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Thermodynamic potential of molten copper oxide for high temperature solar energy storage and oxygen production

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  • Jafarian, Mehdi
  • Arjomandi, Maziar
  • Nathan, Graham J.

Abstract

A novel cycle, the chemical looping of molten copper oxide, is proposed with the thermodynamic potential to achieve sensible, latent and thermochemical heat storage with an energy density of approximately 5.0GJ/m3, which is approximately 6 times more than the 0.83GJ/m3 of molten salt. This cycle avoids the technical challenges associated with the application of solid materials (especially multivalent metals) for thermochemical energy storage such as attrition, agglomeration, particle breakage and structural change in successive reduction and oxidation reactions, although it brings alternative challenges associated with the handling of molten metal oxides. A process path for the concept is proposed based on data from the literature for the equilibrium composition of copper and oxygen at different temperatures and gas phase pressures. The process has been modelled with codes developed in MATLAB. The calculations estimate that from the total input concentrated solar thermal energy into the system, about 73% can be absorbed, while the rest is lost through re-radiation heat loss. Furthermore, it is estimated that of the absorbed heat, approximately 95% is stored, while the rest leaves the system as high temperature gas. The calculations also predict that approximately 20% of the inlet solar thermal energy is partitioned as the chemical storage, which is also employed for oxygen production. Also reported is the sensitivity to the effects of key operating parameters.

Suggested Citation

  • Jafarian, Mehdi & Arjomandi, Maziar & Nathan, Graham J., 2017. "Thermodynamic potential of molten copper oxide for high temperature solar energy storage and oxygen production," Applied Energy, Elsevier, vol. 201(C), pages 69-83.
    • Handle: RePEc:eee:appene:v:201:y:2017:i:c:p:69-83
    DOI: 10.1016/j.apenergy.2017.05.049
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    References listed on IDEAS

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    Cited by:

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    2. Rehan Anwar & M. Veronica Sofianos, 2024. "Exploring the Role of Additives in Enhancing the Performance of Limestone-Based Thermochemical Energy Storage: A Review," Energies, MDPI, vol. 17(11), pages 1-20, May.
    3. Nicole Carina Preisner & Marc Linder, 2020. "A Moving Bed Reactor for Thermochemical Energy Storage Based on Metal Oxides," Energies, MDPI, vol. 13(5), pages 1-20, March.
    4. Tao, Ye & Tian, Wende & Kong, Lingqi & Sun, Suli & Fan, Chenyang, 2022. "Energy, exergy, economic, environmental (4E) and dynamic analysis based global optimization of chemical looping air separation for oxygen and power co-production," Energy, Elsevier, vol. 261(PB).
    5. Selvan Bellan & Tatsuya Kodama & Nobuyuki Gokon & Koji Matsubara, 2022. "A review on high‐temperature thermochemical heat storage: Particle reactors and materials based on solid–gas reactions," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 11(5), September.
    6. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    7. Silakhori, Mahyar & Jafarian, Mehdi & Arjomandi, Maziar & Nathan, Graham J., 2019. "The energetic performance of a liquid chemical looping cycle with solar thermal energy storage," Energy, Elsevier, vol. 170(C), pages 93-101.
    8. Zhu, Qibin & Xuan, Yimin & Liu, Xianglei & Yang, Lili & Lian, Wenlei & Zhang, Jin, 2020. "A 130 kWe solar simulator with tunable ultra-high flux and characterization using direct multiple lamps mapping," Applied Energy, Elsevier, vol. 270(C).

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