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A Moving Bed Reactor for Thermochemical Energy Storage Based on Metal Oxides

Author

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  • Nicole Carina Preisner

    (Institute of Engineering Thermodynamics, DLR, Linder Höhe, 51147 Köln, Germany)

  • Marc Linder

    (Institute of Engineering Thermodynamics, DLR, Pfaffenwaldring 38–40, 70569 Stuttgart, Germany)

Abstract

High-temperature thermal energy storage enables concentrated solar power plants to provide base load. Thermochemical energy storage is based on reversible gas–solid reactions and brings along the advantage of potential loss-free energy storage in the form of separated reaction products and possible high energy densities. The redox reaction of metal oxides is able to store thermal energy at elevated temperatures with air providing the gaseous reaction partner. However, due to the high temperature level, it is crucial to extract both the inherent sensible and thermochemical energies of the metal-oxide particles for enhanced system efficiency. So far, experimental research in the field of thermochemical energy storage focused mainly on solar receivers for continuously charging metal oxides. A continuously operated system of energy storage and solar tower decouples the storage capacity from generated power with metal-oxide particles applied as heat transfer medium and energy storage material. Hence, a heat exchanger based on a countercurrent moving bed concept was developed in a kW -scale. The reactor addresses the combined utilization of the reaction enthalpy of the oxidation and the extraction of thermal energy of a manganese–iron-oxide particle flow. A stationary temperature profile of the bulk was achieved with two distinct temperature sections. The oxidation induced a nearly isothermal section with an overall stable off-gas temperature. The oxidation and heat extraction from the manganese–iron oxide resulted in a total energy density of 569 kJ/kg with a thermochemical share of 21.1%.

Suggested Citation

  • Nicole Carina Preisner & Marc Linder, 2020. "A Moving Bed Reactor for Thermochemical Energy Storage Based on Metal Oxides," Energies, MDPI, vol. 13(5), pages 1-20, March.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:5:p:1232-:d:329498
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    References listed on IDEAS

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    1. Marco Mancini & Andreas Schwabauer, 2023. "On the Thermal Stability of a Counter-Current Fixed-Bed Gasifier," Energies, MDPI, vol. 16(9), pages 1-36, April.
    2. Ying Yang & Yingjie Li & Xianyao Yan & Jianli Zhao & Chunxiao Zhang, 2021. "Development of Thermochemical Heat Storage Based on CaO/CaCO 3 Cycles: A Review," Energies, MDPI, vol. 14(20), pages 1-26, October.
    3. Michela Lanchi & Luca Turchetti & Salvatore Sau & Raffaele Liberatore & Stefano Cerbelli & Maria Anna Murmura & Maria Cristina Annesini, 2020. "A Discussion of Possible Approaches to the Integration of Thermochemical Storage Systems in Concentrating Solar Power Plants," Energies, MDPI, vol. 13(18), pages 1-26, September.
    4. Xing Tian & Jian Yang & Zhigang Guo & Qiuwang Wang, 2021. "Numerical Investigation of Gravity-Driven Granular Flow around the Vertical Plate: Effect of Pin-Fin and Oscillation on the Heat Transfer," Energies, MDPI, vol. 14(8), pages 1-14, April.
    5. Tescari, Stefania & Neumann, Nicole Carina & Sundarraj, Pradeepkumar & Moumin, Gkiokchan & Rincon Duarte, Juan Pablo & Linder, Marc & Roeb, Martin, 2022. "Storing solar energy in continuously moving redox particles – Experimental analysis of charging and discharging reactors," Applied Energy, Elsevier, vol. 308(C).
    6. Anti Kur & Jo Darkwa & John Calautit & Rabah Boukhanouf & Mark Worall, 2023. "Solid–Gas Thermochemical Energy Storage Materials and Reactors for Low to High-Temperature Applications: A Concise Review," Energies, MDPI, vol. 16(2), pages 1-35, January.

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