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Comparative Production of Bio-Oil from In Situ Catalytic Upgrading of Fast Pyrolysis of Lignocellulosic Biomass

Author

Listed:
  • Ali Abdulkhani

    (Department of Wood and Paper Sciences and Technology, Faculty of Natural Resources, University of Tehran, Karaj 1417466191, Iran)

  • Zahra Echresh Zadeh

    (Department of Chemical Engineering, University College London, Torrington Place, London WC1E 7JE, UK)

  • Solomon Gajere Bawa

    (Department of Chemical Engineering, University College London, Torrington Place, London WC1E 7JE, UK)

  • Fubao Sun

    (Key Laboratory of Industrial Biotechnology, Ministry of Education, School of Biotechnology, Jiangnan University, Wuxi 214122, China)

  • Meysam Madadi

    (Key Laboratory of Industrial Biotechnology, Ministry of Education, School of Biotechnology, Jiangnan University, Wuxi 214122, China)

  • Xueming Zhang

    (Beijing Key Laboratory of Lignocellulosic Chemistry, College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, China)

  • Basudeb Saha

    (School of Engineering, Lancaster University, Lancaster LA1 4YW, UK)

Abstract

Catalytic upgrading of fast pyrolysis bio-oil from two different types of lignocellulosic biomass was conducted using an H-ZSM-5 catalyst at different temperatures. A fixed-bed pyrolysis reactor has been used to perform in situ catalytic pyrolysis experiments at temperatures of 673, 773, and 873 K, where the catalyst (H-ZSM-5) has been mixed with wood chips or lignin, and the pyrolysis and upgrading processes have been performed simultaneously. The fractionation method has been employed to determine the chemical composition of bio-oil samples after catalytic pyrolysis experiments by gas chromatography with mass spectroscopy (GCMS). Other characterization techniques, e.g., water content, viscosity, elemental analysis, pH, and bomb calorimetry have been used, and the obtained results have been compared with the non-catalytic pyrolysis method. The highest bio-oil yield has been reported for bio-oil obtained from softwood at 873 K for both non-catalytic and catalytic bio-oil samples. The results indicate that the main effect of H-ZSM-5 has been observed on the amount of water and oxygen for all bio-oil samples at three different temperatures, where a significant reduction has been achieved compared to non-catalytic bio-oil samples. In addition, a significant viscosity reduction has been reported compared to non-catalytic bio-oil samples, and less viscous bio-oil samples have been produced by catalytic pyrolysis. Furthermore, the obtained results show that the heating values have been increased for upgraded bio-oil samples compared to non-catalytic bio-oil samples. The GCMS analysis of the catalytic bio-oil samples (H-ZSM-5) indicates that toluene and methanol have shown very similar behavior in extracting bio-oil samples in contrast to non-catalytic experiments. However, methanol performed better for extracting chemicals at a higher temperature.

Suggested Citation

  • Ali Abdulkhani & Zahra Echresh Zadeh & Solomon Gajere Bawa & Fubao Sun & Meysam Madadi & Xueming Zhang & Basudeb Saha, 2023. "Comparative Production of Bio-Oil from In Situ Catalytic Upgrading of Fast Pyrolysis of Lignocellulosic Biomass," Energies, MDPI, vol. 16(6), pages 1-19, March.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:6:p:2715-:d:1097204
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    References listed on IDEAS

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    1. Ha, Jeong-Myeong & Hwang, Kyung-Ran & Kim, Young-Min & Jae, Jungho & Kim, Kwang Ho & Lee, Hyung Won & Kim, Jae-Young & Park, Young-Kwon, 2019. "Recent progress in the thermal and catalytic conversion of lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 422-441.
    2. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part I: Chemical pathways and bio-oil upgrading," Renewable Energy, Elsevier, vol. 185(C), pages 483-505.
    3. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part II: Catalytic research," Renewable Energy, Elsevier, vol. 189(C), pages 315-338.
    4. Li, Chao & Li, Yuannian & Jiang, Yuchen & Zhang, Lijun & Zhang, Shu & Ding, Kuan & Li, Bin & Wang, Shuang & Hu, Xun, 2023. "Staged pyrolysis of biomass to probe the evolution of fractions of bio-oil," Energy, Elsevier, vol. 263(PD).
    5. Ansari, Khursheed B. & Kamal, Bushra & Beg, Sidra & Wakeel Khan, Md. Aquib & Khan, Mohd Shariq & Al Mesfer, Mohammed K. & Danish, Mohd., 2021. "Recent developments in investigating reaction chemistry and transport effects in biomass fast pyrolysis: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    6. Kumar, R. & Strezov, V. & Weldekidan, H. & He, J. & Singh, S. & Kan, T. & Dastjerdi, B., 2020. "Lignocellulose biomass pyrolysis for bio-oil production: A review of biomass pre-treatment methods for production of drop-in fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    7. Zahra Echresh Zadeh & Ali Abdulkhani & Basudeb Saha, 2020. "Characterization of Fast Pyrolysis Bio-Oil from Hardwood and Softwood Lignin," Energies, MDPI, vol. 13(4), pages 1-14, February.
    8. Echresh Zadeh, Zahra & Abdulkhani, Ali & Saha, Basudeb, 2021. "A comparative production and characterisation of fast pyrolysis bio-oil from Populus and Spruce woods," Energy, Elsevier, vol. 214(C).
    9. Jeong, Yeon Woo & Choi, Sang Kyu & Choi, Yeon Seok & Kim, Seock Joon, 2015. "Production of biocrude-oil from swine manure by fast pyrolysis and analysis of its characteristics," Renewable Energy, Elsevier, vol. 79(C), pages 14-19.
    10. Zhang, Yayun & Duan, Dengle & Lei, Hanwu & Villota, Elmar & Ruan, Roger, 2019. "Jet fuel production from waste plastics via catalytic pyrolysis with activated carbons," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
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    1. Madadi, Meysam & Elsayed, Mahdy & Song, Guojie & Bakr, Mahmoud M. & Qin, Yuanhang & Sun, Fubao & Abomohra, Abdelfatah, 2023. "Holistic lignocellulosic biorefinery approach for dual production of bioethanol and xylonic acid coupled with efficient dye removal," Renewable and Sustainable Energy Reviews, Elsevier, vol. 185(C).

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