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Thermodynamic Analysis of the Effect of Green Hydrogen Addition to a Fuel Mixture on the Steam Methane Reforming Process

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  • Robert Kaczmarczyk

    (Department of Fundamental Research in Energy Engineering, Faculty of Energy and Fuels, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Krakow, Poland)

Abstract

Steam methane (CH 4 –H 2 O) reforming in the presence of a catalyst, usually nickel, is the most common technology for generating synthesis gas as a feedstock in chemical synthesis and a source of pure H 2 and CO. What is essential from the perspective of further gas use is the parameter describing a ratio of equilibrium concentration of hydrogen to carbon monoxide ( H / C = x H 2 / x C O ) . The parameter is determined by operating temperature and the initial ratio of steam concentration to methane S C = x H 2 O 0 / x C H 4 0 . In this paper, the author presents a thermodynamic analysis of the effect of green hydrogen addition to a fuel mixture on the steam methane reforming process of gaseous phase (CH 4 /H 2 )–H 2 O. The thermodynamic analysis of conversion of hydrogen-enriched methane (CH 4 /H 2 )–H 2 O has been performed using parametric equation formalism, allowing for determining the equilibrium composition of the process in progress. A thermodynamic condition of carbon precipitation in methane reforming (CH 4 /H 2 ) with the gaseous phase of H 2 O has been interpreted. The ranges of substrate concentrations creating carbon deposition for temperature T = 1000 K have been determined, based on the technologies used. The results obtained can serve as a model basis for describing the properties of steam reforming of methane and hydrogen mixture (CH 4 /H 2 )–H 2 O.

Suggested Citation

  • Robert Kaczmarczyk, 2021. "Thermodynamic Analysis of the Effect of Green Hydrogen Addition to a Fuel Mixture on the Steam Methane Reforming Process," Energies, MDPI, vol. 14(20), pages 1-14, October.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:20:p:6564-:d:654669
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    References listed on IDEAS

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    1. Agrafiotis, Christos & von Storch, Henrik & Roeb, Martin & Sattler, Christian, 2014. "Solar thermal reforming of methane feedstocks for hydrogen and syngas production—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 656-682.
    2. Robert Kaczmarczyk & Sebastian Gurgul, 2021. "A Thermodynamic Analysis of Heavy Hydrocarbons Reforming for Solid Oxide Fuel Cell Application as a Part of Hybrid Energy Systems," Energies, MDPI, vol. 14(2), pages 1-11, January.
    3. van der Zwaan, B.C.C. & Schoots, K. & Rivera-Tinoco, R. & Verbong, G.P.J., 2011. "The cost of pipelining climate change mitigation: An overview of the economics of CH4, CO2 and H2 transportation," Applied Energy, Elsevier, vol. 88(11), pages 3821-3831.
    4. Marcin Pajak & Grzegorz Brus & Janusz S. Szmyd, 2021. "Catalyst Distribution Optimization Scheme for Effective Green Hydrogen Production from Biogas Reforming," Energies, MDPI, vol. 14(17), pages 1-14, September.
    5. Minutillo, Mariagiovanna & Perna, Alessandra & Sorce, Alessandro, 2020. "Green hydrogen production plants via biogas steam and autothermal reforming processes: energy and exergy analyses," Applied Energy, Elsevier, vol. 277(C).
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    Cited by:

    1. Marcin Pajak & Grzegorz Brus & Shinji Kimijima & Janusz S. Szmyd, 2023. "Enhancing Hydrogen Production from Biogas through Catalyst Rearrangements," Energies, MDPI, vol. 16(10), pages 1-21, May.
    2. Gayatri Udaysinh Ingale & Hyun-Min Kwon & Soohwa Jeong & Dongho Park & Whidong Kim & Byeingryeol Bang & Young-Il Lim & Sung Won Kim & Youn-Bae Kang & Jungsoo Mun & Sunwoo Jun & Uendo Lee, 2022. "Assessment of Greenhouse Gas Emissions from Hydrogen Production Processes: Turquoise Hydrogen vs. Steam Methane Reforming," Energies, MDPI, vol. 15(22), pages 1-20, November.

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