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Experimental investigation on the inhibition of flame retardants on the flammability of R1234ze(E)

Author

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  • Zhao, Zhen
  • Luo, Jielin
  • Zou, Dexin
  • Yang, Kaiyin
  • Wang, Qin
  • Chen, Guangming

Abstract

Owing to environmental friendliness, R1234ze(E) is considered as an alternative refrigerant, but the flammability restricts its use and promotion. To reduce the combustible risk, nonflammable refrigerants can be blended, while there is a lack of research on mixture flammability. In this paper, the inhibition effects of three typical refrigerants R744, R1336mzz(E) and R1233zd(E) on the flammability of R1234ze(E) were experimentally investigated under the condition of 23 °C and 50% relative humidity. The flammable limits at different concentrations were measured and the critical suppression concentrations of the three retardants were determined as 0.41, 0.2 and 0.4 respectively, by which the parameters of fitting equations to their flammable limits were obtained. The inhibition mechanisms were briefly analyzed in terms of both physical and chemical effects, and typical flame propagation phenomena were compared with further analyses. A model for estimating critical suppression concentrations of ternary blends was established. The critical suppression lines of ternary blends R744/R1234ze(E)/R1336mzz(E) and R744/R1234ze(E)/R1233zd(E) were obtained, by which the nonflammable zones of the two ternary blends were preliminarily determined. The results have provided complements for previous studies using R744/R1234ze(E) at flammable concentrations and will contribute to utilize R1234ze(E) and its blends in safety for both scientific researches and industrial applications.

Suggested Citation

  • Zhao, Zhen & Luo, Jielin & Zou, Dexin & Yang, Kaiyin & Wang, Qin & Chen, Guangming, 2023. "Experimental investigation on the inhibition of flame retardants on the flammability of R1234ze(E)," Energy, Elsevier, vol. 263(PE).
    • Handle: RePEc:eee:energy:v:263:y:2023:i:pe:s0360544222030353
    DOI: 10.1016/j.energy.2022.126149
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    References listed on IDEAS

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    1. Yang, Zhao & Wu, Xi & Tian, Tian, 2015. "Flammability of Trans-1, 3, 3, 3-tetrafluoroprop-1-ene and its binary blends," Energy, Elsevier, vol. 91(C), pages 386-392.
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    Cited by:

    1. Zhang, Ji & Hu, Xudong & Wu, Ding & Huang, Xiaohui & Wang, Xuehui & Yang, Yan & Wen, Chuang, 2023. "A comparative study on design and performance evaluation of Organic Rankine Cycle (ORC) under different two-phase heat transfer correlations," Applied Energy, Elsevier, vol. 350(C).
    2. Wang, Xueyan & Tian, Hua & Shu, Gequn & Yang, Zhao, 2024. "Study on flammability limit and combustion reactions behaviors of R744/R152a environmentally friendly mixed working fluid by experiments and molecular dynamic simulation," Energy, Elsevier, vol. 304(C).
    3. Fan, Xiaoya & Liu, Yufei & Li, Xingxing & Chen, Qi & Wang, Shuhua & Chen, Guangming, 2024. "Experimental study on the influence of flame retardants under high-temperature conditions on the flammability of R1234ze(E) and R290," Energy, Elsevier, vol. 293(C).
    4. Wang, Xueyan & Tian, Hua & Shu, Gequn & Yang, Zhao, 2024. "Experimental and chemical kinetics study on the flammability limit of CO2/C3H6 mixture working fluid at variable initial temperature," Energy, Elsevier, vol. 301(C).
    5. Zhang, Ji & Wu, Ding & Huang, Xiaohui & Hu, Xudong & Fang, Xi & Wen, Chuang, 2024. "Comparative study on the organic rankine cycle off-design performance under different zeotropic mixture flow boiling correlations," Renewable Energy, Elsevier, vol. 226(C).
    6. Kumma, Nagarjuna & Kruthiventi, S.S Harish, 2024. "Current status of refrigerants used in domestic applications: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).

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