IDEAS home Printed from https://ideas.repec.org/a/gam/jcltec/v5y2022i1p1-24d1008896.html
   My bibliography  Save this article

CO 2 -Selective Capture from Light Hydrocarbon Mixtures by Metal-Organic Frameworks: A Review

Author

Listed:
  • Hengcong Huang

    (College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Siping Rd 1239, Shanghai 200092, China)

  • Luyao Wang

    (College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Siping Rd 1239, Shanghai 200092, China)

  • Xiaoyu Zhang

    (College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Siping Rd 1239, Shanghai 200092, China)

  • Hongshuo Zhao

    (College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Siping Rd 1239, Shanghai 200092, China)

  • Yifan Gu

    (College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Siping Rd 1239, Shanghai 200092, China)

Abstract

CO 2 represents a typical impurity in light hydrocarbon feedstocks, which affects the quality of subsequent chemical products. Owing to their highly similar nature, industrial separation requires large amounts of energy. Adsorptive gas separation based on porous materials is considered an efficient alternative, as it can offer faster kinetics, higher selectivity, long-term stability and more energy-efficient regeneration. For the adsorption separation method, preferential CO 2 capture from gas mixtures in one step is more energy-efficient for direct purification than light hydrocarbons, saving about 40% energy by eliminating energy-intensive post-regeneration processes such as countercurrent vacuum blowdown. Therefore, CO 2 -selective adsorbents are more sought-after than light hydrocarbon-selective adsorbents. Metal-organic frameworks (MOFs) have been demonstrated as outstanding physisorbents for CO 2 capture due to their configurable channels for CO 2 recognition, structural flexibility and large specific surface area. Many highly selective CO 2 adsorption behaviors of MOFs have been reportedly achieved by precise modulation of pore size, pore chemistry or structural flexibility. In this review, we discuss the emerging development of MOFs for CO 2 -selective capture from different light hydrocarbon mixtures. The challenges of CO 2 recognition and the strategies employed to achieve CO 2 selectivity over light hydrocarbon mixtures by MOFs are summarized. In addition, the current challenges and prospects in the field of MOFs for CO 2 capture are discussed and elaborated.

Suggested Citation

  • Hengcong Huang & Luyao Wang & Xiaoyu Zhang & Hongshuo Zhao & Yifan Gu, 2022. "CO 2 -Selective Capture from Light Hydrocarbon Mixtures by Metal-Organic Frameworks: A Review," Clean Technol., MDPI, vol. 5(1), pages 1-24, December.
    • Handle: RePEc:gam:jcltec:v:5:y:2022:i:1:p:1-24:d:1008896
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2571-8797/5/1/1/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/2571-8797/5/1/1/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Omid T. Qazvini & Ravichandar Babarao & Shane G. Telfer, 2021. "Selective capture of carbon dioxide from hydrocarbons using a metal-organic framework," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    2. Patrick Nugent & Youssef Belmabkhout & Stephen D. Burd & Amy J. Cairns & Ryan Luebke & Katherine Forrest & Tony Pham & Shengqian Ma & Brian Space & Lukasz Wojtas & Mohamed Eddaoudi & Michael J. Zaworo, 2013. "Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation," Nature, Nature, vol. 495(7439), pages 80-84, March.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yifan Gu & Jia-Jia Zheng & Ken-ichi Otake & Shigeyoshi Sakaki & Hirotaka Ashitani & Yoshiki Kubota & Shogo Kawaguchi & Ming-Shui Yao & Ping Wang & Ying Wang & Fengting Li & Susumu Kitagawa, 2023. "Soft corrugated channel with synergistic exclusive discrimination gating for CO2 recognition in gas mixture," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Qingju Wang & Jianbo Hu & Lifeng Yang & Zhaoqiang Zhang & Tian Ke & Xili Cui & Huabin Xing, 2022. "One-step removal of alkynes and propadiene from cracking gases using a multi-functional molecular separator," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    3. Ga, Seongbin & An, Nahyeon & Lee, Gi Yeol & Joo, Chonghyo & Kim, Junghwan, 2024. "Economic analysis with multiscale high-throughput screening for covalent organic framework adsorbents in ammonia-based green hydrogen separation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    4. Zhang, Chen & Zhang, Xinqi & Su, Tingyu & Zhang, Yiheng & Wang, Liwei & Zhu, Xuancan, 2023. "Modification schemes of efficient sorbents for trace CO2 capture," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    5. Ga, Seongbin & An, Nahyeon & Lee, Gi Yeol & Joo, Chonghyo & Kim, Junghwan, 2024. "Multidisciplinary high-throughput screening of metal–organic framework for ammonia-based green hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 192(C).
    6. Yaumi, A.L. & Bakar, M.Z. Abu & Hameed, B.H., 2017. "Recent advances in functionalized composite solid materials for carbon dioxide capture," Energy, Elsevier, vol. 124(C), pages 461-480.
    7. Qingju Wang & Lifeng Yang & Tian Ke & Jianbo Hu & Xian Suo & Xili Cui & Huabin Xing, 2024. "Selective sorting of hexane isomers by anion-functionalized metal-organic frameworks with optimal energy regulation," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    8. Wang, Pengfei & Teng, Ying & Zhu, Jinlong & Bao, Wancheng & Han, Songbai & Li, Yun & Zhao, Yusheng & Xie, Heping, 2022. "Review on the synergistic effect between metal–organic frameworks and gas hydrates for CH4 storage and CO2 separation applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    9. Jian Yu & Wenting He & Bin Liu, 2020. "Adsorption of Acid Orange Ⅱ with Two Step Modified Sepiolite: Optimization, Adsorption Performance, Kinetics, Thermodynamics and Regeneration," IJERPH, MDPI, vol. 17(5), pages 1-14, March.
    10. Al-Qahtani, Amjad & Parkinson, Brett & Hellgardt, Klaus & Shah, Nilay & Guillen-Gosalbez, Gonzalo, 2021. "Uncovering the true cost of hydrogen production routes using life cycle monetisation," Applied Energy, Elsevier, vol. 281(C).
    11. Amira Alazmi & Sabina A. Nicolae & Pierpaolo Modugno & Bashir E. Hasanov & Maria M. Titirici & Pedro M. F. J. Costa, 2021. "Activated Carbon from Palm Date Seeds for CO 2 Capture," IJERPH, MDPI, vol. 18(22), pages 1-11, November.
    12. Jingqi Wang & Jiapeng Liu & Hongshuai Wang & Musen Zhou & Guolin Ke & Linfeng Zhang & Jianzhong Wu & Zhifeng Gao & Diannan Lu, 2024. "A comprehensive transformer-based approach for high-accuracy gas adsorption predictions in metal-organic frameworks," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    13. Budzianowski, Wojciech M., 2016. "A review of potential innovations for production, conditioning and utilization of biogas with multiple-criteria assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 1148-1171.
    14. Jiyu Cui & Fang Wu & Wen Zhang & Lifeng Yang & Jianbo Hu & Yin Fang & Peng Ye & Qiang Zhang & Xian Suo & Yiming Mo & Xili Cui & Huajun Chen & Huabin Xing, 2023. "Direct prediction of gas adsorption via spatial atom interaction learning," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    15. Hong-Hua Qiu & Lu-Ge Liu, 2018. "A Study on the Evolution of Carbon Capture and Storage Technology Based on Knowledge Mapping," Energies, MDPI, vol. 11(5), pages 1-25, May.
    16. Shi, Jinsong & Xu, Jianguo & Cui, Hongmin & Yan, Nanfu & Zou, Jiyong & Liu, Yuewei & You, Shengyong, 2023. "Synthesis of highly porous N-doped hollow carbon nanospheres with a combined soft template-chemical activation method for CO2 capture," Energy, Elsevier, vol. 280(C).
    17. Bacsik, Zoltán & Cheung, Ocean & Vasiliev, Petr & Hedin, Niklas, 2016. "Selective separation of CO2 and CH4 for biogas upgrading on zeolite NaKA and SAPO-56," Applied Energy, Elsevier, vol. 162(C), pages 613-621.
    18. Sirinapa Wongwilawan & Thien S. Nguyen & Thi Phuong Nga Nguyen & Abdulhadi Alhaji & Wonki Lim & Yeongran Hong & Jin Su Park & Mert Atilhan & Bumjoon J. Kim & Mohamed Eddaoudi & Cafer T. Yavuz, 2023. "Non-solvent post-modifications with volatile reagents for remarkably porous ketone functionalized polymers of intrinsic microporosity," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    19. Xiuling Chen & Yanfang Fan & Lei Wu & Linzhou Zhang & Dong Guan & Canghai Ma & Nanwen Li, 2021. "Ultra-selective molecular-sieving gas separation membranes enabled by multi-covalent-crosslinking of microporous polymer blends," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    20. Dissanayake, Pavani Dulanja & You, Siming & Igalavithana, Avanthi Deshani & Xia, Yinfeng & Bhatnagar, Amit & Gupta, Souradeep & Kua, Harn Wei & Kim, Sumin & Kwon, Jung-Hwan & Tsang, Daniel C.W. & Ok, , 2020. "Biochar-based adsorbents for carbon dioxide capture: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jcltec:v:5:y:2022:i:1:p:1-24:d:1008896. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.