IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v10y2017i11p1803-d118083.html
   My bibliography  Save this article

Silicon-Carbon Composite Electrode Materials Prepared by Pyrolysis of a Mixture of Manila Hemp, Silicon Powder, and Flake Artificial Graphite for Lithium Batteries

Author

Listed:
  • Qin Si

    (Graduate School of Engineering, Mie University, Tsu 514-8507, Japan)

  • Daisuke Mori

    (Graduate School of Engineering, Mie University, Tsu 514-8507, Japan)

  • Yasuo Takeda

    (Graduate School of Engineering, Mie University, Tsu 514-8507, Japan)

  • Osamu Yamamoto

    (Graduate School of Engineering, Mie University, Tsu 514-8507, Japan)

  • Nobuyuki Imanishi

    (Graduate School of Engineering, Mie University, Tsu 514-8507, Japan)

Abstract

A high performance lithium anode is a key component for high energy density lithium batteries. Silicon based lithium anode materials are attractive for the lithium anode due to their high theoretical capacity. However, a severe problem is the huge volume change that occurs during cycling, resulting in a poor capacity retention. We have developed a silicon based anode that disperses silicon particles on a carbon paper made from Manila hemp. The composite silicon electrode materials showed a high initial coulombic efficiency of 83%. The initial capacity of 566 mAh g −1 based on the total weight of the electrode was retained at 491 mAh g −1 after 70 cycles at the charge and discharge rate of 100 mA g −1 and at room temperature.

Suggested Citation

  • Qin Si & Daisuke Mori & Yasuo Takeda & Osamu Yamamoto & Nobuyuki Imanishi, 2017. "Silicon-Carbon Composite Electrode Materials Prepared by Pyrolysis of a Mixture of Manila Hemp, Silicon Powder, and Flake Artificial Graphite for Lithium Batteries," Energies, MDPI, vol. 10(11), pages 1-9, November.
    • Handle: RePEc:gam:jeners:v:10:y:2017:i:11:p:1803-:d:118083
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/10/11/1803/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/10/11/1803/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. M. Armand & J.-M. Tarascon, 2008. "Building better batteries," Nature, Nature, vol. 451(7179), pages 652-657, February.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xingyu Zhang & Jian Chen & Yinhua Bao, 2022. "Model-Based Investigations of Porous Si-Based Anodes for Lithium-Ion Batteries with Effects of Volume Changes," Energies, MDPI, vol. 15(23), pages 1-18, November.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mohammadmahdi Ghiji & Vasily Novozhilov & Khalid Moinuddin & Paul Joseph & Ian Burch & Brigitta Suendermann & Grant Gamble, 2020. "A Review of Lithium-Ion Battery Fire Suppression," Energies, MDPI, vol. 13(19), pages 1-30, October.
    2. Jun-Ping Hu & Hang Sheng & Qi Deng & Qiang Ma & Jun Liu & Xiong-Wei Wu & Jun-Jie Liu & Yu-Ping Wu, 2020. "High-Rate Layered Cathode of Lithium-Ion Batteries through Regulating Three-Dimensional Agglomerated Structure," Energies, MDPI, vol. 13(7), pages 1-12, April.
    3. Li, Qun & Yin, Longwei & Ma, Jingyun & Li, Zhaoqiang & Zhang, Zhiwei & Chen, Ailian & Li, Caixia, 2015. "Mesoporous silicon/carbon hybrids with ordered pore channel retention and tunable carbon incorporated content as high performance anode materials for lithium-ion batteries," Energy, Elsevier, vol. 85(C), pages 159-166.
    4. Yiding, Li & Wenwei, Wang & Cheng, Lin & Xiaoguang, Yang & Fenghao, Zuo, 2021. "A safety performance estimation model of lithium-ion batteries for electric vehicles under dynamic compression," Energy, Elsevier, vol. 215(PA).
    5. Chen, Dongfang & Pan, Lyuming & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "Carbon-coated oxygen vacancies-rich Co3O4 nanoarrays grow on nickel foam as efficient bifunctional electrocatalysts for rechargeable zinc-air batteries," Energy, Elsevier, vol. 224(C).
    6. Zhao, Bin, 2017. "Why will dominant alternative transportation fuels be liquid fuels, not electricity or hydrogen?," Energy Policy, Elsevier, vol. 108(C), pages 712-714.
    7. Ziheng Zhang & Maxim Avdeev & Huaican Chen & Wen Yin & Wang Hay Kan & Guang He, 2022. "Lithiated Prussian blue analogues as positive electrode active materials for stable non-aqueous lithium-ion batteries," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    8. Zhi Chang & Huijun Yang & Xingyu Zhu & Ping He & Haoshen Zhou, 2022. "A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    9. Entwistle, Jake & Ge, Ruihuan & Pardikar, Kunal & Smith, Rachel & Cumming, Denis, 2022. "Carbon binder domain networks and electrical conductivity in lithium-ion battery electrodes: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 166(C).
    10. Yohwan Choi & Hongseok Kim, 2016. "Optimal Scheduling of Energy Storage System for Self-Sustainable Base Station Operation Considering Battery Wear-Out Cost," Energies, MDPI, vol. 9(6), pages 1-19, June.
    11. Jack E. N. Swallow & Michael W. Fraser & Nis-Julian H. Kneusels & Jodie F. Charlton & Christopher G. Sole & Conor M. E. Phelan & Erik Björklund & Peter Bencok & Carlos Escudero & Virginia Pérez-Dieste, 2022. "Revealing solid electrolyte interphase formation through interface-sensitive Operando X-ray absorption spectroscopy," Nature Communications, Nature, vol. 13(1), pages 1-14, December.
    12. Chao Wang & Ming Liu & Michel Thijs & Frans G. B. Ooms & Swapna Ganapathy & Marnix Wagemaker, 2021. "High dielectric barium titanate porous scaffold for efficient Li metal cycling in anode-free cells," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    13. Zheng, Menglian & Meinrenken, Christoph J. & Lackner, Klaus S., 2014. "Agent-based model for electricity consumption and storage to evaluate economic viability of tariff arbitrage for residential sector demand response," Applied Energy, Elsevier, vol. 126(C), pages 297-306.
    14. Navaratnarajah Kuganathan & Efstratia N. Sgourou & Yerassimos Panayiotatos & Alexander Chroneos, 2019. "Defect Process, Dopant Behaviour and Li Ion Mobility in the Li 2 MnO 3 Cathode Material," Energies, MDPI, vol. 12(7), pages 1-11, April.
    15. Jiang, Yunfeng & Xia, Bing & Zhao, Xin & Nguyen, Truong & Mi, Chris & de Callafon, Raymond A., 2017. "Data-based fractional differential models for non-linear dynamic modeling of a lithium-ion battery," Energy, Elsevier, vol. 135(C), pages 171-181.
    16. Lu Zhang & Xiaohua Zhang & Guiying Tian & Qinghua Zhang & Michael Knapp & Helmut Ehrenberg & Gang Chen & Zexiang Shen & Guochun Yang & Lin Gu & Fei Du, 2020. "Lithium lanthanum titanate perovskite as an anode for lithium ion batteries," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    17. Runlin Wang & Haozhe Zhang & Qiyu Liu & Fu Liu & Xile Han & Xiaoqing Liu & Kaiwei Li & Gaozhi Xiao & Jacques Albert & Xihong Lu & Tuan Guo, 2022. "Operando monitoring of ion activities in aqueous batteries with plasmonic fiber-optic sensors," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    18. Wu, Xiaoyu & Li, Songmei & Wang, Bo & Liu, Jianhua & Yu, Mei, 2020. "Free-standing 3D network-like cathode based on biomass-derived N-doped carbon/graphene/g-C3N4 hybrid ultrathin sheets as sulfur host for high-rate Li-S battery," Renewable Energy, Elsevier, vol. 158(C), pages 509-519.
    19. Yi Wu & Saurabh Saxena & Yinjiao Xing & Youren Wang & Chuan Li & Winco K. C. Yung & Michael Pecht, 2018. "Analysis of Manufacturing-Induced Defects and Structural Deformations in Lithium-Ion Batteries Using Computed Tomography," Energies, MDPI, vol. 11(4), pages 1-22, April.
    20. Du, Peng & Cao, Liang & Zhang, Bao & Wang, Chunhui & Xiao, Zhiming & Zhang, Jiafeng & Wang, Dong & Ou, Xing, 2021. "Recent progress on heterostructure materials for next-generation sodium/potassium ion batteries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:10:y:2017:i:11:p:1803-:d:118083. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.