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Thermal behaviors and kinetics for fast pyrolysis of chemical pretreated waste cassava residues

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  • Zhang, Jun
  • Gu, Jing
  • Yuan, Haoran
  • Chen, Yong

Abstract

In the present study, thermal decomposition behaviors and kinetics for fast pyrolysis of acid/alkali pretreated waste cassava residues were investigated. The results demonstrated that chemical pretreatments apparently loosened the compact structure of cassava residue and benefited to the sufficient contact with acid/alkali sites. Acid/alkali pretreatments enriched the product varieties and had remarkable influence on the adjustment of product formation. Particularly, the pyrolysis behavior obviously shifted to low-temperature zones for pretreated samples. Low heating rate significantly promoted the formation of anhydrosugars with 27% levoglucosan produced, while elevating heating rate contributed to furfural production. Some oxygenated-chemicals, such as acetic acid, hydroxyacetone and 4-hydroxydihydrofuran-2(3H)-one, were apparently formed in the presence of alkali metal. Noticeably, the generation of most gaseous products was restrained for those acid-impregnated cassava residues. Moreover, kinetic study suggested that the apparent activation energy for waste cassava residue pyrolysis was significantly lowered, further verifying the positive role of chemical pretreatments.

Suggested Citation

  • Zhang, Jun & Gu, Jing & Yuan, Haoran & Chen, Yong, 2020. "Thermal behaviors and kinetics for fast pyrolysis of chemical pretreated waste cassava residues," Energy, Elsevier, vol. 208(C).
    • Handle: RePEc:eee:energy:v:208:y:2020:i:c:s0360544220312998
    DOI: 10.1016/j.energy.2020.118192
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    References listed on IDEAS

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    1. Pattiya, Adisak & Sukkasi, Sittha & Goodwin, Vituruch, 2012. "Fast pyrolysis of sugarcane and cassava residues in a free-fall reactor," Energy, Elsevier, vol. 44(1), pages 1067-1077.
    2. Isahak, Wan Nor Roslam Wan & Hisham, Mohamed W.M. & Yarmo, Mohd Ambar & Yun Hin, Taufiq-yap, 2012. "A review on bio-oil production from biomass by using pyrolysis method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 5910-5923.
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    Cited by:

    1. Shiqiao Yang & Ming Lei & Min Li & Chao Liu & Beichen Xue & Rui Xiao, 2022. "Comprehensive Estimation of Combustion Behavior and Thermochemical Structure Evolution of Four Typical Industrial Polymeric Wastes," Energies, MDPI, vol. 15(7), pages 1-22, March.
    2. Liu, Huiyu & Zhang, Jun & Shan, Rui & Yuan, Haoran & Chen, Yong, 2024. "Mechanistic insights into Ga-modified hollow ZSM-5 catalyzed fast pyrolysis of cassava residue," Energy, Elsevier, vol. 295(C).
    3. Mohd Safaai, Nor Sharliza & Pang, Shusheng, 2021. "Pyrolysis kinetics of chemically treated and torrefied radiata pine identified through thermogravimetric analysis," Renewable Energy, Elsevier, vol. 175(C), pages 200-213.
    4. Zhang, Jun & Li, Chengyu & Yuan, Haoran & Chen, Yong, 2022. "Enhancement of aromatics production via cellulose fast pyrolysis over Ru modified hierarchical zeolites," Renewable Energy, Elsevier, vol. 184(C), pages 280-290.

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