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Recent advances in alkali-doped polybenzimidazole membranes for fuel cell applications

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  • Wu, Q.X.
  • Pan, Z.F.
  • An, L.

Abstract

Polybenzimidazole (PBI), with a well-known excellent thermal stability, has been recognized as an alternative for anion exchange membrane fuel cells (AEMFC), primarily because it can serve as an ionic conductor after doping with inorganic hydroxides (typically KOH/NaOH) and thus allows fuel cells to be operated at high temperatures (currently as high as 120 °C). In addition, alkali-doped PBI membranes also offer many other favored physiochemical properties, such as high ionic conductivity. The objective of this article is to provide a review of recent research on the alkali-doped PBI membranes and their applications in fuel cells, including mechanisms of ion conduction through the alkali-doped PBI membranes, stability of the PBI membranes doped with alkali, strategies aiming at improving the ionic conductivity of the PBI membranes doped with alkali, as well as the performance of alkali-doped PBI membrane based fuel cells. Additionally, future perspectives relating to the development of alkali-doped PBI membranes and their applications in fuel cells are also highlighted.

Suggested Citation

  • Wu, Q.X. & Pan, Z.F. & An, L., 2018. "Recent advances in alkali-doped polybenzimidazole membranes for fuel cell applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 89(C), pages 168-183.
    • Handle: RePEc:eee:rensus:v:89:y:2018:i:c:p:168-183
    DOI: 10.1016/j.rser.2018.03.024
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    References listed on IDEAS

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    1. Kongstein, O.E. & Berning, T. & Børresen, B. & Seland, F. & Tunold, R., 2007. "Polymer electrolyte fuel cells based on phosphoric acid doped polybenzimidazole (PBI) membranes," Energy, Elsevier, vol. 32(4), pages 418-422.
    2. An, L. & Zhao, T.S. & Li, Y.S., 2015. "Carbon-neutral sustainable energy technology: Direct ethanol fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1462-1468.
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    4. An, L. & Zhao, T.S. & Zeng, L., 2013. "Agar chemical hydrogel electrode binder for fuel-electrolyte-fed fuel cells," Applied Energy, Elsevier, vol. 109(C), pages 67-71.
    5. An, L. & Jung, C.Y., 2017. "Transport phenomena in direct borohydride fuel cells," Applied Energy, Elsevier, vol. 205(C), pages 1270-1282.
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    1. Wei, L. & Zeng, L. & Wu, M.C. & Fan, X.Z. & Zhao, T.S., 2019. "Seawater as an alternative to deionized water for electrolyte preparations in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    2. Pan, Zhefei & Bi, Yanding & An, Liang, 2019. "Performance characteristics of a passive direct ethylene glycol fuel cell with hydrogen peroxide as oxidant," Applied Energy, Elsevier, vol. 250(C), pages 846-854.
    3. Qiu, Diankai & Peng, Linfa & Lai, Xinmin & Ni, Meng & Lehnert, Werner, 2019. "Mechanical failure and mitigation strategies for the membrane in a proton exchange membrane fuel cell," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    4. Pan, Zhefei & Bi, Yanding & An, Liang, 2020. "A cost-effective and chemically stable electrode binder for alkaline-acid direct ethylene glycol fuel cells," Applied Energy, Elsevier, vol. 258(C).
    5. Jong-Hyeok Park & Jin-Soo Park, 2020. "KOH-doped Porous Polybenzimidazole Membranes for Solid Alkaline Fuel Cells," Energies, MDPI, vol. 13(3), pages 1-11, January.

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