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Effect of Additives on the Sorption Kinetics of a Silica Gel Bed in Adsorption Chiller

Author

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  • Karol Sztekler

    (Faculty of Energy and Fuels, AGH University of Science and Technology, Mickiewicza 30, 30-059 Krakow, Poland)

  • Wojciech Kalawa

    (Faculty of Energy and Fuels, AGH University of Science and Technology, Mickiewicza 30, 30-059 Krakow, Poland)

  • Łukasz Mika

    (Faculty of Energy and Fuels, AGH University of Science and Technology, Mickiewicza 30, 30-059 Krakow, Poland)

  • Agata Mlonka-Medrala

    (Faculty of Energy and Fuels, AGH University of Science and Technology, Mickiewicza 30, 30-059 Krakow, Poland)

  • Marcin Sowa

    (Faculty of Energy and Fuels, AGH University of Science and Technology, Mickiewicza 30, 30-059 Krakow, Poland)

  • Wojciech Nowak

    (Faculty of Energy and Fuels, AGH University of Science and Technology, Mickiewicza 30, 30-059 Krakow, Poland)

Abstract

The article presents experimental results of the metal-based and carbon nanotube additives influence on sorption kinetics of a silica-gel-based adsorption bed in an adsorption chiller. The purpose of the doping is to improve the efficiency of sorption processes within the bed by use of metallic and non-metallic additives characterized by higher thermal diffusivity than basic adsorption material. The higher the thermal conductivity of the bed, the faster the sorption processes take place, which directly translates into greater efficiency of the refrigerator. In this study, sorption kinetics of pure silica gel sorbent doped with a given amount of aluminum (Al) and copper (Cu) powders and carbon nanotubes (CNT) were analyzed. The tests were performed on DVS Dynamic Gravimetric Vapor Sorption System apparatus used for dynamic vapor sorption measurements. A decrease in the amount of adsorbed water was observed with an increase in the mass share of the additives in the performed studies. Experimental results show that, CNTs seems to be the most promising additive as the sorption process time was reduced with the smallest decrease in water uptake. Any significant reduction of adsorption time was noted in case of the Al addition. Whereas, in case of Cu doping, delamination of the mixture was observed.

Suggested Citation

  • Karol Sztekler & Wojciech Kalawa & Łukasz Mika & Agata Mlonka-Medrala & Marcin Sowa & Wojciech Nowak, 2021. "Effect of Additives on the Sorption Kinetics of a Silica Gel Bed in Adsorption Chiller," Energies, MDPI, vol. 14(4), pages 1-13, February.
  • Handle: RePEc:gam:jeners:v:14:y:2021:i:4:p:1083-:d:501712
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    References listed on IDEAS

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    Cited by:

    1. Marcin Sosnowski & Jaroslaw Krzywanski & Norbert Skoczylas, 2022. "Adsorption Desalination and Cooling Systems: Advances in Design, Modeling and Performance," Energies, MDPI, vol. 15(11), pages 1-6, May.
    2. Wojciech Kalawa & Karol Sztekler & Agata Mlonka-Mędrala & Ewelina Radomska & Wojciech Nowak & Łukasz Mika & Tomasz Bujok & Piotr Boruta, 2023. "Simulation Analysis of Mechanical Fluidized Bed in Adsorption Chillers," Energies, MDPI, vol. 16(15), pages 1-22, August.
    3. Karol Sztekler & Agata Mlonka-Mędrala & Nezar H. Khdary & Wojciech Kalawa & Wojciech Nowak & Łukasz Mika, 2022. "Possibility of Advanced Modified-Silica-Based Porous Materials Utilisation in Water Adsorption Processes—A Comparative Study," Energies, MDPI, vol. 15(1), pages 1-15, January.
    4. Karol Sztekler, 2021. "Optimisation of Operation of Adsorption Chiller with Desalination Function," Energies, MDPI, vol. 14(9), pages 1-20, May.
    5. Karol Sztekler & Tomasz Siwek & Wojciech Kalawa & Lukasz Lis & Lukasz Mika & Ewelina Radomska & Wojciech Nowak, 2021. "CFD Analysis of Elements of an Adsorption Chiller with Desalination Function," Energies, MDPI, vol. 14(22), pages 1-19, November.
    6. Karol Sztekler & Wojciech Kalawa & Łukasz Mika & Marcin Sowa, 2021. "Effect of Metal Additives in the Bed on the Performance Parameters of an Adsorption Chiller with Desalination Function," Energies, MDPI, vol. 14(21), pages 1-27, November.
    7. Lukasz Lasek & Anna Zylka & Jaroslaw Krzywanski & Dorian Skrobek & Karol Sztekler & Wojciech Nowak, 2023. "Review of Fluidized Bed Technology Application for Adsorption Cooling and Desalination Systems," Energies, MDPI, vol. 16(21), pages 1-21, October.
    8. Marcin Sowa & Karol Sztekler & Agata Mlonka-Mędrala & Łukasz Mika, 2023. "An Overview of Developments In Silica Gel Matrix Composite Sorbents for Adsorption Chillers with Desalination Function," Energies, MDPI, vol. 16(15), pages 1-34, August.
    9. Małgorzata Sieradzka & Agata Mlonka-Mędrala & Izabela Kalemba-Rec & Markus Reinmöller & Felix Küster & Wojciech Kalawa & Aneta Magdziarz, 2022. "Evaluation of Physical and Chemical Properties of Residue from Gasification of Biomass Wastes," Energies, MDPI, vol. 15(10), pages 1-19, May.
    10. Karol Sztekler & Łukasz Mika, 2021. "Increasing the Performance of an Adsorption Chiller Operating in the Water Desalination Mode," Energies, MDPI, vol. 14(22), pages 1-19, November.
    11. Chauhan, P.R. & Kaushik, S.C. & Tyagi, S.K., 2022. "Current status and technological advancements in adsorption refrigeration systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    12. Piotr Boruta & Tomasz Bujok & Łukasz Mika & Karol Sztekler, 2021. "Adsorbents, Working Pairs and Coated Beds for Natural Refrigerants in Adsorption Chillers—State of the Art," Energies, MDPI, vol. 14(15), pages 1-41, August.
    13. Tomasz Bujok & Piotr Boruta & Łukasz Mika & Karol Sztekler, 2021. "Analysis of Designs of Heat Exchangers Used in Adsorption Chillers," Energies, MDPI, vol. 14(23), pages 1-28, December.

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