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Recent advances in synthesis strategies for biomass-derived high-energy-density jet fuels

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  • Fang, Zhenquan
  • Zhang, Xinghua
  • Zhuang, Xiuzheng
  • Ma, Longlong

Abstract

High-energy-density jet fuels enable volume/weight-limited aircraft to exhibit a higher speed, payload, and flying range. Lignocellulosic biomass, with renewability and sustainability, has gained prominence in high-energy-density jet fuel production. This review systematically summarizes the current progress in the regioselective synthesis of high-energy-density jet fuels through different C–C coupling strategies, such as aldol condensation, hydroalkylation/alkylation, the Diels–Alder reaction, oligomerization, reductive coupling, Robinson annulation, the Guerbet reaction, Michael addition, and cyclopropanation. First, the structure-property relationship of fuel molecules was analyzed. The components of high-energy-density jet fuels are then classified into linear/branched alkanes, mono/bi-cyclo-alkanes, polycyclic cyclo-alkanes, spiro/bridge cyclo-alkanes, branched bi/polycyclic cyclo-alkanes, and mixed cyclo-alkanes, based on their molecular characteristics. The synthesis of each fuel type is summarized based on the C–C coupling strategies and feedstocks used. Finally, the challenges of current high-energy-density jet-fuel synthetic strategies are described, along with the scope for future research. This review can guide the development of improved methods and schemes for the synthesis and upgrading of high-energy-density jet fuels.

Suggested Citation

  • Fang, Zhenquan & Zhang, Xinghua & Zhuang, Xiuzheng & Ma, Longlong, 2024. "Recent advances in synthesis strategies for biomass-derived high-energy-density jet fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 202(C).
    • Handle: RePEc:eee:rensus:v:202:y:2024:i:c:s1364032124004416
    DOI: 10.1016/j.rser.2024.114715
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