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Ethanol Electrooxidation at Platinum-Rare Earth (RE = Ce, Sm, Ho, Dy) Binary Alloys

Author

Listed:
  • D.M.F. Santos

    (CeFEMA, Instituto Superior Técnico, Universidade de Lisboa, 1049-001 Lisbon, Portugal)

  • J.R.B. Lourenço

    (CeFEMA, Instituto Superior Técnico, Universidade de Lisboa, 1049-001 Lisbon, Portugal)

  • D. Macciò

    (Dipartimento di Chímica e Chímica Industriale, Universitá di Genova, I-16146 Genova, Italy)

  • A. Saccone

    (Dipartimento di Chímica e Chímica Industriale, Universitá di Genova, I-16146 Genova, Italy)

  • C.A.C. Sequeira

    (CeFEMA, Instituto Superior Técnico, Universidade de Lisboa, 1049-001 Lisbon, Portugal)

  • J.L. Figueiredo

    (Laboratory of Catalysis and Materials, LSRE-LCM, Faculdade de Engenharia, Universidade do Porto, 4200-465 Porto, Portugal)

Abstract

Proton exchange membrane fuel cells and direct alcohol fuel cells have been extensively studied over the last three decades or so. They have emerged as potential systems to power portable applications, providing clean energy, and offering good commercial viability. Ethanol is considered one of the most interesting fuels in this field. Herein, platinum-rare earth (Pt-RE) binary alloys (RE = Ce, Sm, Ho, Dy, nominal composition 50 at.% Pt) were produced and studied as anodes for ethanol oxidation reaction (EOR) in alkaline medium. A Pt-Dy alloy with nominal composition 40 at.% Pt was also tested. Their electrocatalytic performance was evaluated by voltammetric and chronoamperometric measurements in 2 M NaOH solution with different ethanol concentrations (0.2–0.8 M) in the 25–45 °C temperature range. Several EOR kinetic parameters were determined for the Pt-RE alloys, namely the charge transfer and diffusion coefficients, and the number of exchanged electrons. Charge transfer coefficients ranging from 0.60 to 0.69 and n values as high as 0.7 were obtained for the Pt 0.5 Sm 0.5 electrode. The EOR reaction order at the Pt-RE alloys was found to vary between 0.4 and 0.9. The Pt-RE electrodes displayed superior performance for EOR than bare Pt, with Pt 0.5 Sm 0.5 exhibiting the highest electrocatalytic activity. The improved electrocatalytic activity in all of the evaluated Pt-RE binary alloys suggests a strategy for the solution of the existing anode issues due to the structure-sensitive EOR.

Suggested Citation

  • D.M.F. Santos & J.R.B. Lourenço & D. Macciò & A. Saccone & C.A.C. Sequeira & J.L. Figueiredo, 2020. "Ethanol Electrooxidation at Platinum-Rare Earth (RE = Ce, Sm, Ho, Dy) Binary Alloys," Energies, MDPI, vol. 13(7), pages 1-21, April.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:7:p:1658-:d:340721
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    References listed on IDEAS

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    1. Santos, D.M.F. & Šljukić, B. & Sequeira, C.A.C. & Macciò, D. & Saccone, A. & Figueiredo, J.L., 2013. "Electrocatalytic approach for the efficiency increase of electrolytic hydrogen production: Proof-of-concept using platinum--dysprosium alloys," Energy, Elsevier, vol. 50(C), pages 486-492.
    2. Badwal, S.P.S. & Giddey, S. & Kulkarni, A. & Goel, J. & Basu, S., 2015. "Direct ethanol fuel cells for transport and stationary applications – A comprehensive review," Applied Energy, Elsevier, vol. 145(C), pages 80-103.
    3. Eileen Hao Yu & Ulrike Krewer & Keith Scott, 2010. "Principles and Materials Aspects of Direct Alkaline Alcohol Fuel Cells," Energies, MDPI, vol. 3(8), pages 1-30, August.
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