IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v97y2018icp436-455.html
   My bibliography  Save this article

Choline-based deep eutectic solvents for CO2 separation: Review and thermodynamic analysis

Author

Listed:
  • Zhang, Yingying
  • Ji, Xiaoyan
  • Lu, Xiaohua

Abstract

CO2 separation plays an important role in energy saving and CO2 emission reduction, both of which are necessary to address the issue of global warming. Ionic liquids (ILs) have been proposed to be “green” solvents for CO2 separation. Unfortunately, the high cost, toxicity, and poor biodegradability of these compounds limit their large-scale application. Deep eutectic solvents (DESs) were recently considered a new type of IL with additional advantages in terms of cost, environmental impact, and synthesis. DESs based on choline salts (i.e., choline-based DESs) are promising candidates for CO2 separation. In this work, the microstructures, physicochemical properties, and water effect of choline-based DESs are surveyed and compared with those of conventional ILs. The properties of choline-based DESs are similar to those of conventional ILs, but research on the latter remains limited. Further study on the microstructures, properties, and separation performance of choline-based DESs considering dynamic factors must be carried out through experimental measurements and model development. Thermodynamic analysis based on Gibbs free energy change is conducted to investigate the performances of choline-based-DESs during CO2 separation from biogas. Choline-based-DESs are screened on the basis of energy use and amount of absorbent needed. The performances of the screened choline-based-DESs are further compared with those of conventional ILs screened in our previous work, as well as commercial CO2 absorbents. Comparisons indicate that the screened DES-based absorbents show great application potential due to their nonvolatility, low energy use, or low amount required. The performances of physical choline-based-DES and 30 wt% MEA for CO2 separation from other gas streams (e.g., flue gas, lime kiln gas, and bio-syngas) are discussed. Considering the high amounts of physical absorbents required to enable separation, further study with techno-economic analysis needs to be carried out.

Suggested Citation

  • Zhang, Yingying & Ji, Xiaoyan & Lu, Xiaohua, 2018. "Choline-based deep eutectic solvents for CO2 separation: Review and thermodynamic analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 97(C), pages 436-455.
    • Handle: RePEc:eee:rensus:v:97:y:2018:i:c:p:436-455
    DOI: 10.1016/j.rser.2018.08.007
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032118305744
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2018.08.007?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhang, Yingying & Ji, Xiaoyan & Xie, Yujiao & Lu, Xiaohua, 2018. "Thermodynamic analysis of CO2 separation from biogas with conventional ionic liquids," Applied Energy, Elsevier, vol. 217(C), pages 75-87.
    2. Jianmin Zhang & Jian Sun & Xiaochun Zhang & Yansong Zhao & Suojiang Zhang, 2011. "The recent development of CO 2 fixation and conversion by ionic liquid," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 1(2), pages 142-159, June.
    3. Zhang, Yingying & Ji, Xiaoyan & Lu, Xiaohua, 2014. "Energy consumption analysis for CO2 separation from gas mixtures," Applied Energy, Elsevier, vol. 130(C), pages 237-243.
    4. Zhang, Yingying & Ji, Xiaoyan & Xie, Yujiao & Lu, Xiaohua, 2016. "Screening of conventional ionic liquids for carbon dioxide capture and separation," Applied Energy, Elsevier, vol. 162(C), pages 1160-1170.
    5. Xie, Yujiao & Zhang, Yingying & Lu, Xiaohua & Ji, Xiaoyan, 2014. "Energy consumption analysis for CO2 separation using imidazolium-based ionic liquids," Applied Energy, Elsevier, vol. 136(C), pages 325-335.
    6. Jason E. Bara, 2012. "What chemicals will we need to capture CO 2 ?," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 2(3), pages 162-171, June.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Haider, Junaid & Saeed, Saad & Qyyum, Muhammad Abdul & Kazmi, Bilal & Ahmad, Rizwan & Muhammad, Ayyaz & Lee, Moonyong, 2020. "Simultaneous capture of acid gases from natural gas adopting ionic liquids: Challenges, recent developments, and prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    2. Song, Xueyi & Yuan, Junjie & Yang, Chen & Deng, Gaofeng & Wang, Zhichao & Gao, Jubao, 2023. "Carbon dioxide separation performance evaluation of amine-based versus choline-based deep eutectic solvents," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    3. Sun, Jiasi & Sato, Yuki & Sakai, Yuka & Kansha, Yasuki, 2023. "Ternary deep eutectic solvents: Evaluations based on how their physical properties affect energy consumption during post-combustion CO2 capture," Energy, Elsevier, vol. 270(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, Yingying & Ji, Xiaoyan & Xie, Yujiao & Lu, Xiaohua, 2018. "Thermodynamic analysis of CO2 separation from biogas with conventional ionic liquids," Applied Energy, Elsevier, vol. 217(C), pages 75-87.
    2. Xiao, Min & Liu, Helei & Gao, Hongxia & Olson, Wilfred & Liang, Zhiwu, 2019. "CO2 capture with hybrid absorbents of low viscosity imidazolium-based ionic liquids and amine," Applied Energy, Elsevier, vol. 235(C), pages 311-319.
    3. Ibrahim, Muna Hassan & Hayyan, Maan & Hashim, Mohd Ali & Hayyan, Adeeb, 2017. "The role of ionic liquids in desulfurization of fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 1534-1549.
    4. Li, Shuangjun & Deng, Shuai & Zhao, Li & Zhao, Ruikai & Yuan, Xiangzhou, 2021. "Thermodynamic carbon pump 2.0: Elucidating energy efficiency through the thermodynamic cycle," Energy, Elsevier, vol. 215(PB).
    5. Wang, Honglin & Ma, Chunyan & Yang, Zhuhong & Lu, Xiaohua & Ji, Xiaoyan, 2020. "Improving high-pressure water scrubbing through process integration and solvent selection for biogas upgrading," Applied Energy, Elsevier, vol. 276(C).
    6. Ma, Chunyan & Xie, Yujiao & Ji, Xiaoyan & Liu, Chang & Lu, Xiaohua, 2018. "Modeling, simulation and evaluation of biogas upgrading using aqueous choline chloride/urea," Applied Energy, Elsevier, vol. 229(C), pages 1269-1283.
    7. Edyta Słupek & Patrycja Makoś & Jacek Gębicki, 2020. "Theoretical and Economic Evaluation of Low-Cost Deep Eutectic Solvents for Effective Biogas Upgrading to Bio-Methane," Energies, MDPI, vol. 13(13), pages 1-19, July.
    8. Xie, Yujiao & Björkmalm, Johanna & Ma, Chunyan & Willquist, Karin & Yngvesson, Johan & Wallberg, Ola & Ji, Xiaoyan, 2018. "Techno-economic evaluation of biogas upgrading using ionic liquids in comparison with industrially used technology in Scandinavian anaerobic digestion plants," Applied Energy, Elsevier, vol. 227(C), pages 742-750.
    9. Xu, Ming-Xin & Wu, Hai-Bo & Wu, Ya-Chang & Wang, Han-Xiao & Ouyang, Hao-Dong & Lu, Qiang, 2021. "Design and evaluation of a novel system for the flue gas compression and purification from the oxy-fuel combustion process," Applied Energy, Elsevier, vol. 285(C).
    10. Huang, Hong & Peters, Ralf & Samsun, Remzi Can & Stolten, Detlef & He, Chang & Zhou, Xiantai, 2024. "A novel intercooling carbon dioxide capture process using ionic liquids with ultra-low energy consumption," Energy, Elsevier, vol. 301(C).
    11. Cheng, Jun & Wang, Yali & Liu, Niu & Hou, Wen & Zhou, Junhu, 2020. "Enhanced CO2 selectivity of mixed matrix membranes with carbonized Zn/Co zeolitic imidazolate frameworks," Applied Energy, Elsevier, vol. 272(C).
    12. Zhao, Ruikai & Deng, Shuai & Liu, Yinan & Zhao, Qing & He, Junnan & Zhao, Li, 2017. "Carbon pump: Fundamental theory and applications," Energy, Elsevier, vol. 119(C), pages 1131-1143.
    13. Xie, Yujiao & Ma, Chunyan & Lu, Xiaohua & Ji, Xiaoyan, 2016. "Evaluation of imidazolium-based ionic liquids for biogas upgrading," Applied Energy, Elsevier, vol. 175(C), pages 69-81.
    14. Zenon Ziobrowski & Adam Rotkegel, 2021. "Feasibility study of CO2/N2 separation intensification on supported ionic liquid membranes by commonly used impregnation methods," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 11(2), pages 297-312, April.
    15. Zhang, Yingying & Ji, Xiaoyan & Xie, Yujiao & Lu, Xiaohua, 2016. "Screening of conventional ionic liquids for carbon dioxide capture and separation," Applied Energy, Elsevier, vol. 162(C), pages 1160-1170.
    16. Hongtian Ge & Andrew J. Furlong & Scott Champagne & Robin W. Hughes & Jan B. Haelssig & Arturo Macchi, 2024. "Modelling and Design of a Novel Integrated Heat Exchange Reactor for Oxy-Fuel Combustion Flue Gas Deoxygenation," Energies, MDPI, vol. 17(6), pages 1-13, March.
    17. Wang, Tao & Yu, Wei & Le Moullec, Yann & Liu, Fei & Xiong, Yili & He, Hui & Lu, Jiahui & Hsu, Emily & Fang, Mengxiang & Luo, Zhongyang, 2017. "Solvent regeneration by novel direct non-aqueous gas stripping process for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 205(C), pages 23-32.
    18. Rongrong Zhai & Hongtao Liu & Hao Wu & Hai Yu & Yongping Yang, 2018. "Analysis of Integration of MEA-Based CO 2 Capture and Solar Energy System for Coal-Based Power Plants Based on Thermo-Economic Structural Theory," Energies, MDPI, vol. 11(5), pages 1-30, May.
    19. Kim, Junghwan & Lee, Jisook & Lee, Yunje & Kim, Huiyong & Kim, Eunseok & Lee, Kwang Soon, 2019. "Evaluation of aqueous polyamines as CO2 capture solvents," Energy, Elsevier, vol. 187(C).
    20. Yang, Hou-Yun & Wang, Yi-Xuan & He, Chuan-Shu & Qin, Yuan & Li, Wen-Qiang & Li, Wei-Hua & Mu, Yang, 2020. "Redox mediator-modified biocathode enables highly efficient microbial electro-synthesis of methane from carbon dioxide," Applied Energy, Elsevier, vol. 274(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:97:y:2018:i:c:p:436-455. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.