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Novel Ag@C nanocables supported Pd anodes and its implication in energy conversion using direct liquid fuel cells

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  • Bai, Zhengyu
  • Huang, Rumeng
  • Shi, Min
  • Zhang, Qing
  • Yang, Lin
  • Yang, Zongxian
  • Zhang, Jiujun

Abstract

In this work, renewable ethylene glycol (EG) was developed as a potential fuel for direct liquid fuel cells (DLFCs) with Ag@C nanocables by immobilization of Palladium (Pd/Ag@C) anodes for sustainable electric power generation. The results confirm that the obtained nanocable is composed of a silver nanowire as a core and a carbonaceous layer as a shell. According to TEM, the resulting Pd nanoparticles are well-distributed on the surface of the Ag@C, and the mean size of the Pd nanoparticles is 4.4nm. Electrochemical behavior tests indicate that the Pd/Ag@C can achieve a maximum current density of 1027.4mAmg−1Pd based on a half-cell reaction on EG fuel, suggesting that EG is a suitable fuel for DLFCs. It is concluded that the as-prepared Pd/Ag@C would be a potential candidate as an anode in energy conversion using DLFCs. Furthermore, the current study confirmed the practical applicability of EG as a direct fuel with Pd/Ag@C anode applied in DEGFCs may have a great effect on future energy systems.

Suggested Citation

  • Bai, Zhengyu & Huang, Rumeng & Shi, Min & Zhang, Qing & Yang, Lin & Yang, Zongxian & Zhang, Jiujun, 2016. "Novel Ag@C nanocables supported Pd anodes and its implication in energy conversion using direct liquid fuel cells," Applied Energy, Elsevier, vol. 175(C), pages 429-434.
    • Handle: RePEc:eee:appene:v:175:y:2016:i:c:p:429-434
    DOI: 10.1016/j.apenergy.2016.04.033
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    References listed on IDEAS

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    1. Gomes, R.S. & De Bortoli, A.L., 2016. "A three-dimensional mathematical model for the anode of a direct ethanol fuel cell," Applied Energy, Elsevier, vol. 183(C), pages 1292-1301.

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