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Production of Fuel-Like Fractions by Fractional Distillation of Bio-Oil from Açaí ( Euterpe oleracea Mart.) Seeds Pyrolysis

Author

Listed:
  • Douglas Alberto Rocha de Castro

    (Graduate Program of Natural Resources Engineering of Amazon, Rua Corrêa N° 1, Campus Profissional-UFPA, Belém 66075-110, Brazil)

  • Haroldo Jorge da Silva Ribeiro

    (Graduate Program of Natural Resources Engineering of Amazon, Rua Corrêa N° 1, Campus Profissional-UFPA, Belém 66075-110, Brazil)

  • Lauro Henrique Hamoy Guerreiro

    (Graduate Program of Chemical Engineering, Rua Corrêa N° 1, Campus Profissional-UFPA, Belém 66075-110, Brazil)

  • Lucas Pinto Bernar

    (Graduate Program of Natural Resources Engineering of Amazon, Rua Corrêa N° 1, Campus Profissional-UFPA, Belém 66075-110, Brazil)

  • Sami Jonatan Bremer

    (Hochschule für Technik und Wirtschaft Berlin, Wilhelminenhofstrasse 75A, 12459 Berlin, Germany)

  • Marcelo Costa Santo

    (Graduate Program of Natural Resources Engineering of Amazon, Rua Corrêa N° 1, Campus Profissional-UFPA, Belém 66075-110, Brazil)

  • Hélio da Silva Almeida

    (Faculty of Sanitary and Environmental Engineering, Rua Corrêa N° 1, Campus Profissional-UFPA, Belém 66075-900, Brazil
    Graduate Program of Civil Engineering, Rua Corrêa N° 1, Campus Profissional-UFPA, Belém 66075-110, Brazil)

  • Sergio Duvoisin

    (Faculty of Chemical Engineering-UEA, Avenida Darcy Vargas N°. 1200, Manaus 69050-020, Brazil)

  • Luiz Eduardo Pizarro Borges

    (Laboratory of Catalyst Preparation and Catalytic Cracking, Section of Chemical Engineering-IME, Praça General Tibúrcio No. 80, Rio de Janeiro 22290-270, Brazil)

  • Nélio Teixeira Machado

    (Graduate Program of Natural Resources Engineering of Amazon, Rua Corrêa N° 1, Campus Profissional-UFPA, Belém 66075-110, Brazil
    Faculty of Sanitary and Environmental Engineering, Rua Corrêa N° 1, Campus Profissional-UFPA, Belém 66075-900, Brazil)

Abstract

This work investigates the effect of production scales (laboratory, bench, and pilot) by pyrolysis of Açaí ( Euterpe oleracea Mart.) seeds at 450 °C and 1.0 atmosphere, on the yields of reaction products and acid value of bio-oils. The experiments were carried out in batch mode using a laboratory scale reactor of 143 mL, a bench scale reactor of 1.5 L, and a pilot scale reactor of 143 L (≈1:10:1000). The bio-oil was obtained in pilot scale, fractionated by distillation to produce biofuel-like fractions. The distillation of bio-oil was carried out in a laboratory column. The physical-chemistry properties (density, kinematic viscosity, acid value, and refractive index) of bio-oils and distillation fractions were determined. The qualitative analysis was determined by FT-IR and the chemical composition by GC-MS. The pyrolysis showed bio-oil yields from 4.37 to 13.09 (wt.%), decreasing with reactor volume. The acid value of bio-oils varied from 68.31 to 70.26 mg KOH/g. The distillation of bio-oil produced gasoline, light kerosene, and kerosene-like fuel fractions, and the yields were 16.16, 19.56, and 41.89 (wt.%), respectively. The physical-chemistry properties of distillation fractions increase with temperature. The FT-IR analysis of bio-oils and distillation fractions identified the presence of functional groups characteristic of hydrocarbons (alkenes, alkanes, aromatics, and aromatics rings) and oxygenates (carboxylic acids, ketones, esters, ethers, alcohols, phenols). The GC-MS identified 48.24 (area.%) hydrocarbons and 51.76 (area.%) oxygenates in the bio-oil produced in bench scale and 21.52 (area.%) hydrocarbons and 78.48 (area.%) oxygenates in the bio-oil produced in pilot scale. The gasoline-like fraction was composed by 64.0 (area.%) hydrocarbons and 36.0 (area.%) oxygenates, light kerosene-like fraction by 66.67 (area.%) hydrocarbons and 33.33 (area.%) oxygenates, and kerosene-like fraction by 19.87 (area.%) hydrocarbons and 81.13 (area.%) oxygenates.

Suggested Citation

  • Douglas Alberto Rocha de Castro & Haroldo Jorge da Silva Ribeiro & Lauro Henrique Hamoy Guerreiro & Lucas Pinto Bernar & Sami Jonatan Bremer & Marcelo Costa Santo & Hélio da Silva Almeida & Sergio Duv, 2021. "Production of Fuel-Like Fractions by Fractional Distillation of Bio-Oil from Açaí ( Euterpe oleracea Mart.) Seeds Pyrolysis," Energies, MDPI, vol. 14(13), pages 1-27, June.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:13:p:3713-:d:579215
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    References listed on IDEAS

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    Cited by:

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    2. Fernanda Paula da Costa Assunção & Diogo Oliveira Pereira & Jéssica Cristina Conte da Silva & Jorge Fernando Hungria Ferreira & Kelly Christina Alves Bezerra & Lucas Pinto Bernar & Caio Campos Ferreir, 2022. "A Systematic Approach to Thermochemical Treatment of Municipal Household Solid Waste into Valuable Products: Analysis of Routes, Gravimetric Analysis, Pre-Treatment of Solid Mixtures, Thermochemical P," Energies, MDPI, vol. 15(21), pages 1-30, October.
    3. Lucas Pinto Bernar & Caio Campos Ferreira & Augusto Fernando de Freitas Costa & Haroldo Jorge da Silva Ribeiro & Wenderson Gomes dos Santos & Lia Martins Pereira & Anderson Mathias Pereira & Nathalia , 2022. "Catalytic Upgrading of Residual Fat Pyrolysis Vapors over Activated Carbon Pellets into Hydrocarbons-like Fuels in a Two-Stage Reactor: Analysis of Hydrocarbons Composition and Physical-Chemistry Prop," Energies, MDPI, vol. 15(13), pages 1-26, June.
    4. Anderson Rocha Amaral & Lucas Pinto Bernar & Caio Campos Ferreira & Romero Moreira de Oliveira & Anderson Mathias Pereira & Lia Martins Pereira & Marcelo Costa Santos & Fernanda Paula da Costa Assunçã, 2022. "Economic Feasibility Assessment of the Thermal Catalytic Process of Wastes: Açaí Seeds ( Euterpe oleracea ) and Scum from Grease Traps," Energies, MDPI, vol. 15(20), pages 1-23, October.
    5. Caio Campos Ferreira & Lucas Pinto Bernar & Augusto Fernando de Freitas Costa & Haroldo Jorge da Silva Ribeiro & Marcelo Costa Santos & Nathalia Lobato Moraes & Yasmin Santos Costa & Ana Cláudia Fonse, 2022. "Improving Fuel Properties and Hydrocarbon Content from Residual Fat Pyrolysis Vapors over Activated Red Mud Pellets in Two-Stage Reactor: Optimization of Reaction Time and Catalyst Content," Energies, MDPI, vol. 15(15), pages 1-33, August.

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