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Enhancement of aromatics production via cellulose fast pyrolysis over Ru modified hierarchical zeolites

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  • Zhang, Jun
  • Li, Chengyu
  • Yuan, Haoran
  • Chen, Yong

Abstract

In the present study, Ru modified hierarchical zeolites xRu-MZSM were developed for cellulose fast pyrolysis. Comprehensive catalyst characterizations including XRD, XPS, N2 adsorption-desorption, Py-IR and so on, were performed to unveil the essential structural properties. The chemical modification and Ru decoration remarkably regulated the distribution of Brønsted/Lewis acid sites. The presence of RuOx species would supply abundant strong Lewis acid sites for participating catalytic cracking, dehydration, decarbonylation, decarboxylation, cyclization, aromatization, etc., in cooperation with Brønsted acid sites. In-situ generated active Ru0 centers during cellulose pyrolysis might facilitate the proceeding of deoxygenation, hydride transfer, and dehydrogenation. Among the as-prepared catalysts screened, 2Ru-MZSM was much more efficient in aromatics production from cellulose fast pyrolysis compared to parent ZSM, wherein the total aromatics yield achieved 16.8% at temperature of 650 °C and heating rate of 10 °C/ms with corresponding E value as low as 23.40 kJ/mol. Also, plausible reaction mechanism for xRu-MZSM involved cellulose fast pyrolysis was proposed in detail.

Suggested Citation

  • Zhang, Jun & Li, Chengyu & Yuan, Haoran & Chen, Yong, 2022. "Enhancement of aromatics production via cellulose fast pyrolysis over Ru modified hierarchical zeolites," Renewable Energy, Elsevier, vol. 184(C), pages 280-290.
    • Handle: RePEc:eee:renene:v:184:y:2022:i:c:p:280-290
    DOI: 10.1016/j.renene.2021.11.103
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    References listed on IDEAS

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    1. Zeng, Kuo & Li, Jun & Xie, Yingpu & Yang, Haiping & Yang, Xinyi & Zhong, Dian & Zhen, Wanxin & Flamant, Gilles & Chen, Hanping, 2020. "Molten salt pyrolysis of biomass: The mechanism of volatile reforming and pyrolysis," Energy, Elsevier, vol. 213(C).
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    1. Shiqiao Yang & Ming Lei & Min Li & Chao Liu & Beichen Xue & Rui Xiao, 2022. "Comprehensive Estimation of Combustion Behavior and Thermochemical Structure Evolution of Four Typical Industrial Polymeric Wastes," Energies, MDPI, vol. 15(7), pages 1-22, March.
    2. Chen, Xuejiao & Wang, Hong & Yang, Rui & Lin, Wei & Qi, Zhiyong & Zhang, Dongdong, 2024. "Effect of severe torrefaction by superheated steam on pinewood pyrolysis kinetics and pyrolytic oil compounds," Renewable Energy, Elsevier, vol. 227(C).

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