IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v251y2019ic52.html
   My bibliography  Save this article

Development of a high-storage-density hydrogen generator using solid-state NaBH4 as a hydrogen source for unmanned aerial vehicles

Author

Listed:
  • Kwon, Soon-mo
  • Kim, Myoung Jin
  • Kang, Shinuang
  • Kim, Taegyu

Abstract

A hydrogen generator using solid-state sodium borohydride (NaBH4) as a hydrogen source was proposed as part of a high-energy-density fuel-cell system for unmanned aerial vehicles. In this study, solid-state NaBH4 was used in order to overcome problems of a hydrogen generator using catalytic hydrolysis of NaBH4 aqueous solution such as low hydrogen yield and unstable hydrogen generation due to catalyst degradation. An agent solution, hydrochloric acid, was injected on to the NaBH4 to generate hydrogen. In addition, all of the balance-of-plant systems and components were integrated to develop a lightweight, commercially-viable, high-density hydrogen generator. The developed hydrogen generator was evaluated in terms of stable hydrogen generation and restartability for the entire operation time in order to validate the possibility of commercialization. From the performance evaluation, the gravimetric and volumetric specific energy densities of the hydrogen generator were found to be 739.1 W hr/kg and 272.8 W hr/L, respectively. In addition, the hydrogen storage density was 5.1 wt%, which was 1.44 times higher in comparison of a typical hydrogen generator using NaBH4 aqueous solution.

Suggested Citation

  • Kwon, Soon-mo & Kim, Myoung Jin & Kang, Shinuang & Kim, Taegyu, 2019. "Development of a high-storage-density hydrogen generator using solid-state NaBH4 as a hydrogen source for unmanned aerial vehicles," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    • Handle: RePEc:eee:appene:v:251:y:2019:i:c:52
    DOI: 10.1016/j.apenergy.2019.113331
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261919310050
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2019.113331?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Sim, Ju-hyeong & Kim, Taegyu, 2015. "Accelerated hydrolysis of solid-state NaBH4 by injecting NaHCO3 solution for hydrogen generation," Applied Energy, Elsevier, vol. 160(C), pages 999-1006.
    2. Kim, Taegyu, 2014. "NaBH4 (sodium borohydride) hydrogen generator with a volume-exchange fuel tank for small unmanned aerial vehicles powered by a PEM (proton exchange membrane) fuel cell," Energy, Elsevier, vol. 69(C), pages 721-727.
    3. Kim, Jincheol & Kim, Taegyu, 2015. "Compact PEM fuel cell system combined with all-in-one hydrogen generator using chemical hydride as a hydrogen source," Applied Energy, Elsevier, vol. 160(C), pages 945-953.
    4. Pan, Z.F. & An, L. & Wen, C.Y., 2019. "Recent advances in fuel cells based propulsion systems for unmanned aerial vehicles," Applied Energy, Elsevier, vol. 240(C), pages 473-485.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Helder X. Nunes & Diogo L. Silva & Carmen M. Rangel & Alexandra M. F. R. Pinto, 2021. "Rehydrogenation of Sodium Borates to Close the NaBH 4 -H 2 Cycle: A Review," Energies, MDPI, vol. 14(12), pages 1-28, June.
    2. Zenan Shen & Shaoquan Liu & Wei Zhu & Daoyuan Ren & Qiang Xu & Yu Feng, 2024. "A Review on Key Technologies and Developments of Hydrogen Fuel Cell Multi-Rotor Drones," Energies, MDPI, vol. 17(16), pages 1-36, August.
    3. Park, Kilsu & Kim, Myoung-jin & Kwon, Soon-mo & Kang, Shinuang & Kim, Taegyu, 2023. "Performance evaluation of solid NaBH4-based hydrogen generator for fuel-cell-powered unmanned autonomous systems," Applied Energy, Elsevier, vol. 337(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Park, Kilsu & Kim, Myoung-jin & Kwon, Soon-mo & Kang, Shinuang & Kim, Taegyu, 2023. "Performance evaluation of solid NaBH4-based hydrogen generator for fuel-cell-powered unmanned autonomous systems," Applied Energy, Elsevier, vol. 337(C).
    2. Meng, Kai & Zhou, Haoran & Chen, Ben & Tu, Zhengkai, 2021. "Dynamic current cycles effect on the degradation characteristic of a H2/O2 proton exchange membrane fuel cell," Energy, Elsevier, vol. 224(C).
    3. Stančin, H. & Mikulčić, H. & Wang, X. & Duić, N., 2020. "A review on alternative fuels in future energy system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 128(C).
    4. Zenan Shen & Shaoquan Liu & Wei Zhu & Daoyuan Ren & Qiang Xu & Yu Feng, 2024. "A Review on Key Technologies and Developments of Hydrogen Fuel Cell Multi-Rotor Drones," Energies, MDPI, vol. 17(16), pages 1-36, August.
    5. Nicu Bizon & Mircea Raceanu & Emmanouel Koudoumas & Adriana Marinoiu & Emmanuel Karapidakis & Elena Carcadea, 2020. "Renewable/Fuel Cell Hybrid Power System Operation Using Two Search Controllers of the Optimal Power Needed on the DC Bus," Energies, MDPI, vol. 13(22), pages 1-26, November.
    6. Wang, Yujie & Sun, Zhendong & Chen, Zonghai, 2019. "Energy management strategy for battery/supercapacitor/fuel cell hybrid source vehicles based on finite state machine," Applied Energy, Elsevier, vol. 254(C).
    7. Erika Michela Dematteis & Jussara Barale & Marta Corno & Alessandro Sciullo & Marcello Baricco & Paola Rizzi, 2021. "Solid-State Hydrogen Storage Systems and the Relevance of a Gender Perspective," Energies, MDPI, vol. 14(19), pages 1-26, September.
    8. Cai, Haokun & Liu, Liping & Chen, Qiang & Lu, Ping & Dong, Jian, 2016. "Ni-polymer nanogel hybrid particles: A new strategy for hydrogen production from the hydrolysis of dimethylamine-borane and sodium borohydride," Energy, Elsevier, vol. 99(C), pages 129-135.
    9. Su, Guoqing & Yang, Daijun & Xiao, Qiangfeng & Dai, Haiqin & Zhang, Cunman, 2021. "Effects of vortexes in feed header on air flow distribution of PEMFC stack: CFD simulation and optimization for better uniformity," Renewable Energy, Elsevier, vol. 173(C), pages 498-506.
    10. Lin, Chen & Yan, Xiaohui & Wei, Guanghua & Ke, Changchun & Shen, Shuiyun & Zhang, Junliang, 2019. "Optimization of configurations and cathode operating parameters on liquid-cooled proton exchange membrane fuel cell stacks by orthogonal method," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    11. Wang, Di & Wang, Yuqi & Wang, Feng & Zheng, Shuaishuai & Guan, Sinan & Zheng, Lan & Wu, Le & Yang, Xin & Lv, Ming & Zhang, Zaoxiao, 2022. "Optimal design of disc mini-channel metal hydride reactor with high hydrogen storage efficiency," Applied Energy, Elsevier, vol. 308(C).
    12. Belmonte, N. & Staulo, S. & Fiorot, S. & Luetto, C. & Rizzi, P. & Baricco, M., 2018. "Fuel cell powered octocopter for inspection of mobile cranes: Design, cost analysis and environmental impacts," Applied Energy, Elsevier, vol. 215(C), pages 556-565.
    13. Gupta, Sowmya & Rajhans, Chinmay & Duttagupta, Siddhartha P. & Mitra, Mira, 2021. "Hybrid energy design for lighter than air systems," Renewable Energy, Elsevier, vol. 173(C), pages 781-794.
    14. Bizon, Nicu, 2019. "Fuel saving strategy using real-time switching of the fueling regulators in the proton exchange membrane fuel cell system," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    15. Pan, Z.F. & An, L. & Wen, C.Y., 2019. "Recent advances in fuel cells based propulsion systems for unmanned aerial vehicles," Applied Energy, Elsevier, vol. 240(C), pages 473-485.
    16. Meng, Huanru & Yu, Xianxian & Luo, Xiaobing & Tu, Zhengkai, 2024. "Modelling and operation characteristics of air-cooled PEMFC with metallic bipolar plate used in unmanned aerial vehicle," Energy, Elsevier, vol. 300(C).
    17. Pan, Zhefei & Bi, Yanding & An, Liang, 2019. "Performance characteristics of a passive direct ethylene glycol fuel cell with hydrogen peroxide as oxidant," Applied Energy, Elsevier, vol. 250(C), pages 846-854.
    18. Netskina, O.V. & Komova, O.V. & Simagina, V.I. & Odegova, G.V. & Prosvirin, I.P. & Bulavchenko, O.A., 2016. "Aqueous-alkaline NaBH4 solution: The influence of storage duration of solutions on reduction and activity of cobalt catalysts," Renewable Energy, Elsevier, vol. 99(C), pages 1073-1081.
    19. Pavel Shuhayeu & Aliaksandr Martsinchyk & Katsiaryna Martsinchyk & Jaroslaw Milewski, 2024. "Investigating PEM Fuel Cells as an Alternative Power Source for Electric UAVs: Modeling, Optimization, and Performance Analysis," Energies, MDPI, vol. 17(17), pages 1-15, September.
    20. Cheng, Ming & Luo, Liuxuan & Feng, Yong & Feng, Qilong & Yan, Xiaohui & Shen, Shuiyun & Guo, Yangge & Zhang, Junliang, 2024. "Numerical studies on porous water transport plates applied in PEMFCs under pure oxygen condition," Applied Energy, Elsevier, vol. 362(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:251:y:2019:i:c:52. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.