energy density and high alkali content. Densification, pyrolysis and adding additives are available methods to upgrade biomass fuels. Nevertheless, emission rules of nitrogen and sulfur oxides in combustion of densified biochar need to be clarified. This paper focuses on the emission and transformation mechanisms of nitrogen and sulfur pollutants during pyrolysis and combustion of biomass with phosphorus based additives by means of thermodynamic calculation and experimental research. The addition of additives promoted the emissions of H2S, COS and NH3 during pyrolysis, so the treatment of H2S and COS needs to be considered particularly. During combustion of densified biochar at 1000 °C, increased pyrolysis temperature accelerated SO2 emissions, while it had no obvious influence on NO emissions. NH4H2PO4 accelerated organic sulfur release, NH4H2PO4 and Ca(H2PO4)2 slightly reduced the emission of NO. The maximum values of NO and SO2 release rates were about 2.81 and 1.55 g/kg, respectively, which were lower than those of most typical fuels. The upgraded densified biochars have benefits such as high calorific value, low melting point and low pollutant emission.

Suggested Citation

  • Wang, Qian & Cao, Qiankun & Wang, Rui & Wang, Peifu & Zhao, Yanhua & Li, Shijie & Han, Feifei, 2023. "Influence of phosphorus based additives on nitrogen and sulfur pollutants emissions during densified biochar combustion," Energy, Elsevier, vol. 275(C).
    • Handle: RePEc:eee:energy:v:275:y:2023:i:c:s0360544223008368
    DOI: 10.1016/j.energy.2023.127442
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    1. Yao, Xiwen & Zhao, Zhicheng & Li, Jishuo & Zhang, Bohan & Zhou, Haodong & Xu, Kaili, 2020. "Experimental investigation of physicochemical and slagging characteristics of inorganic constituents in ash residues from gasification of different herbaceous biomass," Energy, Elsevier, vol. 198(C).
    2. Dai, Leilei & Wang, Yunpu & Liu, Yuhuan & Ruan, Roger & He, Chao & Yu, Zhenting & Jiang, Lin & Zeng, Zihong & Tian, Xiaojie, 2019. "Integrated process of lignocellulosic biomass torrefaction and pyrolysis for upgrading bio-oil production: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 20-36.
    3. Mian, Inamullah & Li, Xian & Dacres, Omar D. & Wang, Jianjiang & Wei, Bo & Jian, Yiming & Zhong, Mei & Liu, Jingmei & Ma, Fengyun & Rahman, Noor, 2020. "Combustion kinetics and mechanism of biomass pellet," Energy, Elsevier, vol. 205(C).
    4. Naik, S.N. & Goud, Vaibhav V. & Rout, Prasant K. & Dalai, Ajay K., 2010. "Production of first and second generation biofuels: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 578-597, February.
    5. Lasek, Janusz A. & Kopczyński, Marcin & Janusz, Marcin & Iluk, Andrzej & Zuwała, Jarosław, 2017. "Combustion properties of torrefied biomass obtained from flue gas-enhanced reactor," Energy, Elsevier, vol. 119(C), pages 362-368.
    6. Cheng, Wei & Zhu, Youjian & Shao, Jing’ai & Zhang, Wennan & Wu, Guihao & Jiang, Hao & Hu, Junhao & Huang, Zhen & Yang, Haiping & Chen, Hanping, 2021. "Mitigation of ultrafine particulate matter emission from agricultural biomass pellet combustion by the additive of phosphoric acid modified kaolin," Renewable Energy, Elsevier, vol. 172(C), pages 177-187.
    7. Tran, Khanh-Quang & Luo, Xun & Seisenbaeva, Gulaim & Jirjis, Raida, 2013. "Stump torrefaction for bioenergy application," Applied Energy, Elsevier, vol. 112(C), pages 539-546.
    8. Zhao, Bingtao & Su, Yaxin & Liu, Dunyu & Zhang, Hang & Liu, Wang & Cui, Guomin, 2016. "SO2/NOx emissions and ash formation from algae biomass combustion: Process characteristics and mechanisms," Energy, Elsevier, vol. 113(C), pages 821-830.
    9. Jianhui Qi & Haopeng Li & Qian Wang & Kuihua Han, 2021. "Combustion Characteristics, Kinetics, SO 2 and NO Release of Low-Grade Biomass Materials and Briquettes," Energies, MDPI, vol. 14(9), pages 1-13, May.
    10. Wang, Qian & Han, Kuihua & Wang, Peifu & Li, Shijie & Zhang, Mingyang, 2020. "Influence of additive on ash and combustion characteristics during biomass combustion under O2/CO2 atmosphere," Energy, Elsevier, vol. 195(C).
    11. Ghiasi, Bahman & Kumar, Linoj & Furubayashi, Takaaki & Lim, C. Jim & Bi, Xiaotao & Kim, Chang Soo & Sokhansanj, Shahab, 2014. "Densified biocoal from woodchips: Is it better to do torrefaction before or after densification?," Applied Energy, Elsevier, vol. 134(C), pages 133-142.
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