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Evaluation of aqueous polyamines as CO2 capture solvents

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  • Kim, Junghwan
  • Lee, Jisook
  • Lee, Yunje
  • Kim, Huiyong
  • Kim, Eunseok
  • Lee, Kwang Soon

Abstract

Aqueous alkanol amines or their blends are used as solvents for acid gas removal in most amine scrubbing processes. In this study, we selected six polyamines with three amine groups that have sufficiently high boiling temperatures and evaluated their potentials as CO2 capture solvents by investigating the CO2 vapor–liquid equilibrium, mass transfer rate, viscosity, and thermal stability. Among the tested polyamines, two were chosen and mixed with 2-(butylamino)ethanol and piperazine (PZ) to compensate for the inferior properties of each polyamine, and their properties were investigated. As a result, aqueous 2,6,10-trimethyl-2,6,10-triazaundecane mixed with a small amount of PZ showed a great potential as a new CO2 capture solvent in that it has a quite high absorption rate and thermal stability and a low reboiler duty.

Suggested Citation

  • Kim, Junghwan & Lee, Jisook & Lee, Yunje & Kim, Huiyong & Kim, Eunseok & Lee, Kwang Soon, 2019. "Evaluation of aqueous polyamines as CO2 capture solvents," Energy, Elsevier, vol. 187(C).
    • Handle: RePEc:eee:energy:v:187:y:2019:i:c:s0360544219315865
    DOI: 10.1016/j.energy.2019.115908
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    References listed on IDEAS

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    1. El Hadri, Nabil & Quang, Dang Viet & Goetheer, Earl L.V. & Abu Zahra, Mohammad R.M., 2017. "Aqueous amine solution characterization for post-combustion CO2 capture process," Applied Energy, Elsevier, vol. 185(P2), pages 1433-1449.
    2. Zhang, Yingying & Ji, Xiaoyan & Xie, Yujiao & Lu, Xiaohua, 2016. "Screening of conventional ionic liquids for carbon dioxide capture and separation," Applied Energy, Elsevier, vol. 162(C), pages 1160-1170.
    3. Zhang, Rui & Yang, Qi & Yu, Bing & Yu, Hai & Liang, Zhiwu, 2018. "Toward to efficient CO2 capture solvent design by analyzing the effect of substituent type connected to N-atom," Energy, Elsevier, vol. 144(C), pages 1064-1072.
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    1. Gautam, Ashish & Mondal, Monoj Kumar, 2024. "Post-combustion CO2 absorption-desorption performance of novel aqueous binary amine blend of Hexamethylenediamine (HMDA) and 2-Dimethylaminoethanol (DMAE)," Energy, Elsevier, vol. 296(C).
    2. Yang, Ming-Ke & Han, Yu & Zou, En-Bao & Chen, Wan & Peng, Xiao-Wan & Dong, Bao-Can & Sun, Chang-Yu & Liu, Bei & Chen, Guang-Jin, 2020. "Separation of IGCC syngas by using ZIF-8/dimethylacetamide slurry with high CO2 sorption capacity and sorption speed but low sorption heat," Energy, Elsevier, vol. 201(C).

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