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Hydrolysis characteristics of sugarcane bagasse pretreated by dilute acid solution in a microwave irradiation environment

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  • Chen, Wei-Hsin
  • Ye, Song-Ching
  • Sheen, Herng-Kuang

Abstract

Pretreatment of lignocellulosic biomass is of the utmost importance for the development of bioethanol because of the abundance and low cost of lignocelluloses. To figure out the hydrolysis characteristics of sugarcane bagasse in a microwave irradiation environment, the biomass is pretreated by a dilute sulfuric acid solution at 180°C for 30min, with the concentration ranging from 0 to 0.02M. A variety of analyses, including fiber analysis, TGA, XRD, FTIR and HPLC, are employed to aid in understanding the physical and chemical characteristics of residual solid particles and solutions. A higher concentration is conducive to destroying bagasse; however, the buffering capacity possessed by the biomass is also observed in the pretreatment. The experimental results indicate that around 40–44wt% of bagasse is degraded from the pretreatment in which around 80–98% of hemicellulose is hydrolyzed. In contrast, crystalline cellulose and lignin are hardly affected by the pretreatment. The maximum yields of xylose and glucose as well as the minimum furfural selectivity occur at the acid concentration of 0.005M. Consequently, the aforementioned concentration is recommended for bagasse pretreatment and bioethanol production.

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  • Chen, Wei-Hsin & Ye, Song-Ching & Sheen, Herng-Kuang, 2012. "Hydrolysis characteristics of sugarcane bagasse pretreated by dilute acid solution in a microwave irradiation environment," Applied Energy, Elsevier, vol. 93(C), pages 237-244.
    • Handle: RePEc:eee:appene:v:93:y:2012:i:c:p:237-244
    DOI: 10.1016/j.apenergy.2011.12.014
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    1. Chen, Wei-Hsin & Tu, Yi-Jian & Sheen, Herng-Kuang, 2011. "Disruption of sugarcane bagasse lignocellulosic structure by means of dilute sulfuric acid pretreatment with microwave-assisted heating," Applied Energy, Elsevier, vol. 88(8), pages 2726-2734, August.
    2. Zhou, Adrian & Thomson, Elspeth, 2009. "The development of biofuels in Asia," Applied Energy, Elsevier, vol. 86(Supplemen), pages 11-20, November.
    3. Chen, Wei-Hsin & Kuo, Po-Chih, 2010. "A study on torrefaction of various biomass materials and its impact on lignocellulosic structure simulated by a thermogravimetry," Energy, Elsevier, vol. 35(6), pages 2580-2586.
    4. Prabhakar, S.V.R.K. & Elder, Mark, 2009. "Biofuels and resource use efficiency in developing Asia: Back to basics," Applied Energy, Elsevier, vol. 86(Supplemen), pages 30-36, November.
    5. Quintero, J.A. & Montoya, M.I. & Sánchez, O.J. & Giraldo, O.H. & Cardona, C.A., 2008. "Fuel ethanol production from sugarcane and corn: Comparative analysis for a Colombian case," Energy, Elsevier, vol. 33(3), pages 385-399.
    6. Monte, J.R. & Brienzo, M. & Milagres, A.M.F., 2011. "Utilization of pineapple stem juice to enhance enzyme-hydrolytic efficiency for sugarcane bagasse after an optimized pre-treatment with alkaline peroxide," Applied Energy, Elsevier, vol. 88(1), pages 403-408, January.
    7. Phalan, Ben, 2009. "The social and environmental impacts of biofuels in Asia: An overview," Applied Energy, Elsevier, vol. 86(Supplemen), pages 21-29, November.
    8. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Torrefaction and co-torrefaction characterization of hemicellulose, cellulose and lignin as well as torrefaction of some basic constituents in biomass," Energy, Elsevier, vol. 36(2), pages 803-811.
    9. Saga, Kiyotaka & Imou, Kenji & Yokoyama, Shinya & Minowa, Tomoaki, 2010. "Net energy analysis of bioethanol production system from high-yield rice plant in Japan," Applied Energy, Elsevier, vol. 87(7), pages 2164-2168, July.
    10. Chen, Wei-Hsin & Cheng, Wen-Yi & Lu, Ke-Miao & Huang, Ying-Pin, 2011. "An evaluation on improvement of pulverized biomass property for solid fuel through torrefaction," Applied Energy, Elsevier, vol. 88(11), pages 3636-3644.
    11. Balat, Mustafa & Balat, Havva, 2009. "Recent trends in global production and utilization of bio-ethanol fuel," Applied Energy, Elsevier, vol. 86(11), pages 2273-2282, November.
    12. Demirbas, Ayhan, 2011. "Competitive liquid biofuels from biomass," Applied Energy, Elsevier, vol. 88(1), pages 17-28, January.
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