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Silicon-Carbon Composite Electrode Materials Prepared by Pyrolysis of a Mixture of Manila Hemp, Silicon Powder, and Flake Artificial Graphite for Lithium Batteries

Author

Listed:
  • Qin Si

    (Graduate School of Engineering, Mie University, Tsu 514-8507, Japan)

  • Daisuke Mori

    (Graduate School of Engineering, Mie University, Tsu 514-8507, Japan)

  • Yasuo Takeda

    (Graduate School of Engineering, Mie University, Tsu 514-8507, Japan)

  • Osamu Yamamoto

    (Graduate School of Engineering, Mie University, Tsu 514-8507, Japan)

  • Nobuyuki Imanishi

    (Graduate School of Engineering, Mie University, Tsu 514-8507, Japan)

Abstract

A high performance lithium anode is a key component for high energy density lithium batteries. Silicon based lithium anode materials are attractive for the lithium anode due to their high theoretical capacity. However, a severe problem is the huge volume change that occurs during cycling, resulting in a poor capacity retention. We have developed a silicon based anode that disperses silicon particles on a carbon paper made from Manila hemp. The composite silicon electrode materials showed a high initial coulombic efficiency of 83%. The initial capacity of 566 mAh g −1 based on the total weight of the electrode was retained at 491 mAh g −1 after 70 cycles at the charge and discharge rate of 100 mA g −1 and at room temperature.

Suggested Citation

  • Qin Si & Daisuke Mori & Yasuo Takeda & Osamu Yamamoto & Nobuyuki Imanishi, 2017. "Silicon-Carbon Composite Electrode Materials Prepared by Pyrolysis of a Mixture of Manila Hemp, Silicon Powder, and Flake Artificial Graphite for Lithium Batteries," Energies, MDPI, vol. 10(11), pages 1-9, November.
    • Handle: RePEc:gam:jeners:v:10:y:2017:i:11:p:1803-:d:118083
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    References listed on IDEAS

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    1. M. Armand & J.-M. Tarascon, 2008. "Building better batteries," Nature, Nature, vol. 451(7179), pages 652-657, February.
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    Cited by:

    1. Xingyu Zhang & Jian Chen & Yinhua Bao, 2022. "Model-Based Investigations of Porous Si-Based Anodes for Lithium-Ion Batteries with Effects of Volume Changes," Energies, MDPI, vol. 15(23), pages 1-18, November.

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