IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v256y2019ics0306261919315971.html
   My bibliography  Save this article

New insights into carbon deposition mechanism of nickel/yttrium-stabilized zirconia cermet from methane by in situ investigation

Author

Listed:
  • Yu, Fangyong
  • Xiao, Jie
  • Zhang, Yapeng
  • Cai, Weizi
  • Xie, Yongmin
  • Yang, Naitao
  • Liu, Jiang
  • Liu, Meilin

Abstract

In situ thermal expansion and in situ X-ray powder diffraction (XRD) are used to investigate the dynamic process of the interaction between Ni and methane at high temperature. Thermal expansion results show that it takes 68 min for the Ni and yttrium-stabilized zirconia (Ni-YSZ) cermet at 650 °C to collapse, while it takes only 14 min at 800 °C when exposed to methane. The crystal structure change of Ni, when it interacts with methane at high temperature, is directly observed by in situ XRD characterization. The results of scanning electron microscopy and transmission electron microscopy show a large number of carbon fibers on Ni particles in methane at 650 °C, whereas a considerable amount of encapsulating carbon and few carbon fibers are noted at 800 °C. On the basis of the experimental results, the deactivation mechanisms of Ni-YSZ cermet in methane at 650 °C and 800 °C are elucidated, respectively.

Suggested Citation

  • Yu, Fangyong & Xiao, Jie & Zhang, Yapeng & Cai, Weizi & Xie, Yongmin & Yang, Naitao & Liu, Jiang & Liu, Meilin, 2019. "New insights into carbon deposition mechanism of nickel/yttrium-stabilized zirconia cermet from methane by in situ investigation," Applied Energy, Elsevier, vol. 256(C).
  • Handle: RePEc:eee:appene:v:256:y:2019:i:c:s0306261919315971
    DOI: 10.1016/j.apenergy.2019.113910
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261919315971
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2019.113910?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Liu, Ming & van der Kleij, A. & Verkooijen, A.H.M. & Aravind, P.V., 2013. "An experimental study of the interaction between tar and SOFCs with Ni/GDC anodes," Applied Energy, Elsevier, vol. 108(C), pages 149-157.
    2. Lei, Libin & Keels, Jayson M. & Tao, Zetian & Zhang, Jihao & Chen, Fanglin, 2018. "Thermodynamic and experimental assessment of proton conducting solid oxide fuel cells with internal methane steam reforming," Applied Energy, Elsevier, vol. 224(C), pages 280-288.
    3. Steil, M.C. & Nobrega, S.D. & Georges, S. & Gelin, P. & Uhlenbruck, S. & Fonseca, F.C., 2017. "Durable direct ethanol anode-supported solid oxide fuel cell," Applied Energy, Elsevier, vol. 199(C), pages 180-186.
    4. Seungdoo Park & John M. Vohs & Raymond J. Gorte, 2000. "Direct oxidation of hydrocarbons in a solid-oxide fuel cell," Nature, Nature, vol. 404(6775), pages 265-267, March.
    5. Chen, Huili & Wang, Fen & Wang, Wei & Chen, Daifen & Li, Si-Dian & Shao, Zongping, 2016. "H2S poisoning effect and ways to improve sulfur tolerance of nickel cermet anodes operating on carbonaceous fuels," Applied Energy, Elsevier, vol. 179(C), pages 765-777.
    6. Thieu, Cam-Anh & Ji, Ho-Il & Kim, Hyoungchul & Yoon, Kyung Joong & Lee, Jong-Ho & Son, Ji-Won, 2019. "Palladium incorporation at the anode of thin-film solid oxide fuel cells and its effect on direct utilization of butane fuel at 600 °C," Applied Energy, Elsevier, vol. 243(C), pages 155-164.
    7. E. Perry Murray & T. Tsai & S. A. Barnett, 1999. "A direct-methane fuel cell with a ceria-based anode," Nature, Nature, vol. 400(6745), pages 649-651, August.
    8. Singha, Rajib Kumar & Shukla, Astha & Yadav, Aditya & Adak, Shubhadeep & Iqbal, Zafar & Siddiqui, Nazia & Bal, Rajaram, 2016. "Energy efficient methane tri-reforming for synthesis gas production over highly coke resistant nanocrystalline Ni–ZrO2 catalyst," Applied Energy, Elsevier, vol. 178(C), pages 110-125.
    9. Wu, Hao & Xiao, Jie & Zeng, Xiaoyuan & Li, Xue & Yang, Jing & Zou, Yuling & Liu, Sudongfang & Dong, Peng & Zhang, Yingjie & Liu, Jiang, 2019. "A high performance direct carbon solid oxide fuel cell – A green pathway for brown coal utilization," Applied Energy, Elsevier, vol. 248(C), pages 679-687.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Jincheng & Zhao, Kai & Zhao, Jishi & Li, Jun & Liu, Yihui & Chen, Dongchu & Xu, Qing & Chen, Min, 2022. "A NiMo-YSZ catalyst support layer for regenerable solid oxide fuel cells running on isooctane," Applied Energy, Elsevier, vol. 326(C).
    2. Liang, Bo & Yao, Yue & Guo, Jin & Yang, Huazheng & Liang, Jiajiang & Zhao, Zhijiang & Wu, Gang & Zhan, Yuedong & Zhao, Xiaobo & Tao, Tao & Yao, Yingbang & Lu, Shengguo & Ruirui, Zhao, 2022. "Propane-fuelled microtubular solid oxide fuel cell stack electrically connected by an anodic rectangular window," Applied Energy, Elsevier, vol. 309(C).
    3. Wang, Chao & Liao, Mingzheng & Jiang, Zhiqiang & Liang, Bo & Weng, Jiahong & Song, Qingbin & Zhao, Ming & Chen, Ying & Lei, Libin, 2022. "Sorption-enhanced propane partial oxidation hydrogen production for solid oxide fuel cell (SOFC) applications," Energy, Elsevier, vol. 247(C).
    4. Fukunaga, Akihiko & Kato, Asami & Hara, Yuki & Matsumoto, Takaya, 2023. "Dehydrogenation of methylcyclohexane using solid oxide fuel cell – A smart energy conversion," Applied Energy, Elsevier, vol. 348(C).
    5. Li, Bangxin & Irvine, John T.S. & Ni, Jiupai & Ni, Chengsheng, 2022. "High-performance and durable alcohol-fueled symmetrical solid oxide fuel cell based on ferrite perovskite electrode," Applied Energy, Elsevier, vol. 306(PB).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yue Teng & Ho Yeon Lee & Haesu Lee & Yoon Ho Lee, 2022. "Effect of Sputtering Pressure on the Nanostructure and Residual Stress of Thin-Film YSZ Electrolyte," Sustainability, MDPI, vol. 14(15), pages 1-9, August.
    2. Berre Kumuk & Nisa Nur Atak & Battal Dogan & Salih Ozer & Pinar Demircioglu & Ismail Bogrekci, 2024. "Numerical and Thermodynamic Analysis of the Effect of Operating Temperature in Methane-Fueled SOFC," Energies, MDPI, vol. 17(11), pages 1-17, May.
    3. Silva-Mosqueda, Dulce María & Elizalde-Blancas, Francisco & Pumiglia, Davide & Santoni, Francesca & Boigues-Muñoz, Carlos & McPhail, Stephen J., 2019. "Intermediate temperature solid oxide fuel cell under internal reforming: Critical operating conditions, associated problems and their impact on the performance," Applied Energy, Elsevier, vol. 235(C), pages 625-640.
    4. Massimiliano Cimenti & Josephine M. Hill, 2009. "Direct Utilization of Liquid Fuels in SOFC for Portable Applications: Challenges for the Selection of Alternative Anodes," Energies, MDPI, vol. 2(2), pages 1-34, June.
    5. Mohamad Fairus Rabuni & Tao Li & Mohd Hafiz Dzarfan Othman & Faidzul Hakim Adnan & Kang Li, 2023. "Progress in Solid Oxide Fuel Cells with Hydrocarbon Fuels," Energies, MDPI, vol. 16(17), pages 1-36, September.
    6. Fan, Liyuan & Li, Chao'en & van Biert, Lindert & Zhou, Shou-Han & Tabish, Asif Nadeem & Mokhov, Anatoli & Aravind, Purushothaman Vellayani & Cai, Weiwei, 2022. "Advances on methane reforming in solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 166(C).
    7. Sariboğa, Vedat & Öksüzömer, Faruk, 2012. "The investigation of active Ni/YSZ interlayer for Cu-based direct-methane solid oxide fuel cells," Applied Energy, Elsevier, vol. 93(C), pages 707-721.
    8. Xu, Han & Dang, Zheng, 2016. "Lattice Boltzmann modeling of carbon deposition in porous anode of a solid oxide fuel cell with internal reforming," Applied Energy, Elsevier, vol. 178(C), pages 294-307.
    9. Hu, Boxun & Keane, Michael & Patil, Kailash & Mahapatra, Manoj K. & Pasaogullari, Ugur & Singh, Prabhakar, 2014. "Direct methanol utilization in intermediate temperature liquid-tin anode solid oxide fuel cells," Applied Energy, Elsevier, vol. 134(C), pages 342-348.
    10. Park, Kwangjin & Lee, Sangho & Bae, Gyujong & Bae, Joongmyeon, 2015. "Performance analysis of Cu, Sn and Rh impregnated NiO/CGO91 anode for butane internal reforming SOFC at intermediate temperature," Renewable Energy, Elsevier, vol. 83(C), pages 483-490.
    11. Dai, Huidong & Besser, R.S., 2022. "Understanding hydrogen sulfide impact on a portable, commercial, propane-powered solid-oxide fuel cell," Applied Energy, Elsevier, vol. 307(C).
    12. Cai, Weizi & Zhou, Qian & Xie, Yongmin & Liu, Jiang & Long, Guohui & Cheng, Shuang & Liu, Meilin, 2016. "A direct carbon solid oxide fuel cell operated on a plant derived biofuel with natural catalyst," Applied Energy, Elsevier, vol. 179(C), pages 1232-1241.
    13. Thieu, Cam-Anh & Ji, Ho-Il & Kim, Hyoungchul & Yoon, Kyung Joong & Lee, Jong-Ho & Son, Ji-Won, 2019. "Palladium incorporation at the anode of thin-film solid oxide fuel cells and its effect on direct utilization of butane fuel at 600 °C," Applied Energy, Elsevier, vol. 243(C), pages 155-164.
    14. Chen, Qianyang & Qiu, Qianyuan & Yan, Xiaomin & Zhou, Mingyang & Zhang, Yapeng & Liu, Zhijun & Cai, Weizi & Wang, Wei & Liu, Jiang, 2020. "A compact and seal-less direct carbon solid oxide fuel cell stack stepping into practical application," Applied Energy, Elsevier, vol. 278(C).
    15. Radenahmad, Nikdalila & Azad, Atia Tasfiah & Saghir, Muhammad & Taweekun, Juntakan & Bakar, Muhammad Saifullah Abu & Reza, Md Sumon & Azad, Abul Kalam, 2020. "A review on biomass derived syngas for SOFC based combined heat and power application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    16. Saadabadi, S. Ali & Thallam Thattai, Aditya & Fan, Liyuan & Lindeboom, Ralph E.F. & Spanjers, Henri & Aravind, P.V., 2019. "Solid Oxide Fuel Cells fuelled with biogas: Potential and constraints," Renewable Energy, Elsevier, vol. 134(C), pages 194-214.
    17. Milanese, Marco & Colangelo, Gianpiero & Laforgia, Domenico & de Risi, Arturo, 2017. "Multi-parameter optimization of double-loop fluidized bed solar reactor for thermochemical fuel production," Energy, Elsevier, vol. 134(C), pages 919-932.
    18. Lyu, Zewei & Shi, Wangying & Han, Minfang, 2018. "Electrochemical characteristics and carbon tolerance of solid oxide fuel cells with direct internal dry reforming of methane," Applied Energy, Elsevier, vol. 228(C), pages 556-567.
    19. Badwal, S.P.S. & Giddey, S. & Kulkarni, A. & Goel, J. & Basu, S., 2015. "Direct ethanol fuel cells for transport and stationary applications – A comprehensive review," Applied Energy, Elsevier, vol. 145(C), pages 80-103.
    20. Arda Hatunoglu & Alessandro Dell’Era & Luca Del Zotto & Andrea Di Carlo & Erwin Ciro & Enrico Bocci, 2021. "Deactivation Model Study of High Temperature H 2 S Wet-Desulfurization by Using ZnO," Energies, MDPI, vol. 14(23), pages 1-14, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:256:y:2019:i:c:s0306261919315971. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.