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CO2-utilization in the synthesis of methanol: Potential analysis and exergetic assessment

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  • Blumberg, Timo
  • Morosuk, Tatiana
  • Tsatsaronis, George

Abstract

Carbon capture and utilization represents a major strategy to reduce anthropogenic CO2-emissions by valorization to chemical and petrochemical products. The integration of CO2 is not only aimed at abating emissions, but also at a partial substitution of raw materials, most of which are fossil fuels. In this context, Gas-to-Liquid processes are of great importance, in particular the production of methanol from its predominating feedstock natural gas. In the present study the CO2-utilization potential and impact of CO2-integration measures in methanol synthesis routes are investigated and assessed from a thermodynamic point of view. Sensitivity analyses for an estimation of the CO2-integration potential by dry reforming and direct hydrogenation are carried out. In a dry-reforming process, a carbon dioxide-to-methane mole ratio of one results from tradeoffs among the CH4-conversion, the desired syngas composition, and the heat demand.

Suggested Citation

  • Blumberg, Timo & Morosuk, Tatiana & Tsatsaronis, George, 2019. "CO2-utilization in the synthesis of methanol: Potential analysis and exergetic assessment," Energy, Elsevier, vol. 175(C), pages 730-744.
    • Handle: RePEc:eee:energy:v:175:y:2019:i:c:p:730-744
    DOI: 10.1016/j.energy.2019.03.107
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    References listed on IDEAS

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    1. Blumberg, Timo & Morosuk, Tatiana & Tsatsaronis, George, 2017. "Exergy-based evaluation of methanol production from natural gas with CO2 utilization," Energy, Elsevier, vol. 141(C), pages 2528-2539.
    2. Pérez-Fortes, Mar & Schöneberger, Jan C. & Boulamanti, Aikaterini & Tzimas, Evangelos, 2016. "Methanol synthesis using captured CO2 as raw material: Techno-economic and environmental assessment," Applied Energy, Elsevier, vol. 161(C), pages 718-732.
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    1. Mehrpooya, Mehdi & Ansarinasab, Hojat & Mousavi, Seyed Ali, 2021. "Life cycle assessment and exergoeconomic analysis of the multi-generation system based on fuel cell for methanol, power, and heat production," Renewable Energy, Elsevier, vol. 172(C), pages 1314-1332.
    2. Koytsoumpa, Efthymia Ioanna & Karellas, Sotirios & Kakaras, Emmanouil, 2020. "Modelling of methanol production via combined gasification and power to fuel," Renewable Energy, Elsevier, vol. 158(C), pages 598-611.
    3. Ding, Haoran & Liu, Shenghui & Liu, Fei & Han, Long & Sun, Shien & Qi, Zhifu, 2024. "Experimental and numerical investigation of chemical-loop steam methane reforming on monolithic BaCoO3/CeO2 oxygen," Energy, Elsevier, vol. 302(C).
    4. Wei, Guoqiang & Zhou, Huan & Huang, Zhen & Zheng, Anqing & Zhao, Kun & Lin, Yan & Chang, Guozhang & Zhao, Zengli & Li, Haibin & Fang, Yitian, 2021. "Reaction performance of Ce-enhanced hematite oxygen carrier in chemical looping reforming of biomass pyrolyzed gas coupled with CO2 splitting," Energy, Elsevier, vol. 215(PB).
    5. Huang, Yue & Zhu, Lin & He, Yangdong & Zeng, Xingyan & Wang, Yuan & Hao, Qiang & Zhang, Chaoli & Zhu, Yifei, 2024. "Exergoenvironment evaluation of carbon resource conversion and utilization via CO2 direct hydrogenation for methanol and power cogeneration," Energy, Elsevier, vol. 306(C).
    6. Blumberg, Timo & Lee, Young Duk & Morosuk, Tatiana & Tsatsaronis, George, 2019. "Exergoenvironmental analysis of methanol production by steam reforming and autothermal reforming of natural gas," Energy, Elsevier, vol. 181(C), pages 1273-1284.

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