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Pretreatment of bio-oil followed by upgrading via esterification to boiler fuel

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  • Tanneru, Sathish K.
  • Parapati, Divya R.
  • Steele, Philip H.

Abstract

Bio-oils produced from fast pyrolysis of renewable energy feedstocks are chemically complex organic liquids that contain over 200 different organic compounds. Many of these compounds are oxygenates which result in 40–45% oxygen content in the bio-oils. Due to this high oxygen content bio-oils have numerous negative properties that include low heating value, high acidity, high water content and variable viscosity. It is universally agreed that for production of a viable fuel pyrolysis bio-oils must be upgraded. Esterification is a viable means to produce a boiler fuel but maximum heating energies remain rather low and amount of alcohol usually added is uneconomic. In this study we tested oxidative pretreatment prior to esterification as a means to both increase heating energy and decrease the amount of alcohol required. The most effective oxidative pretreatment was with application of a combined ozone/H2O2 treatment. The esterification of the ozone/H2O2 pretreated product produced a boiler fuel with improved yield and better physical/chemical properties compared to direct esterification of bio-oil. As compared to the product from direct esterification of bio-oil the esterified ozone/H2O2 pretreated bio-oil provided a 23% increased boiler fuel yield of 48 wt%; higher heating value was 5.7% higher at 35.3 MJ/kg.

Suggested Citation

  • Tanneru, Sathish K. & Parapati, Divya R. & Steele, Philip H., 2014. "Pretreatment of bio-oil followed by upgrading via esterification to boiler fuel," Energy, Elsevier, vol. 73(C), pages 214-220.
    • Handle: RePEc:eee:energy:v:73:y:2014:i:c:p:214-220
    DOI: 10.1016/j.energy.2014.06.039
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    References listed on IDEAS

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    1. Bridgwater, A. V. & Peacocke, G. V. C., 2000. "Fast pyrolysis processes for biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 4(1), pages 1-73, March.
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    1. Zhang, Zhaoxia & Bi, Peiyan & Jiang, Peiwen & Fan, Minghui & Deng, Shumei & Zhai, Qi & Li, Quanxin, 2015. "Production of gasoline fraction from bio-oil under atmospheric conditions by an integrated catalytic transformation process," Energy, Elsevier, vol. 90(P2), pages 1922-1930.
    2. Ribeiro, Luiz Augusto Badan & Martins, Robson Cristiano & Mesa-Pérez, Juan Miguel & Bizzo, Waldir Antonio, 2019. "Study of bio-oil properties and ageing through fractionation and ternary mixtures with the heavy fraction as the main component," Energy, Elsevier, vol. 169(C), pages 344-355.
    3. Zhang, Xinghua & Chen, Lungang & Kong, Wei & Wang, Tiejun & Zhang, Qi & Long, Jinxing & Xu, Ying & Ma, Longlong, 2015. "Upgrading of bio-oil to boiler fuel by catalytic hydrotreatment and esterification in an efficient process," Energy, Elsevier, vol. 84(C), pages 83-90.
    4. Zhang, Yuan & Wang, Yong & Cui, Hongyou & Zhao, Pingping & Song, Feng & Sun, Xiuyu & Xie, Yujiao & Yi, Weiming & Wang, Lihong, 2018. "Effects of hydrolysis and oxidative hydrolysis pretreatments on upgrading of the water-soluble fraction of bio-oil via decarboxylation," Applied Energy, Elsevier, vol. 226(C), pages 730-742.
    5. Gollakota, Anjani R.K. & Reddy, Madhurima & Subramanyam, Malladi D. & Kishore, Nanda, 2016. "A review on the upgradation techniques of pyrolysis oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 1543-1568.
    6. Douglas Alberto Rocha de Castro & Haroldo Jorge da Silva Ribeiro & Lauro Henrique Hamoy Guerreiro & Lucas Pinto Bernar & Sami Jonatan Bremer & Marcelo Costa Santo & Hélio da Silva Almeida & Sergio Duv, 2021. "Production of Fuel-Like Fractions by Fractional Distillation of Bio-Oil from Açaí ( Euterpe oleracea Mart.) Seeds Pyrolysis," Energies, MDPI, vol. 14(13), pages 1-27, June.

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