IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v187y2022icp237-247.html
   My bibliography  Save this article

Dehydration of fatty acid methyl ester mixtures from enzymatic biodiesel using a modified PVDF membrane

Author

Listed:
  • Padula, Miquele L.
  • Romero, Arthur S.
  • Hotza, Dachamir
  • Innocentini, Murilo D.M.
  • Pinto, Maria E.G.
  • Pedrini, Augusto S.
  • Rebelatto, Evertan
  • Ribeiro, Luiz Fernando B.
  • Zin, Guilherme
  • Oliveira, J. Vladimir
  • Di Luccio, Marco

Abstract

This study aimed to investigate the efficiency of microfiltration with a polymeric membrane in the dehydration of fatty acid ester mixtures. The dip-coating method was used to modify the surface of polyvinylidene fluoride (PVDF) hydrophilic membranes using silazane to render them hydrophobic. The membranes were characterized by the contact angle, Fourier-transform infrared spectroscopy (FTIR), zeta potential, field emission scanning electron microscopy (FESEM), membrane water absorption, silazane crosslinking to the membrane surface, and chemical compatibility of membranes to methanol. The microfiltration experiments were carried out in the dead-end and crossflow configurations. Membrane performance was evaluated by permeate flux values, mass reduction ratio, moisture, acidity, and glycerol content in the permeate. Mixtures with different compositions and concentrations of methyl ester, methanol, water, oleic acid, glycerol, and enzyme were used. Silazane deposition time of 60 min at 1 mg silazane/g toluene resulted in the best performance. The modification resulted in chemical and morphological changes in the membrane surface to render it hydrophobic changing its water contact angle from 0 to 94°. For dead-end and crossflow filtration configurations, the modified membranes presented the highest fluxes when compared to the unmodified control membrane, regardless of the composition of the mixtures. All biodiesel mixtures treated with the modified membrane had a decreased water content and an increased oleic acid content in the permeate. This work demonstrated that biocatalyzed fatty acid methyl esters (FAME) can be dehydrated using silazane-modified membranes, resulting in increased separation efficiency.

Suggested Citation

  • Padula, Miquele L. & Romero, Arthur S. & Hotza, Dachamir & Innocentini, Murilo D.M. & Pinto, Maria E.G. & Pedrini, Augusto S. & Rebelatto, Evertan & Ribeiro, Luiz Fernando B. & Zin, Guilherme & Olivei, 2022. "Dehydration of fatty acid methyl ester mixtures from enzymatic biodiesel using a modified PVDF membrane," Renewable Energy, Elsevier, vol. 187(C), pages 237-247.
    • Handle: RePEc:eee:renene:v:187:y:2022:i:c:p:237-247
    DOI: 10.1016/j.renene.2022.01.055
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122000659
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.01.055?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Sokač, Tea & Gojun, Martin & Tušek, Ana Jurinjak & Šalić, Anita & Zelić, Bruno, 2020. "Purification of biodiesel produced by lipase catalysed transesterification by ultrafiltration: Selection of membranes and analysis of membrane blocking mechanisms," Renewable Energy, Elsevier, vol. 159(C), pages 642-651.
    2. Michelin, Simone & Penha, Frederico M. & Sychoski, Melania M. & Scherer, Robison P. & Treichel, Helen & Valério, Alexsandra & Di Luccio, M. & de Oliveira, Débora & Oliveira, J. Vladimir, 2015. "Kinetics of ultrasound-assisted enzymatic biodiesel production from Macauba coconut oil," Renewable Energy, Elsevier, vol. 76(C), pages 388-393.
    3. Aghababaie, Marzieh & Beheshti, Masoud & Razmjou, Amir & Bordbar, Abdol-Khalegh, 2019. "Two phase enzymatic membrane reactor for the production of biodiesel from crude Eruca sativa oil," Renewable Energy, Elsevier, vol. 140(C), pages 104-110.
    4. Alves, Magno José & Nascimento, Suellen Mendonça & Pereira, Iara Gomes & Martins, Maria Inês & Cardoso, Vicelma Luiz & Reis, Miria, 2013. "Biodiesel purification using micro and ultrafiltration membranes," Renewable Energy, Elsevier, vol. 58(C), pages 15-20.
    5. Bharathiraja, B. & Chakravarthy, M. & Kumar, R. Ranjith & Yuvaraj, D. & Jayamuthunagai, J. & Kumar, R. Praveen & Palani, S., 2014. "Biodiesel production using chemical and biological methods – A review of process, catalyst, acyl acceptor, source and process variables," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 368-382.
    6. Nath, Biswajit & Kalita, Pranjal & Das, Bipul & Basumatary, Sanjay, 2020. "Highly efficient renewable heterogeneous base catalyst derived from waste Sesamum indicum plant for synthesis of biodiesel," Renewable Energy, Elsevier, vol. 151(C), pages 295-310.
    7. Gog, Adriana & Roman, Marius & Toşa, Monica & Paizs, Csaba & Irimie, Florin Dan, 2012. "Biodiesel production using enzymatic transesterification – Current state and perspectives," Renewable Energy, Elsevier, vol. 39(1), pages 10-16.
    8. Uliana, Nilva R. & Kuhl, Louise A. & Quadri, Marintho B. & Oliveira, J. Vladimir, 2018. "Model and simulation of a packed resin column for biodiesel purification," Renewable Energy, Elsevier, vol. 126(C), pages 1074-1084.
    9. dos Santos, Letícia Karen & Hatanaka, Rafael Rodrigues & de Oliveira, José Eduardo & Flumignan, Danilo Luiz, 2017. "Experimental factorial design on hydroesterification of waste cooking oil by subcritical conditions for biodiesel production," Renewable Energy, Elsevier, vol. 114(PB), pages 574-580.
    10. Sandouqa, Arwa & Al-Hamamre, Zayed, 2021. "Economical evaluation of jojoba cultivation for biodiesel production in Jordan," Renewable Energy, Elsevier, vol. 177(C), pages 1116-1132.
    11. Kusworo, Tutuk Djoko & Widayat, Widayat & Utomo, Dani Puji & Pratama, Yulius Harmawan Setya & Arianti, Riska Anindisa Vira, 2020. "Performance evaluation of modified nanohybrid membrane polyethersulfone-nano ZnO (PES-nano ZnO) using three combination effect of PVP, irradiation of ultraviolet and thermal for biodiesel purification," Renewable Energy, Elsevier, vol. 148(C), pages 935-945.
    12. Atadashi, I.M. & Aroua, M.K. & Aziz, A. Abdul, 2011. "Biodiesel separation and purification: A review," Renewable Energy, Elsevier, vol. 36(2), pages 437-443.
    13. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.
    14. Nejad, Ardeshir Shayan & Zahedi, Ali Reza, 2018. "Optimization of biodiesel production as a clean fuel for thermal power plants using renewable energy source," Renewable Energy, Elsevier, vol. 119(C), pages 365-374.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Kusworo, Tutuk Djoko & Widayat, Widayat & Utomo, Dani Puji & Pratama, Yulius Harmawan Setya & Arianti, Riska Anindisa Vira, 2020. "Performance evaluation of modified nanohybrid membrane polyethersulfone-nano ZnO (PES-nano ZnO) using three combination effect of PVP, irradiation of ultraviolet and thermal for biodiesel purification," Renewable Energy, Elsevier, vol. 148(C), pages 935-945.
    2. Seyyedeh Faezeh Mirab Haghighi & Payam Parvasi & Seyyed Mohammad Jokar & Angelo Basile, 2021. "Investigating the Effects of Ultrasonic Frequency and Membrane Technology on Biodiesel Production from Chicken Waste," Energies, MDPI, vol. 14(8), pages 1-21, April.
    3. Gojun, Martin & Šalić, Anita & Zelić, Bruno, 2021. "Integrated microsystems for lipase-catalyzed biodiesel production and glycerol removal by extraction or ultrafiltration," Renewable Energy, Elsevier, vol. 180(C), pages 213-221.
    4. Gourich, Wail & Chan, Eng-Seng & Ng, Wei Zhe & Obon, Aaron Anthony & Maran, Kireshwen & Ong, Yi Hui & Lee, Chin Loong & Tan, Jully & Song, Cher Pin, 2022. "Life cycle benefits of enzymatic biodiesel co-produced in palm oil mills from sludge palm oil as renewable fuel for rural electrification," Applied Energy, Elsevier, vol. 325(C).
    5. Mukhtar, Ahmad & Saqib, Sidra & Mubashir, Muhammad & Ullah, Sami & Inayat, Abrar & Mahmood, Abid & Ibrahim, Muhammad & Show, Pau Loke, 2021. "Mitigation of CO2 emissions by transforming to biofuels: Optimization of biofuels production processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    6. Christopher, Lew P. & Hemanathan Kumar, & Zambare, Vasudeo P., 2014. "Enzymatic biodiesel: Challenges and opportunities," Applied Energy, Elsevier, vol. 119(C), pages 497-520.
    7. Ennaceri, Houda & Fischer, Kristina & Schulze, Agnes & Moheimani, Navid Reza, 2022. "Membrane fouling control for sustainable microalgal biodiesel production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    8. Marta Ramos & Ana Paula Soares Dias & Jaime Filipe Puna & João Gomes & João Carlos Bordado, 2019. "Biodiesel Production Processes and Sustainable Raw Materials," Energies, MDPI, vol. 12(23), pages 1-30, November.
    9. Zhao, Xuebing & Qi, Feng & Yuan, Chongli & Du, Wei & Liu, Dehua, 2015. "Lipase-catalyzed process for biodiesel production: Enzyme immobilization, process simulation and optimization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 182-197.
    10. Mauro Banchero & Giuseppe Gozzelino, 2018. "A Simple Pseudo-Homogeneous Reversible Kinetic Model for the Esterification of Different Fatty Acids with Methanol in the Presence of Amberlyst-15," Energies, MDPI, vol. 11(7), pages 1-12, July.
    11. Sokač, Tea & Gojun, Martin & Tušek, Ana Jurinjak & Šalić, Anita & Zelić, Bruno, 2020. "Purification of biodiesel produced by lipase catalysed transesterification by ultrafiltration: Selection of membranes and analysis of membrane blocking mechanisms," Renewable Energy, Elsevier, vol. 159(C), pages 642-651.
    12. Zhang, Zhijin & Du, Yingjie & Kuang, Geling & Shen, Xuejian & Jia, Xiaotong & Wang, Ziyuan & Feng, Yuxiao & Jia, Shiru & Liu, Fufeng & Bilal, Muhammad & Cui, Jiandong, 2022. "Lipase-Ca2+ hybrid nanobiocatalysts through interfacial protein-inorganic self-assembly in deep-eutectic solvents (DES)/water two-phase system for biodiesel production," Renewable Energy, Elsevier, vol. 197(C), pages 110-124.
    13. Wang, Meng & Nie, Kaili & Yun, Feng & Cao, Hao & Deng, Li & Wang, Fang & Tan, Tianwei, 2015. "Biodiesel with low temperature properties: Enzymatic synthesis of fusel alcohol fatty acid ester in a solvent free system," Renewable Energy, Elsevier, vol. 83(C), pages 1020-1025.
    14. Liu, Xiaoyan & Zhu, Fenfen & Zhang, Rongyan & Zhao, Luyao & Qi, Juanjuan, 2021. "Recent progress on biodiesel production from municipal sewage sludge," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    15. Tizvir, A. & Shojaeefard, M.H. & Zahedi, A. & Molaeimanesh, G.R., 2022. "Performance and emission characteristics of biodiesel fuel from Dunaliella tertiolecta microalgae," Renewable Energy, Elsevier, vol. 182(C), pages 552-561.
    16. Babu, D. & Karvembu, R. & Anand, R., 2018. "Impact of split injection strategy on combustion, performance and emissions characteristics of biodiesel fuelled common rail direct injection assisted diesel engine," Energy, Elsevier, vol. 165(PB), pages 577-592.
    17. Li, Zhuoxue & Yang, Depo & Huang, Miaoling & Hu, Xinjun & Shen, Jiangang & Zhao, Zhimin & Chen, Jianping, 2012. "Chrysomya megacephala (Fabricius) larvae: A new biodiesel resource," Applied Energy, Elsevier, vol. 94(C), pages 349-354.
    18. Zahedi, Ali Reza & Mirnezami, Seyed Abolfazl, 2020. "Experimental analysis of biomass to biodiesel conversion using a novel renewable combined cycle system," Renewable Energy, Elsevier, vol. 162(C), pages 1177-1194.
    19. Zhou, Li & Li, Fashe & Duan, Yaozong & Wang, Hua, 2023. "Effect of phospholipids on the premixed combustion behavior of Jatropha curcas biodiesel," Renewable Energy, Elsevier, vol. 218(C).
    20. Oliveira, Anne Caroline Defranceschi & Frensch, Gustavo & Marques, Francisco de Assis & Vargas, José Viriato Coelho & Rodrigues, Maria Luiza Fernandes & Mariano, André Bellin, 2020. "Production of methyl oleate by direct addition of fermented solid Penicillium sumatrense and Aspergillus fumigatus," Renewable Energy, Elsevier, vol. 162(C), pages 1132-1139.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:187:y:2022:i:c:p:237-247. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.