IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v13y2020i6p1514-d335801.html
   My bibliography  Save this article

Investigation and Analysis of R463A as an Alternative Refrigerant to R404A with Lower Global Warming Potential

Author

Listed:
  • Piyanut Saengsikhiao

    (Energy Technology Program, Faculty of Engineering, Prince of Songkla University, Songkhla 90112, Thailand)

  • Juntakan Taweekun

    (Department of Mechanical Engineering, Faculty of Engineering, Prince of Songkla University, Songkhla 90112, Thailand)

  • Kittinan Maliwan

    (Department of Mechanical Engineering, Faculty of Engineering, Prince of Songkla University, Songkhla 90112, Thailand)

  • Somchai Sae-ung

    (Department of Mechanical Engineering, Faculty of Engineering, Prince of Songkla University, Songkhla 90112, Thailand)

  • Thanansak Theppaya

    (Department of Mechanical Engineering, Faculty of Engineering, Prince of Songkla University, Songkhla 90112, Thailand)

Abstract

This research presents the development of R463A refrigerant, a nonflammable refrigerant that was retrofitted to replace R404A. R463A is primarily composed of hydrofluorocarbons/hydrocarbons/carbon dioxide (HFCs/HCs/CO 2 ), and has global-warming potential (GWP) of 1494. It is a nonazeotropic mixture of R32 (36%), R125 (30%), R134a (14%), R1234yf (14%), and R744 (6%). R463A is composed of polyol ester oil (POE), and it is classified as a Class A1 incombustible and nontoxic refrigerant. R463A has a higher cooling capacity (Qe) than that of R404A, as it is composed of hydrofluorocarbons (HFCs) R32 and carbon dioxide (CO 2 ) R744, and has lower GWP than that of R404A due to the use of hydrofluoroolefins (HFOs) from R1234yf. The results of this research showed that R463A can be retrofitted to replace R404A due to its composition of POE, Class A1 incombustibility, and lower toxicity. The properties of R463A and R404A, as analyzed using national institute of standards and technology (NIST) reference fluid thermodynamic and transport properties database (REFPROP) software and NIST vapor compression cycle model accounting for refrigerant thermodynamic and transport properties (CYCLE_D-HX) software, are in accordance with the CAN/ANSI/AHRI540 standards of the Air-Conditioning, Heating, and Refrigeration Institute (AHRI). The normal boiling point of R463A was found to be higher than that of R404A by 23%, with a higher cooling capacity and a 63% lower GWP value than that of R404A. The critical pressure and temperature of R463A were found to be higher than those of R404A; it can be used in a high-ambient-temperature environment, has higher refrigerant and heat-rejection effects, and has lower GWP than that of R404A by 52% due to the HFOs from the R1234yf component. The cooling coefficient of performance (COPc) of R463A was found to be higher than that of R404A by 10% under low-temperature applications. R463A is another refrigerant option that is composed of 7% carbon dioxide (CO 2 ), and is consistent with the evolution of fourth-generation refrigerants that contain a mixture of HFCs, HFOs, HCs, and natural refrigerants, which are required to produce a low-GWP, zero-ozone-depletion-potential (ODP), high-capacity, low-operating-pressure, and nontoxic refrigerant.

Suggested Citation

  • Piyanut Saengsikhiao & Juntakan Taweekun & Kittinan Maliwan & Somchai Sae-ung & Thanansak Theppaya, 2020. "Investigation and Analysis of R463A as an Alternative Refrigerant to R404A with Lower Global Warming Potential," Energies, MDPI, vol. 13(6), pages 1-19, March.
  • Handle: RePEc:gam:jeners:v:13:y:2020:i:6:p:1514-:d:335801
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/13/6/1514/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/13/6/1514/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. La Rocca, Vincenzo & Panno, Giuseppe, 2011. "Experimental performance evaluation of a vapour compression refrigerating plant when replacing R22 with alternative refrigerants," Applied Energy, Elsevier, vol. 88(8), pages 2809-2815, August.
    2. Makhnatch, Pavel & Mota-Babiloni, Adrián & López-Belchí, Alejandro & Khodabandeh, Rahmatollah, 2019. "R450A and R513A as lower GWP mixtures for high ambient temperature countries: Experimental comparison with R134a," Energy, Elsevier, vol. 166(C), pages 223-235.
    3. Abas, Naeem & Kalair, Ali Raza & Khan, Nasrullah & Haider, Aun & Saleem, Zahid & Saleem, Muhammad Shoaib, 2018. "Natural and synthetic refrigerants, global warming: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 557-569.
    4. Mota-Babiloni, Adrián & Navarro-Esbrí, Joaquín & Makhnatch, Pavel & Molés, Francisco, 2017. "Refrigerant R32 as lower GWP working fluid in residential air conditioning systems in Europe and the USA," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1031-1042.
    5. Yang, Min-Hsiung & Yeh, Rong-Hua & Hung, Tzu-Chen, 2017. "Thermo-economic analysis of the transcritical organic Rankine cycle using R1234yf/R32 mixtures as the working fluids for lower-grade waste heat recovery," Energy, Elsevier, vol. 140(P1), pages 818-836.
    6. Aprea, Ciro & Maiorino, Angelo, 2011. "An experimental investigation of the global environmental impact of the R22 retrofit with R422D," Energy, Elsevier, vol. 36(2), pages 1161-1170.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Adriano da S. Marques & Monica Carvalho & Álvaro A. V. Ochoa & Ronelly J. Souza & Carlos A. C. dos Santos, 2020. "Exergoeconomic Assessment of a Compact Electricity-Cooling Cogeneration Unit," Energies, MDPI, vol. 13(20), pages 1-18, October.
    2. Ana Fernández-Guillamón & Ángel Molina-García & Francisco Vera-García & José A. Almendros-Ibáñez, 2021. "Organic Rankine Cycle Optimization Performance Analysis Based on Super-Heater Pressure: Comparison of Working Fluids," Energies, MDPI, vol. 14(9), pages 1-16, April.
    3. Bartosz Gil & Anna Szczepanowska & Sabina Rosiek, 2021. "New HFC/HFO Blends as Refrigerants for the Vapor-Compression Refrigeration System (VCRS)," Energies, MDPI, vol. 14(4), pages 1-23, February.
    4. Piyanut Saengsikhiao & Juntakan Taweekun, 2021. "Energy Efficiency Improvement Solutions for Supermarkets by Low-E Glass Door and Digital Semi-Hermetic Compressor," Energies, MDPI, vol. 14(11), pages 1-11, May.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Albà, C.G. & Alkhatib, I.I.I. & Llovell, F. & Vega, L.F., 2023. "Hunting sustainable refrigerants fulfilling technical, environmental, safety and economic requirements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    2. Kasaeian, Alibakhsh & Hosseini, Seyed Mohsen & Sheikhpour, Mojgan & Mahian, Omid & Yan, Wei-Mon & Wongwises, Somchai, 2018. "Applications of eco-friendly refrigerants and nanorefrigerants: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 96(C), pages 91-99.
    3. Yang, Zhao & Wu, Xi, 2013. "Retrofits and options for the alternatives to HCFC-22," Energy, Elsevier, vol. 59(C), pages 1-21.
    4. Aprea, Ciro & Maiorino, Angelo & Mastrullo, Rita, 2011. "Change in energy performance as a result of a R422D retrofit: An experimental analysis for a vapor compression refrigeration plant for a walk-in cooler," Applied Energy, Elsevier, vol. 88(12), pages 4742-4748.
    5. Xu, Weicong & Zhao, Ruikai & Deng, Shuai & Zhao, Li & Mao, Samuel S., 2021. "Is zeotropic working fluid a promising option for organic Rankine cycle: A quantitative evaluation based on literature data," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    6. Zhang, Yifan & Ren, Xiao & Duan, Xinyue & Gong, Liang & Hung, Tzu-Chen, 2024. "Strategy for the zeotropic organic rankine cycle operation to match the heat sink variation," Energy, Elsevier, vol. 286(C).
    7. Mota-Babiloni, Adrián & Barbosa, Jader R. & Makhnatch, Pavel & Lozano, Jaime A., 2020. "Assessment of the utilization of equivalent warming impact metrics in refrigeration, air conditioning and heat pump systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 129(C).
    8. Matsuura, Riku & Watanabe, Kosuke & Yamauchi, Yuji & Sato, Haruka & Chen, Li-Jen & Ohmura, Ryo, 2021. "Thermodynamic analysis of hydrate-based refrigeration cycle," Energy, Elsevier, vol. 220(C).
    9. Mastrowski, Mikolaj & Smolka, Jacek & Hafner, Armin & Haida, Michal & Palacz, Michal & Banasiak, Krzysztof, 2019. "Experimental study of the heat transfer problem in expansion devices in CO2 refrigeration systems," Energy, Elsevier, vol. 173(C), pages 586-597.
    10. Zhao, Zhen & Luo, Jielin & Zou, Dexin & Yang, Kaiyin & Wang, Qin & Chen, Guangming, 2023. "Experimental investigation on the inhibition of flame retardants on the flammability of R1234ze(E)," Energy, Elsevier, vol. 263(PE).
    11. Jiang, Sufan & Gao, Shan & Pan, Guangsheng & Zhao, Xin & Liu, Yu & Guo, Yasen & Wang, Sicheng, 2020. "A novel robust security constrained unit commitment model considering HVDC regulation," Applied Energy, Elsevier, vol. 278(C).
    12. Wang, Chenfang & Li, Qingshan & Wang, Chunmei & Zhang, Yangjun & Zhuge, Weilin, 2021. "Thermodynamic analysis of a hydrogen fuel cell waste heat recovery system based on a zeotropic organic Rankine cycle," Energy, Elsevier, vol. 232(C).
    13. Ciro Aprea & Laura Canale & Marco Dell’Isola & Giorgio Ficco & Andrea Frattolillo & Angelo Maiorino & Fabio Petruzziello, 2023. "On the Use of Ultrasonic Flowmeters for Cooling Energy Metering and Sub-Metering in Direct Expansion Systems," Energies, MDPI, vol. 16(12), pages 1-16, June.
    14. Qi Chen & Yinsong Li, 2022. "Experimental Investigation on Intermittent Operation Characteristics of Dual-Temperature Refrigeration System Using Hydrocarbon Mixture," Energies, MDPI, vol. 15(11), pages 1-19, May.
    15. Zhu, Sipeng & Ma, Zetai & Zhang, Kun & Deng, Kangyao, 2020. "Energy and exergy analysis of the combined cycle power plant recovering waste heat from the marine two-stroke engine under design and off-design conditions," Energy, Elsevier, vol. 210(C).
    16. Kumma, Nagarjuna & Kruthiventi, S.S Harish, 2024. "Current status of refrigerants used in domestic applications: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    17. Yoonho, Lee, 2019. "LNG-FSRU cold energy recovery regasification using a zeotropic mixture of ethane and propane," Energy, Elsevier, vol. 173(C), pages 857-869.
    18. Wu, Xi & Yang, Zhao & Wang, Xiaoming & Lin, Yulong, 2013. "Experimental and theoretical study on the influence of temperature and humidity on the flammability limits of ethylene (R1150)," Energy, Elsevier, vol. 52(C), pages 185-191.
    19. Wang, Yao & Wang, Qianlong & Yu, Jianlin & Qian, Suxin, 2023. "A heat pump dual temperature display cabinet using natural refrigerants," Applied Energy, Elsevier, vol. 330(PB).
    20. Hu, Shuozhuo & Li, Jian & Yang, Fubin & Yang, Zhen & Duan, Yuanyuan, 2020. "Multi-objective optimization of organic Rankine cycle using hydrofluorolefins (HFOs) based on different target preferences," Energy, Elsevier, vol. 203(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:13:y:2020:i:6:p:1514-:d:335801. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.