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Experimental factorial design on hydroesterification of waste cooking oil by subcritical conditions for biodiesel production

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  • dos Santos, Letícia Karen
  • Hatanaka, Rafael Rodrigues
  • de Oliveira, José Eduardo
  • Flumignan, Danilo Luiz

Abstract

Hydroesterification is innovation biodiesel production using low cost feedstock by two-step: hydrolysis of waste cooking oil to FFAs in subcritical water and chemical esterification of FFAs into FAME (biodiesel) with methanol. The purpose was to apply the experimental factorial design to evaluate the influence of reaction variables on the effectiveness of hydrolysis and determine the relationship of FFAs and FAMEs yields. Experiments were conducted in a batch reactor under diverse reaction conditions to determine the optimal parameters for hydrolysis. This analyses indicated that high FFAs yields (95 wt%) are achieved using 250 °C; 120 min; 100:1 water-to-oil molar ratio and 700 rpm. Research results revealed a conversion the FFAs in 98.5 wt% of FAMEs with high quality by esterification in biodiesel production. This study shows that the biodiesel produced by subcritical/chemical hydroesterification process has similar qualities to the biodiesel obtained by traditional alkaline transesterification, which suggests a promising alternative for biodiesel production.

Suggested Citation

  • dos Santos, Letícia Karen & Hatanaka, Rafael Rodrigues & de Oliveira, José Eduardo & Flumignan, Danilo Luiz, 2017. "Experimental factorial design on hydroesterification of waste cooking oil by subcritical conditions for biodiesel production," Renewable Energy, Elsevier, vol. 114(PB), pages 574-580.
  • Handle: RePEc:eee:renene:v:114:y:2017:i:pb:p:574-580
    DOI: 10.1016/j.renene.2017.07.066
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    References listed on IDEAS

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    1. Jack P. C. Kleijnen, 2015. "Response Surface Methodology," International Series in Operations Research & Management Science, in: Michael C Fu (ed.), Handbook of Simulation Optimization, edition 127, chapter 0, pages 81-104, Springer.
    2. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    3. Meher, L.C. & Vidya Sagar, D. & Naik, S.N., 2006. "Technical aspects of biodiesel production by transesterification--a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 10(3), pages 248-268, June.
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    Cited by:

    1. Padula, Miquele L. & Romero, Arthur S. & Hotza, Dachamir & Innocentini, Murilo D.M. & Pinto, Maria E.G. & Pedrini, Augusto S. & Rebelatto, Evertan & Ribeiro, Luiz Fernando B. & Zin, Guilherme & Olivei, 2022. "Dehydration of fatty acid methyl ester mixtures from enzymatic biodiesel using a modified PVDF membrane," Renewable Energy, Elsevier, vol. 187(C), pages 237-247.
    2. dos Santos, Letícia Karen & Hatanaka, Rafael Rodrigues & de Oliveira, José Eduardo & Flumignan, Danilo Luiz, 2019. "Production of biodiesel from crude palm oil by a sequential hydrolysis/esterification process using subcritical water," Renewable Energy, Elsevier, vol. 130(C), pages 633-640.
    3. Mauro Banchero & Giuseppe Gozzelino, 2018. "A Simple Pseudo-Homogeneous Reversible Kinetic Model for the Esterification of Different Fatty Acids with Methanol in the Presence of Amberlyst-15," Energies, MDPI, vol. 11(7), pages 1-12, July.

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