IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v8y2017i1d10.1038_ncomms15802.html
   My bibliography  Save this article

Electronic metal-support interaction enhanced oxygen reduction activity and stability of boron carbide supported platinum

Author

Listed:
  • Colleen Jackson

    (HySA/Catalysis, Catalysis Institute, University of Cape Town, Corner of Madiba Circle and South Lane)

  • Graham T. Smith

    (HySA/Catalysis, Catalysis Institute, University of Cape Town, Corner of Madiba Circle and South Lane
    Engineering Sciences, University of Southampton)

  • David W. Inwood

    (University of Southampton)

  • Andrew S. Leach

    (University of Southampton)

  • Penny S. Whalley

    (University of Southampton)

  • Mauro Callisti

    (Engineering Sciences, University of Southampton)

  • Tomas Polcar

    (Engineering Sciences, University of Southampton)

  • Andrea E. Russell

    (University of Southampton)

  • Pieter Levecque

    (HySA/Catalysis, Catalysis Institute, University of Cape Town, Corner of Madiba Circle and South Lane)

  • Denis Kramer

    (Engineering Sciences, University of Southampton)

Abstract

Catalysing the reduction of oxygen in acidic media is a standing challenge. Although activity of platinum, the most active metal, can be substantially improved by alloying, alloy stability remains a concern. Here we report that platinum nanoparticles supported on graphite-rich boron carbide show a 50–100% increase in activity in acidic media and improved cycle stability compared to commercial carbon supported platinum nanoparticles. Transmission electron microscopy and x-ray absorption fine structure analysis confirm similar platinum nanoparticle shapes, sizes, lattice parameters, and cluster packing on both supports, while x-ray photoelectron and absorption spectroscopy demonstrate a change in electronic structure. This shows that purely electronic metal-support interactions can significantly improve oxygen reduction activity without inducing shape, alloying or strain effects and without compromising stability. Optimizing the electronic interaction between the catalyst and support is, therefore, a promising approach for advanced electrocatalysts where optimizing the catalytic nanoparticles themselves is constrained by other concerns.

Suggested Citation

  • Colleen Jackson & Graham T. Smith & David W. Inwood & Andrew S. Leach & Penny S. Whalley & Mauro Callisti & Tomas Polcar & Andrea E. Russell & Pieter Levecque & Denis Kramer, 2017. "Electronic metal-support interaction enhanced oxygen reduction activity and stability of boron carbide supported platinum," Nature Communications, Nature, vol. 8(1), pages 1-11, August.
    • Handle: RePEc:nat:natcom:v:8:y:2017:i:1:d:10.1038_ncomms15802
    DOI: 10.1038/ncomms15802
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/ncomms15802
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/ncomms15802?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chenlu Wang & Liping Zhou & Chengzhe Liu & Jiaming Qiao & Xinrui Han & Luyang Wang & Yaxi Liu & Bi Xu & Qinfang Qiu & Zizhuo Zhang & Jiale Wang & Xiaoya Zhou & Mengqi Zeng & Lilei Yu & Lei Fu, 2024. "Pt nanoshells with a high NIR-II photothermal conversion efficiency mediates multimodal neuromodulation against ventricular arrhythmias," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    2. Wenyao Chen & Junbo Cao & Jia Yang & Yueqiang Cao & Hao Zhang & Zheng Jiang & Jing Zhang & Gang Qian & Xinggui Zhou & De Chen & Weikang Yuan & Xuezhi Duan, 2021. "Molecular-level insights into the electronic effects in platinum-catalyzed carbon monoxide oxidation," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    3. Jiayi Chen & Mohammed Aliasgar & Fernando Buendia Zamudio & Tianyu Zhang & Yilin Zhao & Xu Lian & Lan Wen & Haozhou Yang & Wenping Sun & Sergey M. Kozlov & Wei Chen & Lei Wang, 2023. "Diversity of platinum-sites at platinum/fullerene interface accelerates alkaline hydrogen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    4. Wu, Zexing & Chen, Zhi & Xu, Kunhan & Li, Bin & Li, Zhenjiang & Xu, Guangrui & Xiao, Weiping & Ma, Tianyi & Fu, Yunlei & Wang, Lei, 2023. "Cationic defects coupled with trace Pt under the assistance of corrosive engineering for efficient hydrogen electrocatalysis with large current density," Renewable Energy, Elsevier, vol. 210(C), pages 196-202.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:8:y:2017:i:1:d:10.1038_ncomms15802. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.