IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v13y2020i5p1180-d328479.html
   My bibliography  Save this article

Synthesis and Characterization of Novel Green Hybrid Nanocomposites for Application as Proton Exchange Membranes in Direct Borohydride Fuel Cells

Author

Listed:
  • Marwa H. Gouda

    (Polymer Materials Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg Al-Arab City, Alexandria 21934, Egypt)

  • Noha A. Elessawy

    (Polymer Materials Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg Al-Arab City, Alexandria 21934, Egypt)

  • Diogo M.F. Santos

    (Center of Physics and Engineering of Advanced Materials (CeFEMA), Instituto Superior Técnico, Universidade de Lisboa, 1049-001 Lisbon, Portugal)

Abstract

Organic–inorganic nanocomposite membranes for potential application in direct borohydride fuel cells (DBFCs) are formulated from sulfonated poly(vinyl alcohol) (SPVA) with the incorporation of (PO 4 -TiO 2 ) and (SO 4 -TiO 2 ) nanotubes as doping agents. The functionalization of PVA to SPVA was done by using a 4-sulfophthalic acid as an ionic crosslinker and sulfonating agent. Morphological and structural characterization by transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), energy-dispersive X-ray spectroscopy (EDX) and X-ray diffraction (XRD) confirmed the successful synthesis of the doping agents and their incorporation into the polymer. The influence of PO 4 -TiO 2 and SO 4 -TiO 2 doping and their content on the physicochemical properties of the nanocomposite membranes was evaluated. Swelling degree and water uptake gradually reduced to 7% and 13%, respectively, with increasing doping agent concentration. Ion exchange capacity and ionic conductivity of the membrane with 3 wt.% doping agents were raised 5 and 7 times, respectively, compared to the undoped one. The thermal and oxidative stability and tensile strength also increased with the doping content. Furthermore, lower borohydride permeability (0.32 × 10 −6 cm 2 s −1 ) was measured for the membranes with higher amount of inorganic doping agents when compared to the undoped membrane (0.71 × 10 −5 cm 2 s −1 ) and Nafion ® 117 (0.40 × 10 −6 cm 2 s −1 ). These results pave the way for a green, simple and low-cost approach for the development of composite membranes for practical DBFCs.

Suggested Citation

  • Marwa H. Gouda & Noha A. Elessawy & Diogo M.F. Santos, 2020. "Synthesis and Characterization of Novel Green Hybrid Nanocomposites for Application as Proton Exchange Membranes in Direct Borohydride Fuel Cells," Energies, MDPI, vol. 13(5), pages 1-15, March.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:5:p:1180-:d:328479
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/13/5/1180/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/13/5/1180/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Santos, D.M.F. & Sequeira, C.A.C., 2011. "Sodium borohydride as a fuel for the future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3980-4001.
    2. Ma, Jia & Choudhury, Nurul A. & Sahai, Yogeshwar, 2010. "A comprehensive review of direct borohydride fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 183-199, January.
    3. An, L. & Jung, C.Y., 2017. "Transport phenomena in direct borohydride fuel cells," Applied Energy, Elsevier, vol. 205(C), pages 1270-1282.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Marwa H. Gouda & Tamer M. Tamer & Mohamed S. Mohy Eldin, 2021. "A Highly Selective Novel Green Cation Exchange Membrane Doped with Ceramic Nanotubes Material for Direct Methanol Fuel Cells," Energies, MDPI, vol. 14(18), pages 1-11, September.
    2. Marwa H. Gouda & Tamer M. Tamer & Abdelaziz H. Konsowa & Hassan A. Farag & Mohamed S. Mohy Eldin, 2021. "Organic-Inorganic Novel Green Cation Exchange Membranes for Direct Methanol Fuel Cells," Energies, MDPI, vol. 14(15), pages 1-11, August.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. An, L. & Jung, C.Y., 2017. "Transport phenomena in direct borohydride fuel cells," Applied Energy, Elsevier, vol. 205(C), pages 1270-1282.
    2. Santos, D.M.F. & Sequeira, C.A.C., 2011. "Sodium borohydride as a fuel for the future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3980-4001.
    3. Lejing Li & Zhuofeng Hu & Yongqiang Kang & Shiyu Cao & Liangpang Xu & Luo Yu & Lizhi Zhang & Jimmy C. Yu, 2023. "Electrochemical generation of hydrogen peroxide from a zinc gallium oxide anode with dual active sites," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    4. Erika Michela Dematteis & Jussara Barale & Marta Corno & Alessandro Sciullo & Marcello Baricco & Paola Rizzi, 2021. "Solid-State Hydrogen Storage Systems and the Relevance of a Gender Perspective," Energies, MDPI, vol. 14(19), pages 1-26, September.
    5. Boyacı San, Fatma Gül & Okur, Osman & İyigün Karadağ, Çiğdem & Isik-Gulsac, Isil & Okumuş, Emin, 2014. "Evaluation of operating conditions on DBFC (direct borohydride fuel cell) performance with PtRu anode catalyst by response surface method," Energy, Elsevier, vol. 71(C), pages 160-169.
    6. Jianfeng Mao & Duncan H. Gregory, 2015. "Recent Advances in the Use of Sodium Borohydride as a Solid State Hydrogen Store," Energies, MDPI, vol. 8(1), pages 1-24, January.
    7. Boyacı San, Fatma Gül & İyigün Karadağ, Çiğdem & Okur, Osman & Okumuş, Emin, 2016. "Optimization of the catalyst loading for the direct borohydride fuel cell," Energy, Elsevier, vol. 114(C), pages 214-224.
    8. Pan, Zhefei & Bi, Yanding & An, Liang, 2019. "Performance characteristics of a passive direct ethylene glycol fuel cell with hydrogen peroxide as oxidant," Applied Energy, Elsevier, vol. 250(C), pages 846-854.
    9. Netskina, O.V. & Komova, O.V. & Simagina, V.I. & Odegova, G.V. & Prosvirin, I.P. & Bulavchenko, O.A., 2016. "Aqueous-alkaline NaBH4 solution: The influence of storage duration of solutions on reduction and activity of cobalt catalysts," Renewable Energy, Elsevier, vol. 99(C), pages 1073-1081.
    10. Ould-Amara, Salem & Petit, Eddy & Granier, Dominique & Yot, Pascal G. & Demirci, Umit B., 2019. "Alkaline aqueous solution of sodium decahydro-closo-decaborate Na2B10H10 as liquid anodic fuel," Renewable Energy, Elsevier, vol. 143(C), pages 551-557.
    11. Zhao, Yi & Zhang, Zili & Wang, Hao & Qian, Xinfeng, 2016. "Absorption of carbon dioxide by hydrogen donor under atmospheric pressure," Renewable and Sustainable Energy Reviews, Elsevier, vol. 64(C), pages 84-90.
    12. Tamboli, Ashif H. & Chaugule, Avinash A. & Sheikh, Faheem A. & Chung, Wook-Jin & Kim, Hern, 2015. "Synthesis and application of CeO2–NiO loaded TiO2 nanofiber as novel catalyst for hydrogen production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 89(C), pages 568-575.
    13. Heng Zhu & Ximei Lv & Yuexu Wu & Wentao Wang & Yuping Wu & Shicheng Yan & Yuhui Chen, 2024. "Carbonate-carbonate coupling on platinum surface promotes electrochemical water oxidation to hydrogen peroxide," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    14. Takaya Ogawa & Mizutomo Takeuchi & Yuya Kajikawa, 2018. "Comprehensive Analysis of Trends and Emerging Technologies in All Types of Fuel Cells Based on a Computational Method," Sustainability, MDPI, vol. 10(2), pages 1-30, February.
    15. Ke, Yuzhi & Yuan, Wei & Zhou, Feikun & Guo, Wenwen & Li, Jinguang & Zhuang, Ziyi & Su, Xiaoqing & Lu, Biaowu & Zhao, Yonghao & Tang, Yong & Chen, Yu & Song, Jianli, 2021. "A critical review on surface-pattern engineering of nafion membrane for fuel cell applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    16. Andika, Riezqa & Nandiyanto, Asep Bayu Dani & Putra, Zulfan Adi & Bilad, Muhammad Roil & Kim, Young & Yun, Choa Mun & Lee, Moonyong, 2018. "Co-electrolysis for power-to-methanol applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 95(C), pages 227-241.
    17. Jiang, Hanchen & Qiang, Maoshan & Lin, Peng, 2016. "A topic modeling based bibliometric exploration of hydropower research," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 226-237.
    18. Wu, Q.X. & Pan, Z.F. & An, L., 2018. "Recent advances in alkali-doped polybenzimidazole membranes for fuel cell applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 89(C), pages 168-183.
    19. Pachauri, Rupendra Kumar & Chauhan, Yogesh K., 2015. "A study, analysis and power management schemes for fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1301-1319.
    20. Lui, Jade & Chen, Wei-Hsin & Tsang, Daniel C.W. & You, Siming, 2020. "A critical review on the principles, applications, and challenges of waste-to-hydrogen technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:13:y:2020:i:5:p:1180-:d:328479. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.