IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v210y2023icp196-202.html
   My bibliography  Save this article

Cationic defects coupled with trace Pt under the assistance of corrosive engineering for efficient hydrogen electrocatalysis with large current density

Author

Listed:
  • Wu, Zexing
  • Chen, Zhi
  • Xu, Kunhan
  • Li, Bin
  • Li, Zhenjiang
  • Xu, Guangrui
  • Xiao, Weiping
  • Ma, Tianyi
  • Fu, Yunlei
  • Wang, Lei

Abstract

Exploiting efficient and durable samples toward electrocatalytic hydrogen evolution reaction (HER) with large current density is critical for commercializing hydrogen energy. Herein, Ni, Fe layered double hydroxide with cationic defects and trace Pt (Pt/D-NiFe LDH) on NiFe foam is constructed under the assistance of corrosion engineering and alkaline etching at ambient conditions. The porous nanostructure, leaf-like morphology and coexistence of defects and Pt endow the as-designed sample presents a remarkable electrocatalytic activity for HER in alkaline media with low overpotentials with 28, 163 and 217 mV to drive 10, 500 and 1000 mA cm−2. Remarkably, the catalyst enables the two-electrode electrolyzer with low voltages 1.65 and 1.72 V to attain 500 and 1000 mA cm−2. It also can be powered by solar, thermal and wind sustainable energies. The as-synthesized Pt/D-NiFe LDH has excellent catalytic activities and stability in alkaline seawater and neutral electrolytes with small overpotentials.

Suggested Citation

  • Wu, Zexing & Chen, Zhi & Xu, Kunhan & Li, Bin & Li, Zhenjiang & Xu, Guangrui & Xiao, Weiping & Ma, Tianyi & Fu, Yunlei & Wang, Lei, 2023. "Cationic defects coupled with trace Pt under the assistance of corrosive engineering for efficient hydrogen electrocatalysis with large current density," Renewable Energy, Elsevier, vol. 210(C), pages 196-202.
    • Handle: RePEc:eee:renene:v:210:y:2023:i:c:p:196-202
    DOI: 10.1016/j.renene.2023.04.037
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148123004871
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2023.04.037?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chi Zhang & Yuting Luo & Junyang Tan & Qiangmin Yu & Fengning Yang & Zhiyuan Zhang & Liusi Yang & Hui-Ming Cheng & Bilu Liu, 2020. "High-throughput production of cheap mineral-based two-dimensional electrocatalysts for high-current-density hydrogen evolution," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    2. Colleen Jackson & Graham T. Smith & David W. Inwood & Andrew S. Leach & Penny S. Whalley & Mauro Callisti & Tomas Polcar & Andrea E. Russell & Pieter Levecque & Denis Kramer, 2017. "Electronic metal-support interaction enhanced oxygen reduction activity and stability of boron carbide supported platinum," Nature Communications, Nature, vol. 8(1), pages 1-11, August.
    3. Yuting Luo & Lei Tang & Usman Khan & Qiangmin Yu & Hui-Ming Cheng & Xiaolong Zou & Bilu Liu, 2019. "Morphology and surface chemistry engineering toward pH-universal catalysts for hydrogen evolution at high current density," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    4. Heming Liu & Ruikuan Xie & Yuting Luo & Zhicheng Cui & Qiangmin Yu & Zhiqiang Gao & Zhiyuan Zhang & Fengning Yang & Xin Kang & Shiyu Ge & Shaohai Li & Xuefeng Gao & Guoliang Chai & Le Liu & Bilu Liu, 2022. "Dual interfacial engineering of a Chevrel phase electrode material for stable hydrogen evolution at 2500 mA cm−2," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Lingbin Xie & Longlu Wang & Xia Liu & Jianmei Chen & Xixing Wen & Weiwei Zhao & Shujuan Liu & Qiang Zhao, 2024. "Flexible tungsten disulfide superstructure engineering for efficient alkaline hydrogen evolution in anion exchange membrane water electrolysers," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    2. Chenyu Li & Zhijie Wang & Mingda Liu & Enze Wang & Bolun Wang & Longlong Xu & Kaili Jiang & Shoushan Fan & Yinghui Sun & Jia Li & Kai Liu, 2022. "Ultrafast self-heating synthesis of robust heterogeneous nanocarbides for high current density hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    3. Heming Liu & Ruikuan Xie & Yuting Luo & Zhicheng Cui & Qiangmin Yu & Zhiqiang Gao & Zhiyuan Zhang & Fengning Yang & Xin Kang & Shiyu Ge & Shaohai Li & Xuefeng Gao & Guoliang Chai & Le Liu & Bilu Liu, 2022. "Dual interfacial engineering of a Chevrel phase electrode material for stable hydrogen evolution at 2500 mA cm−2," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    4. Rui Yao & Kaian Sun & Kaiyang Zhang & Yun Wu & Yujie Du & Qiang Zhao & Guang Liu & Chen Chen & Yuhan Sun & Jinping Li, 2024. "Stable hydrogen evolution reaction at high current densities via designing the Ni single atoms and Ru nanoparticles linked by carbon bridges," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    5. Yang Gao & Yurui Xue & Lu Qi & Chengyu Xing & Xuchen Zheng & Feng He & Yuliang Li, 2022. "Rhodium nanocrystals on porous graphdiyne for electrocatalytic hydrogen evolution from saline water," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    6. Xin Kang & Fengning Yang & Zhiyuan Zhang & Heming Liu & Shiyu Ge & Shuqi Hu & Shaohai Li & Yuting Luo & Qiangmin Yu & Zhibo Liu & Qiang Wang & Wencai Ren & Chenghua Sun & Hui-Ming Cheng & Bilu Liu, 2023. "A corrosion-resistant RuMoNi catalyst for efficient and long-lasting seawater oxidation and anion exchange membrane electrolyzer," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    7. Fangqing Wang & Peichao Zou & Yangyang Zhang & Wenli Pan & Ying Li & Limin Liang & Cong Chen & Hui Liu & Shijian Zheng, 2023. "Activating lattice oxygen in high-entropy LDH for robust and durable water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    8. Luqi Wang & Yixin Hao & Liming Deng & Feng Hu & Sheng Zhao & Linlin Li & Shengjie Peng, 2022. "Rapid complete reconfiguration induced actual active species for industrial hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    9. Yudi Zhang & Kathryn E. Arpino & Qun Yang & Naoki Kikugawa & Dmitry A. Sokolov & Clifford W. Hicks & Jian Liu & Claudia Felser & Guowei Li, 2022. "Observation of a robust and active catalyst for hydrogen evolution under high current densities," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    10. Jiayi Chen & Mohammed Aliasgar & Fernando Buendia Zamudio & Tianyu Zhang & Yilin Zhao & Xu Lian & Lan Wen & Haozhou Yang & Wenping Sun & Sergey M. Kozlov & Wei Chen & Lei Wang, 2023. "Diversity of platinum-sites at platinum/fullerene interface accelerates alkaline hydrogen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    11. Kamran Dastafkan & Xiangjian Shen & Rosalie K. Hocking & Quentin Meyer & Chuan Zhao, 2023. "Monometallic interphasic synergy via nano-hetero-interfacing for hydrogen evolution in alkaline electrolytes," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    12. Qiangmin Yu & Zhiyuan Zhang & Siyao Qiu & Yuting Luo & Zhibo Liu & Fengning Yang & Heming Liu & Shiyu Ge & Xiaolong Zou & Baofu Ding & Wencai Ren & Hui-Ming Cheng & Chenghua Sun & Bilu Liu, 2021. "A Ta-TaS2 monolith catalyst with robust and metallic interface for superior hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    13. Dandan Guo & Jun Chi & Hongmei Yu & Guang Jiang & Zhigang Shao, 2022. "Self-Supporting NiFe Layered Double Hydroxide “Nanoflower” Cluster Anode Electrode for an Efficient Alkaline Anion Exchange Membrane Water Electrolyzer," Energies, MDPI, vol. 15(13), pages 1-14, June.
    14. Chenlu Wang & Liping Zhou & Chengzhe Liu & Jiaming Qiao & Xinrui Han & Luyang Wang & Yaxi Liu & Bi Xu & Qinfang Qiu & Zizhuo Zhang & Jiale Wang & Xiaoya Zhou & Mengqi Zeng & Lilei Yu & Lei Fu, 2024. "Pt nanoshells with a high NIR-II photothermal conversion efficiency mediates multimodal neuromodulation against ventricular arrhythmias," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    15. Wenyao Chen & Junbo Cao & Jia Yang & Yueqiang Cao & Hao Zhang & Zheng Jiang & Jing Zhang & Gang Qian & Xinggui Zhou & De Chen & Weikang Yuan & Xuezhi Duan, 2021. "Molecular-level insights into the electronic effects in platinum-catalyzed carbon monoxide oxidation," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    16. Wei Liu & Xiting Wang & Fan Wang & Kaifa Du & Zhaofu Zhang & Yuzheng Guo & Huayi Yin & Dihua Wang, 2021. "A durable and pH-universal self-standing MoC–Mo2C heterojunction electrode for efficient hydrogen evolution reaction," Nature Communications, Nature, vol. 12(1), pages 1-10, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:210:y:2023:i:c:p:196-202. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.