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Hydrothermal carbonization of medical wastes and lignocellulosic biomass for solid fuel production from lab-scale to pilot-scale

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  • Shen, Yafei
  • Yu, Shili
  • Ge, Shun
  • Chen, Xingming
  • Ge, Xinlei
  • Chen, Mindong

Abstract

An alternative way has been proposed for the PVC-containing medical wastes valorization by co-hydrothermal carbonization (HTC) with lignocellulosic biomass. The organic-Cl in PVC can be converted to the inorganic-Cl via hydrolysis, defunctionalization, recondensation, and aromatization in the HTC process. Followed by the washing process with the condensed water, the inorganic-Cl with high water-solubility could be removed from the solid products (i.e. hydrochar). Lignin as a biomass component can significantly improve the dechlorination efficiency of PVC in the HTC process. Here, the dechlorination performance of lignocellulosic components is given as the following order: lignin > cellulose > hemicellulose. In addition, lignin can adjust the particle sizes of solid products by inhibiting the agglomeration in the order of lignin > hemicellulose > cellulose. In the pilot-scale HTC process, the addition of woodchips improves the dechlorination efficiency of hospital wastes (HW). The hydrochar particles with low-chlorine content and higher heating value could be used as a clean coal-alternative fuel.

Suggested Citation

  • Shen, Yafei & Yu, Shili & Ge, Shun & Chen, Xingming & Ge, Xinlei & Chen, Mindong, 2017. "Hydrothermal carbonization of medical wastes and lignocellulosic biomass for solid fuel production from lab-scale to pilot-scale," Energy, Elsevier, vol. 118(C), pages 312-323.
    • Handle: RePEc:eee:energy:v:118:y:2017:i:c:p:312-323
    DOI: 10.1016/j.energy.2016.12.047
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    6. Yang, Fangming & Liu, Xin & Li, Mengbin & Uguna, Clement & Wang, Wenlong & Sun, Chenggong, 2023. "Polyvinyl chloride (PVC) derived microporous carbons prepared via hydrothermal dechlorination and potassium hydroxide activation for efficient CO2 capture," Renewable and Sustainable Energy Reviews, Elsevier, vol. 180(C).
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    15. Govindarajan Venkatesh & Kodigal A. Gopinath & Kotha Sammi Reddy & Baddigam Sanjeeva Reddy & Mathyam Prabhakar & Cherukumalli Srinivasarao & Venugopalan Visha Kumari & Vinod Kumar Singh, 2022. "Characterization of Biochar Derived from Crop Residues for Soil Amendment, Carbon Sequestration and Energy Use," Sustainability, MDPI, vol. 14(4), pages 1-16, February.
    16. Kumar, Mayank & Olajire Oyedun, Adetoyese & Kumar, Amit, 2018. "A review on the current status of various hydrothermal technologies on biomass feedstock," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1742-1770.
    17. Florentios Economou & Irene Voukkali & Iliana Papamichael & Valentina Phinikettou & Pantelitsa Loizia & Vincenzo Naddeo & Paolo Sospiro & Marco Ciro Liscio & Christos Zoumides & Diana Mihaela Țîrcă & , 2024. "Turning Food Loss and Food Waste into Watts: A Review of Food Waste as an Energy Source," Energies, MDPI, vol. 17(13), pages 1-32, June.
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    19. Nallagatla Vinod Kumar & Gajanan L. Sawargaonkar & C. Sudha Rani & Ajay Singh & T. Ram Prakash & S. Triveni & Prasad J. Kamdi & Rajesh Pasumarthi & Rayapati Karthik & Bathula Venkatesh, 2023. "Comparative Analysis of Pigeonpea Stalk Biochar Characteristics and Energy Use under Different Biochar Production Methods," Sustainability, MDPI, vol. 15(19), pages 1-17, September.
    20. Yao, Zhongliang & Ma, Xiaoqian & Xiao, Zhiyuan, 2020. "The effect of two pretreatment levels on the pyrolysis characteristics of water hyacinth," Renewable Energy, Elsevier, vol. 151(C), pages 514-527.
    21. Tu, Ren & Sun, Yan & Wu, Yujian & Fan, Xudong & Cheng, Shuchao & Jiang, Enchen & Xu, Xiwei, 2021. "Selective production of furfural and phenols from rice husk: the influence of synergetic pretreatments with different order," Renewable Energy, Elsevier, vol. 168(C), pages 297-308.
    22. Da-Hee An & Dong-Chil Chang & Kwang-Soo Kim & Ji-Eun Lee & Young-Lok Cha & Jae-Hee Jeong & Ji-Bong Choi & Soo-Yeon Kim, 2023. "Miscanthus-Derived Biochar Enhanced Soil Fertility and Soybean Growth in Upland Soil," Agriculture, MDPI, vol. 13(9), pages 1-12, September.
    23. Gianluigi Farru & Judy A. Libra & Kyoung S. Ro & Carla Cannas & Claudio Cara & Aldo Muntoni & Martina Piredda & Giovanna Cappai, 2023. "Valorization of Face Masks Produced during COVID-19 Pandemic through Hydrothermal Carbonization (HTC): A Preliminary Study," Sustainability, MDPI, vol. 15(12), pages 1-15, June.

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