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Conversion of chitin biomass into 5-hydroxymethylfurfural: A review

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  • Cai, Xin
  • Wang, Zhichao
  • Ye, Yueyuan
  • Wang, Duo
  • Zhang, Zhaoxia
  • Zheng, Zhifeng
  • Liu, Yunquan
  • Li, Shuirong

Abstract

5-hydroxymethyfurfural is an important platform chemical, which can be produced by hydrothermal conversion of chitin biomass. 5-Hydroxymethyfurfural can be converted into value-added chemicals and liquid fuels. Thus, the utilization of chitin biomass will help consume crustacean waste and reduce environmental problems caused by the overuse of fossil resources. This review summarizes the recent process in the production of 5-hydroxymethyfurfural from chitin biomass in solvent-catalytic systems. The topics mainly include solvent systems, catalysts, and conversion mechanisms. Suitable solvent system can improve the conversion of chitin biomass into 5-hydroxymethyfurfural. Especially, the strong solubility of concentrated salt solution resulted in mild reaction temperature. Mechanism studies based on solvent system will be helpful to the products control. The catalysts are very important in producing 5-hydroxymethyfurfural from chitin biomass. Catalyst design and related reaction mechanism research will be necessary to improve the selectivity of the 5-hydroxymethyfurfural. Future research will focus on finding a catalyst-solvent combination system that improves the solubility and conversion of chitin biomass, especially on cheap and easily available solvents such as deep eutectic solvents, high-temperature water and inorganic salts such as aluminum chloride, ferrous chloride, etc.

Suggested Citation

  • Cai, Xin & Wang, Zhichao & Ye, Yueyuan & Wang, Duo & Zhang, Zhaoxia & Zheng, Zhifeng & Liu, Yunquan & Li, Shuirong, 2021. "Conversion of chitin biomass into 5-hydroxymethylfurfural: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    • Handle: RePEc:eee:rensus:v:150:y:2021:i:c:s1364032121007358
    DOI: 10.1016/j.rser.2021.111452
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    References listed on IDEAS

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    1. Kumari, Rajni & Kumar, Manish & Vivekanand, V. & Pareek, Nidhi, 2023. "Chitin biorefinery: A narrative and prophecy of crustacean shell waste sustainable transformation into bioactives and renewable energy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    2. Zhou, Qiaoqiao & Liu, Zhenyu & Wu, Ta Yeong & Zhang, Lian, 2023. "Furfural from pyrolysis of agroforestry waste: Critical factors for utilisation of C5 and C6 sugars," Renewable and Sustainable Energy Reviews, Elsevier, vol. 176(C).
    3. Chai, Yu & Tian, Xin-Yu & Zheng, Xiao-Ping & Du, Ya-Peng & Zhang, Yu-Cang & Zheng, Yan-Zhen, 2024. "An effective approach for chitosan conversion to 5-hydroxymethylfurfural catalyzed by bio-based organic acid with ionic liquids additive," Renewable Energy, Elsevier, vol. 221(C).
    4. Shao, Yuewen & Wu, Jie & Zheng, Zhiyuan & Fan, Mengjiao & Sun, Kai & Bkangmo Kontchouo, Félix Mérimé & Zhang, Lijun & Zhang, Shu & Hu, Guangzhi & Hu, Xun, 2022. "Alloying cobalt in Co–Fe–Al catalyst for achieving the selective conversion of furfural to cyclopentanone," Renewable Energy, Elsevier, vol. 195(C), pages 957-971.

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