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Cascade Membrane System for Separation of Water and Organics from Liquid By-Products of HTC of the Agricultural Digestate—Evaluation of Performance

Author

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  • Agnieszka Urbanowska

    (Department of Water and Wastewater Treatment Technology, Faculty of Environmental Engineering, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Małgorzata Kabsch-Korbutowicz

    (Department of Water and Wastewater Treatment Technology, Faculty of Environmental Engineering, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Christian Aragon-Briceño

    (Department of Thermal and Fluid Engineering, University of Twente, Postbus 217, 7500 AE Enschede, The Netherlands)

  • Mateusz Wnukowski

    (Department of Energy Conversion Engineering, Faculty of Mechanical and Power Engineering, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Artur Pożarlik

    (Department of Thermal and Fluid Engineering, University of Twente, Postbus 217, 7500 AE Enschede, The Netherlands)

  • Lukasz Niedzwiecki

    (Department of Energy Conversion Engineering, Faculty of Mechanical and Power Engineering, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Marcin Baranowski

    (Department of Energy Conversion Engineering, Faculty of Mechanical and Power Engineering, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Michał Czerep

    (Department of Energy Conversion Engineering, Faculty of Mechanical and Power Engineering, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Przemysław Seruga

    (Department of Bioprocess Engineering, Wroclaw University of Economics, Komandorska 118/120, 53-345 Wrocław, Poland
    Zakład Gospodarowania Odpadami GAĆ Sp. z o.o., Gać 90, 55-200 Oława, Poland)

  • Halina Pawlak-Kruczek

    (Department of Energy Conversion Engineering, Faculty of Mechanical and Power Engineering, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Eduard Bramer

    (Department of Thermal and Fluid Engineering, University of Twente, Postbus 217, 7500 AE Enschede, The Netherlands)

  • Gerrit Brem

    (Department of Thermal and Fluid Engineering, University of Twente, Postbus 217, 7500 AE Enschede, The Netherlands)

Abstract

New regulations aimed at curbing the problem of eutrophication introduce limitations for traditional ways to use the by-product of anaerobic digestion—the digestate. Hydrothermal carbonisation (HTC) can be a viable way to valorise the digestate in an energy-efficient manner and at the same time maximise the synergy in terms of recovery of water, nutrients, followed by more efficient use of the remaining carbon. Additionally, hydrothermal treatment is a feasible way to recirculate recalcitrant process residues. Recirculation to anaerobic digestion enables recovery of a significant part of chemical energy lost in HTC by organics dissolved in the liquid effluent. Recirculating back to the HTC process can enhance nutrient recovery by making process water more acidic. However, such an effect of synergy can be exploited to its full extent only when viable separation techniques are applied to separate organic by-products of HTC and water. The results presented in this study show that using cascade membrane systems (microfiltration (MF) → ultrafiltration (UF) → nanofiltration (NF)), using polymeric membranes, can facilitate such separation. The best results were obtained by conducting sequential treatment of the liquid by-product of HTC in the following membrane sequence: MF 0.2 µm → UF PES 10 → NF NPO30P, which allowed reaching COD removal efficiency of almost 60%.

Suggested Citation

  • Agnieszka Urbanowska & Małgorzata Kabsch-Korbutowicz & Christian Aragon-Briceño & Mateusz Wnukowski & Artur Pożarlik & Lukasz Niedzwiecki & Marcin Baranowski & Michał Czerep & Przemysław Seruga & Hali, 2021. "Cascade Membrane System for Separation of Water and Organics from Liquid By-Products of HTC of the Agricultural Digestate—Evaluation of Performance," Energies, MDPI, vol. 14(16), pages 1-18, August.
  • Handle: RePEc:gam:jeners:v:14:y:2021:i:16:p:4752-:d:608650
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