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Pyrolysis characteristics of bio-oil fractions separated by molecular distillation

Author

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  • Guo, Xiujuan
  • Wang, Shurong
  • Guo, Zuogang
  • Liu, Qian
  • Luo, Zhongyang
  • Cen, Kefa

Abstract

Molecular distillation was used to separate bio-oil into a light fraction, a middle fraction and a heavy fraction. The chemical composition of the three fractions and the crude bio-oil was analyzed by gas chromatography coupled with mass spectrometry (GC-MS). The diversity of the components reflected the complexity of the bio-oil and the necessity for fractionation. The pyrolysis characteristics of the bio-oil fractions were determined with a thermogravimetric analyzer coupled with Fourier transform infrared spectroscopy (TG-FTIR). The weight loss of components was in agreement with the chemical composition. The light fraction evaporated fastest with the formation of water, CO2, hydrocarbons and alcohols. The heavy fraction had the slowest rate of decomposition and the highest char residue yield due to the presence of phenols and saccharides, and the pyrolysis products included CO2 and alcohols or phenols, which was similar to the middle fraction except the formation of water and formic acid. The release of CO or methane, evidence of a secondary reaction, began at ~450 °C in the pyrolysis of the light and middle fractions.

Suggested Citation

  • Guo, Xiujuan & Wang, Shurong & Guo, Zuogang & Liu, Qian & Luo, Zhongyang & Cen, Kefa, 2010. "Pyrolysis characteristics of bio-oil fractions separated by molecular distillation," Applied Energy, Elsevier, vol. 87(9), pages 2892-2898, September.
    • Handle: RePEc:eee:appene:v:87:y:2010:i:9:p:2892-2898
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    2. Oh, Seung-Jin & Choi, Gyung-Goo & Kim, Joo-Sik, 2016. "Characteristics of bio-oil from the pyrolysis of palm kernel shell in a newly developed two-stage pyrolyzer," Energy, Elsevier, vol. 113(C), pages 108-115.
    3. Ribeiro, Luiz Augusto Badan & Martins, Robson Cristiano & Mesa-Pérez, Juan Miguel & Bizzo, Waldir Antonio, 2019. "Study of bio-oil properties and ageing through fractionation and ternary mixtures with the heavy fraction as the main component," Energy, Elsevier, vol. 169(C), pages 344-355.
    4. Liu, Yang & Ran, Chunmei & Siddiqui, Azka R. & Mao, Xiao & Kang, Qinhao & Fu, Jie & Deng, Zeyu & Song, Yongmeng & Jiang, Zhihui & Zhang, Tianhao & Ao, Wenya & Dai, Jianjun, 2018. "Pyrolysis of textile dyeing sludge in fluidized bed: Characterization and analysis of pyrolysis products," Energy, Elsevier, vol. 165(PA), pages 720-730.
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    7. Toscano Miranda, Nahieh & Lopes Motta, Ingrid & Maciel Filho, Rubens & Wolf Maciel, Maria Regina, 2021. "Sugarcane bagasse pyrolysis: A review of operating conditions and products properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    8. Atadashi, I.M. & Aroua, M.K. & Aziz, A.R. Abdul & Sulaiman, N.M.N., 2011. "Refining technologies for the purification of crude biodiesel," Applied Energy, Elsevier, vol. 88(12), pages 4239-4251.
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    14. Zhang, Qing & Wang, Tiejun & Li, Bing & Jiang, Ting & Ma, Longlong & Zhang, Xinghua & Liu, Qiying, 2012. "Aqueous phase reforming of sorbitol to bio-gasoline over Ni/HZSM-5 catalysts," Applied Energy, Elsevier, vol. 97(C), pages 509-513.
    15. Douglas Alberto Rocha de Castro & Haroldo Jorge da Silva Ribeiro & Lauro Henrique Hamoy Guerreiro & Lucas Pinto Bernar & Sami Jonatan Bremer & Marcelo Costa Santo & Hélio da Silva Almeida & Sergio Duv, 2021. "Production of Fuel-Like Fractions by Fractional Distillation of Bio-Oil from Açaí ( Euterpe oleracea Mart.) Seeds Pyrolysis," Energies, MDPI, vol. 14(13), pages 1-27, June.
    16. Zhang, Xing & Wang, Kaige & Chen, Junhao & Zhu, Lingjun & Wang, Shurong, 2020. "Mild hydrogenation of bio-oil and its derived phenolic monomers over Pt–Ni bimetal-based catalysts," Applied Energy, Elsevier, vol. 275(C).
    17. Rozzeta Dolah & Rohit Karnik & Halimaton Hamdan, 2021. "A Comprehensive Review on Biofuels from Oil Palm Empty Bunch (EFB): Current Status, Potential, Barriers and Way Forward," Sustainability, MDPI, vol. 13(18), pages 1-29, September.
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    19. Feng, Junfeng & Hse, Chung-yun & Wang, Kui & Yang, Zhongzhi & Jiang, Jianchun & Xu, Junming, 2017. "Directional liquefaction of biomass for phenolic compounds and in situ hydrodeoxygenation upgrading of phenolics using bifunctional catalysts," Energy, Elsevier, vol. 135(C), pages 1-13.

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