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A cost-effective and chemically stable electrode binder for alkaline-acid direct ethylene glycol fuel cells

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  • Pan, Zhefei
  • Bi, Yanding
  • An, Liang

Abstract

In preparing direct liquid fuel cell electrodes, an ionomer is necessary, whose functions are not only to bind the discrete catalyst nanoparticles onto the substrate materials to build the porous catalyst layer, but also to construct the triple phase boundaries to provide continuous pathways for reactant delivery. In this work, a cost-effective and chemically stable poly(vinylidene fluoride-co-hexafluoropropylene) electrode binder is adopted and compared with the conventional Nafion and polytetrafluoroethylene in terms of the electrode morphology and the fuel cell performance. It is found that the fuel cell using the poly(vinylidene fluoride-co-hexafluoropropylene)-based electrode exhibits the best performance in terms of an open-circuit voltage of 1.47 V, a maximum current density of 300 mA cm−2, and a peak power density of 120.0 mW cm−2. Comparing to the fuel cell performances fabricated with the conventional Nafion and polytetrafluoroethylene as electrode binder, the peak power density achieved by using the new type of electrode binder shows an improvement of 13.7% and 58.1%, respectively. Poly(vinylidene fluoride-co-hexafluoropropylene) shows the lowest cost of $0.18 kW−1, while polytetrafluoroethylene and Nafion possess the higher cost of $0.80 kW−1 and $145.59 kW−1, respectively. The impressive improvement is attributed to the fact that the poly(vinylidene fluoride-co-hexafluoropropylene)-based electrode has a higher electrochemical surface area due to its intrinsic porous property, enhancing the anodic reaction kinetics. It is found that the best cell performance is achieved with 1.0 M EG and 5.0 M KOH in the anolyte and 1.0 M H2O2 and 4.0 M H2SO4 in the catholyte at 60 °C.

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  • Pan, Zhefei & Bi, Yanding & An, Liang, 2020. "A cost-effective and chemically stable electrode binder for alkaline-acid direct ethylene glycol fuel cells," Applied Energy, Elsevier, vol. 258(C).
    • Handle: RePEc:eee:appene:v:258:y:2020:i:c:s0306261919317477
    DOI: 10.1016/j.apenergy.2019.114060
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    References listed on IDEAS

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    1. An, L. & Zhao, T.S. & Zeng, L., 2013. "Agar chemical hydrogel electrode binder for fuel-electrolyte-fed fuel cells," Applied Energy, Elsevier, vol. 109(C), pages 67-71.
    2. Wu, Qixing & Li, Haiyang & Yuan, Wenxiang & Luo, Zhongkuan & Wang, Fang & Sun, Hongyuan & Zhao, Xuxin & Fu, Huide, 2015. "Performance evaluation of an air-breathing high-temperature proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 160(C), pages 146-152.
    3. Jiang, Jinghui & Li, Yinshi & Liang, Jiarong & Yang, Weiwei & Li, Xianglin, 2019. "Modeling of high-efficient direct methanol fuel cells with order-structured catalyst layer," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    4. Wu, Q.X. & Pan, Z.F. & An, L., 2018. "Recent advances in alkali-doped polybenzimidazole membranes for fuel cell applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 89(C), pages 168-183.
    5. Wu, Q.X. & Zhao, T.S. & Chen, R. & An, L., 2013. "A sandwich structured membrane for direct methanol fuel cells operating with neat methanol," Applied Energy, Elsevier, vol. 106(C), pages 301-306.
    6. Pan, Z.F. & An, L. & Wen, C.Y., 2019. "Recent advances in fuel cells based propulsion systems for unmanned aerial vehicles," Applied Energy, Elsevier, vol. 240(C), pages 473-485.
    7. Munjewar, Seema S. & Thombre, Shashikant B. & Mallick, Ranjan K., 2017. "Approaches to overcome the barrier issues of passive direct methanol fuel cell – Review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1087-1104.
    8. Pan, Zhefei & Bi, Yanding & An, Liang, 2019. "Performance characteristics of a passive direct ethylene glycol fuel cell with hydrogen peroxide as oxidant," Applied Energy, Elsevier, vol. 250(C), pages 846-854.
    9. Badwal, S.P.S. & Giddey, S. & Kulkarni, A. & Goel, J. & Basu, S., 2015. "Direct ethanol fuel cells for transport and stationary applications – A comprehensive review," Applied Energy, Elsevier, vol. 145(C), pages 80-103.
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