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Synthesis and Application of Heterogeneous Catalysts Based on Heteropolyacids for 5-Hydroxymethylfurfural Production from Glucose

Author

Listed:
  • Jéssica Siqueira Mancilha Nogueira

    (Department of Chemical Engineering, Engineering School of Lorena, University of São Paulo, 12602-810 Lorena/SP, Brazil)

  • João Paulo Alves Silva

    (Department of Chemical Engineering, Engineering School of Lorena, University of São Paulo, 12602-810 Lorena/SP, Brazil)

  • Solange I. Mussatto

    (Novo Nordisk Foundation Center for Biosustainability, Technical University of Denmark, 2800 Kongens Lyngby, Denmark)

  • Livia Melo Carneiro

    (Department of Chemical Engineering, Engineering School of Lorena, University of São Paulo, 12602-810 Lorena/SP, Brazil)

Abstract

This study aimed to evaluate the synthesis and application of heterogeneous catalysts based on heteropolyacids for 5-hydroxymethylfurfural (HMF) production from glucose. Initially, assays were carried out in order to establish the most favorable catalyst synthesis conditions. For such purpose, calcination temperature (300 or 500 °C), type of support (Nb 2 O 5 or Al 2 O 3 ), and active phase (H 3 PW 12 O 40 —HPW or H 3 PMo 12 O 40 —HPMo) were tested and combined based on Taguchi’s L 8 orthogonal array. As a result, HPW-Nb 2 O 5 calcined at 300 °C was selected as it presented optimal HMF production performance (9.5% yield). Subsequently, the reaction conditions capable of maximizing HMF production from glucose using the selected catalyst were established. In these experiments, different temperatures (160 or 200 °C), acetone-to-water ratios (1:1 or 3:1 v/v ), glucose concentrations (50 or 100 g/L), and catalyst concentrations (1 or 5% w/v ) were evaluated according to a Taguchi’s L 16 experimental design. The conditions that resulted in the highest HMF yield (40.8%) consisted of using 50 g/L of glucose at 160 °C, 1:1 ( v/v ) acetone-to-water ratio, and catalyst concentration of 5% ( w/v ). Recycling tests revealed that the catalyst can be used in four runs, which results in the same HMF yield (approx. 40%).

Suggested Citation

  • Jéssica Siqueira Mancilha Nogueira & João Paulo Alves Silva & Solange I. Mussatto & Livia Melo Carneiro, 2020. "Synthesis and Application of Heterogeneous Catalysts Based on Heteropolyacids for 5-Hydroxymethylfurfural Production from Glucose," Energies, MDPI, vol. 13(3), pages 1-17, February.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:3:p:655-:d:316232
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    References listed on IDEAS

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    1. da Conceição, Leyvison Rafael V. & Carneiro, Livia M. & Giordani, Domingos S. & de Castro, Heizir F., 2017. "Synthesis of biodiesel from macaw palm oil using mesoporous solid catalyst comprising 12-molybdophosphoric acid and niobia," Renewable Energy, Elsevier, vol. 113(C), pages 119-128.
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    Cited by:

    1. Hu, Lei & Wu, Zhen & Jiang, Yetao & Wang, Xiaoyu & He, Aiyong & Song, Jie & Xu, Jiming & Zhou, Shouyong & Zhao, Yijiang & Xu, Jiaxing, 2020. "Recent advances in catalytic and autocatalytic production of biomass-derived 5-hydroxymethylfurfural," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).

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