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Fabrication of ionic liquid/polymer nanoscale networks by electrospinning and chemical cross-linking and their application in hydrogen generation from the hydrolysis of NaBH4

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  • Chinnappan, Amutha
  • Jadhav, Arvind H.
  • Puguan, John Marc C.
  • Appiah-Ntiamoah, Richard
  • Kim, Hern

Abstract

This study reports the development of a new system of IL (ionic liquid) with metal complex, chemically crosslinked, electrospun nanofibers based on PVDF (poly(vinylidene fluoride)) as a polymer matrix. The nanofibers were fabricated with different amounts of ionic liquid, PEG (polyethylene glycol), and EGDMA (ethylene glycol dimethacrylate) via electrospinning. The obtained nanofiber composites were thermal treated at 135 °C to produce physically bonded structures and chemically cross-linked networks, which were confirmed by SEM (Scanning Electron Microscopy), EDX (Energy Dispersive X-ray Spectrometer) and FT-IR spectra (Fourier transform infrared). The elecrospun PVDF/PEG/EGDMA/IL chemically cross-linked nanofibers were tested for the hydrogen generation from the hydrolysis of sodium borohydride. The nanofiber composites showed high stability and recycling ability in repeated number of runs.

Suggested Citation

  • Chinnappan, Amutha & Jadhav, Arvind H. & Puguan, John Marc C. & Appiah-Ntiamoah, Richard & Kim, Hern, 2015. "Fabrication of ionic liquid/polymer nanoscale networks by electrospinning and chemical cross-linking and their application in hydrogen generation from the hydrolysis of NaBH4," Energy, Elsevier, vol. 79(C), pages 482-488.
    • Handle: RePEc:eee:energy:v:79:y:2015:i:c:p:482-488
    DOI: 10.1016/j.energy.2014.11.041
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    1. Shih, Yu-Jen & Su, Chia-Chi & Huang, Yao-Hui & Lu, Ming-Chun, 2013. "SiO2-supported ferromagnetic catalysts for hydrogen generation from alkaline NaBH4 (sodium borohydride) solution," Energy, Elsevier, vol. 54(C), pages 263-270.
    2. Sahiner, Nurettin & Seven, Fahriye, 2014. "The use of superporous p(AAc (acrylic acid)) cryogels as support for Co and Ni nanoparticle preparation and as reactor in H2 production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 71(C), pages 170-179.
    3. San Martin, J.I. & Zamora, I. & San Martin, J.J. & Aperribay, V. & Torres, E. & Eguia, P., 2010. "Influence of the rated power in the performance of different proton exchange membrane (PEM) fuel cells," Energy, Elsevier, vol. 35(5), pages 1898-1907.
    4. Huang, Zhen-Ming & Su, Ay & Liu, Ying-Chieh, 2013. "Hydrogen generator system using Ru catalyst for PEMFC (proton exchange membrane fuel cell) applications," Energy, Elsevier, vol. 51(C), pages 230-236.
    5. Li, Fang & Arthur, Ernest Evans & La, Dahye & Li, Qiming & Kim, Hern, 2014. "Immobilization of CoCl2 (cobalt chloride) on PAN (polyacrylonitrile) composite nanofiber mesh filled with carbon nanotubes for hydrogen production from hydrolysis of NaBH4 (sodium borohydride)," Energy, Elsevier, vol. 71(C), pages 32-39.
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    1. Tamboli, Ashif H. & Chaugule, Avinash A. & Sheikh, Faheem A. & Chung, Wook-Jin & Kim, Hern, 2015. "Synthesis and application of CeO2–NiO loaded TiO2 nanofiber as novel catalyst for hydrogen production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 89(C), pages 568-575.
    2. Tamboli, Ashif H. & Jadhav, Amol R. & Chung, Wook-Jin & Kim, Hern, 2015. "Structurally modified cerium doped hydrotalcite-like precursor as efficient catalysts for hydrogen production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 93(P1), pages 955-962.
    3. Helder X. Nunes & Diogo L. Silva & Carmen M. Rangel & Alexandra M. F. R. Pinto, 2021. "Rehydrogenation of Sodium Borates to Close the NaBH 4 -H 2 Cycle: A Review," Energies, MDPI, vol. 14(12), pages 1-28, June.
    4. Shen, Xiaochen & Wang, Qing & Wu, Qingquan & Guo, Siqi & Zhang, Zhengyan & Sun, Ziyang & Liu, Baishu & Wang, Zhibin & Zhao, Bin & Ding, Weiping, 2015. "CoB supported on Ag-activated TiO2 as a highly active catalyst for hydrolysis of alkaline NaBH4 solution," Energy, Elsevier, vol. 90(P1), pages 464-474.
    5. Tomboc, Gracita Raquel M. & Tamboli, Ashif H. & Kim, Hern, 2017. "Synthesis of Co3O4 macrocubes catalyst using novel chitosan/urea template for hydrogen generation from sodium borohydride," Energy, Elsevier, vol. 121(C), pages 238-245.
    6. Cai, Haokun & Liu, Liping & Chen, Qiang & Lu, Ping & Dong, Jian, 2016. "Ni-polymer nanogel hybrid particles: A new strategy for hydrogen production from the hydrolysis of dimethylamine-borane and sodium borohydride," Energy, Elsevier, vol. 99(C), pages 129-135.

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