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Ultrasound assisted metal chloride treatment of sugarcane bagasse for bioethanol production

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  • Ramadoss, Govindarajan
  • Muthukumar, Karuppan

Abstract

This study presents the ultrasound assisted metal chloride treatment of sugarcane bagasse (SCB) for bioethanol production. The operating parameters pertaining to pretreatment and enzymatic saccharification were optimized. The ultrasound assisted FeCl3 pretreatment (UAFP) showed the maximum cellulose recovery and delignification of 94.94 and 79.42%, respectively, at the optimum conditions (particle size 0.274 mm, H2O2 concentration 1.5% v/v, substrate dosage 3 g, ultrasound time 75 min, molar ratio of FeCl3 and H2O2 1:100 and temperature 60 °C). Enzymatic saccharification of SCB obtained from UAFP showed 96% glucan digestibility (DG) with 15 FPU cellulase and 30 IU β-glucosidase. The hydrolyzate obtained was fermented using Saccharomyces cerevisiae and about 93% theoretical ethanol yield was achieved at the end of 72 h of fermentation. The structural changes of native and pretreated SCB were investigated by Fourier transform infrared spectroscopic analysis (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM).

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  • Ramadoss, Govindarajan & Muthukumar, Karuppan, 2016. "Ultrasound assisted metal chloride treatment of sugarcane bagasse for bioethanol production," Renewable Energy, Elsevier, vol. 99(C), pages 1092-1102.
    • Handle: RePEc:eee:renene:v:99:y:2016:i:c:p:1092-1102
    DOI: 10.1016/j.renene.2016.08.003
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    References listed on IDEAS

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    1. Chen, Wei-Hsin & Tu, Yi-Jian & Sheen, Herng-Kuang, 2011. "Disruption of sugarcane bagasse lignocellulosic structure by means of dilute sulfuric acid pretreatment with microwave-assisted heating," Applied Energy, Elsevier, vol. 88(8), pages 2726-2734, August.
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    1. Fu, Yansong & Gao, Hairong & Yu, Hua & Yang, Qiaomei & Peng, Hao & Liu, Peng & Li, Yuqi & Hu, Zhen & Zhang, Ran & Li, Jingyang & Qi, Zhi & Wang, Lingqiang & Peng, Liangcai & Wang, Yanting, 2022. "Specific lignin and cellulose depolymerization of sugarcane bagasse for maximum bioethanol production under optimal chemical fertilizer pretreatment with hemicellulose retention and liquid recycling," Renewable Energy, Elsevier, vol. 200(C), pages 1371-1381.
    2. Wang, Ping & Liu, Chaoqi & Chang, Juan & Yin, Qingqiang & Huang, Weiwei & Liu, Yang & Dang, Xiaowei & Gao, Tianzeng & Lu, Fushan, 2019. "Effect of physicochemical pretreatments plus enzymatic hydrolysis on the composition and morphologic structure of corn straw," Renewable Energy, Elsevier, vol. 138(C), pages 502-508.
    3. Saha, Koel & R, Uma Maheswari & Sikder, Jaya & Chakraborty, Sudip & da Silva, Silvio Silverio & dos Santos, Julio Cesar, 2017. "Membranes as a tool to support biorefineries: Applications in enzymatic hydrolysis, fermentation and dehydration for bioethanol production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 873-890.

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